Abstract
Cores of podzolic soil (monolith lysimeters) were treated for 4.8 yr with 1500 mm yr−1 of either 0.5 mM H2SO4 at pH 3, equivalent to 24 g S m−2 yr−1 (acid treated) or distilled water (controls). The acid treatment was about 37 times greater than the average annual input of H3O+ from rain at the site from which the monoliths were taken. Acid treatment acidified the litter (from pH(CaCl2)3.4 to pH(CaCl2)2.6) and the mineral soil to a depth of 80 cm (mean pH(CaCl2) decrease of 0.2 unit). In the litter and upper A horizon, ion-exchange reactions provided the main neutralizing mechanism, resulting in a decrease in the reserves of extractable (in 2.5 % acetic acid) Ca, Mg, and Mn of about 70 to 80 %. Dissolution of solid phase Al from hydrous oxides provided most neutralization below this depth. Al3+ was the principal soluble Al species throughout the profile. In the litter and upper A horizon, some of the mobilized Al3+ was retained on cation exchange sites resulting in an increase in exchangeable Al. Deeper in the profile, where the exchange sites were effectively saturated with Al3+, no increase in exchangeable Al occurred, and Al3+ was, therefore, available for leaching. Some reversible adsorption of SO4 2−, associated with hydrous Al oxides, occurred in the Bs and C horizons. The results are discussed in relation to possible effects of acid deposition over regions of Europe and N. America.
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References
Abrahamsen, G.: 1983, ‘Sulphur Pollution: Ca, Mg, and Al in Soil and Soil Water and Possible Effects on Forest Trees’, in B. Ulrich and J.Pankrath (eds.), Effects of Air Pollutants on Forest Ecosystems D. Reidel Publ. Co., Dordrecht, Holland, pp. 207–218.
Allen, S. E.: 1974, Chemical Analysis of Ecological Materials, Blackwell Scientific Publications, Oxford.
Avery, B. W.: 1973, J. of Soil Science 24, 324.
Bache, B. W.: 1980, ‘Acidification of Soils’, in T. C. Hutchinson and M. Havas (eds.), Effects of Acid Precipitation on Terrestrial Ecosystems, Plenum Press, New York, pp. 183–202.
Bache, B. W. and Sharp, G. S.: 1976, Geoderma 15, 91.
Barnhisel, R. and Bertsch, P. M.: 1982, ‘Aluminium’, in A. L. Page (ed.), Methods of Soil Analysis; Part 2: Chemical and Microbiological Properties, American Society of Agronomy, Madison, Wisconsin, pp. 275–299.
Belford, R. K.: 1979, J. Soil Science 30, 363.
Boar, P. L. and Ingram, L. K.: 1970, Analyst 95, 124.
Bormann, F. H. and Likens, G. E.: 1978, Pattern and Process in a Forested Ecosystem, Springer-Verlag, New York.
Brown, K. A.: 1985, Soil Biol. and Biochem. 17, 31.
Burrows, W. D.: 1977, CRC Critical Revs. in Environmental Controls (C. P. Straub (ed.)), June 1977, pp. 167–216.
Butters, B. and Chenery, E. M.: 1959, Analyst 84, 239.
Carson, C. D. and Dixon, J. B.: 1979, ‘Acidity’, in R. W. Fairbridges and C. W. Finkl (eds.), Encyclopedia of Soil Science, Part 1: Physics, Chemistry and Technology Dowden, Hutchinson and Ross, Stroudsberg, Pa, pp. 1–3.
Chao, T. T., Harward, M. E., and Fang, S. C.; 1964, Soil Sci. Soc. America Proc. 28, 632.
Goodnight, J. H., Sall, J. P., and Sarle, W. S.: 1982, ‘The GLM Procedure’, in A. A. Ray (ed.), SAS Users' Guide: Statistics, SAS Institute Inc., Cary, North Carolina, pp. 139–199.
Granat, L.: 1978, Atmos. Env. 12, 413.
Hesse, P. R.: 1971, Textbook of Soil Chemical Analysis, John Murray, London, p. 355.
Hingston, F. J., Atkinson, R. J., Posner, A. M., and Quirk: 1967, Nature 215, 1459.
Hovland, J., Abrahamsen, G., and Ogner, G.: 1980, Plant Soil 56, 365.
Hutchinson, T. C. and Whitby, L. M.: 1977, Water, Air, and Soil Pollut. 7, 421.
IERE: 1981, Effects of SO 2 and its Derivatives on Natural Ecosystems, Agriculture, Forestry and Fisheries, International Electric Research Exchange Report, Central Electricity Research Laboratories, Leatherhead, U.K.
Johnson, D.W.: 1980, ‘Site Susceptibility to Leaching by H2SO4, in T. C. Hutchinson and M. Havas (eds.), Effects of Acid Precipitation on Terrestrial Ecosystems, Plenum Press, New York, pp. 525–535.
Likens, G. E., Bormann, F. H., Pierce, R. S., Eaton, J. S., and Johnson, N. M.: 1977, Biogeochemistry of a Forested Ecosystem, Springer-Verlag, New York.
McFee, W. W.: 1983, Env. Exp. Bot. 23, 203.
OECD: 1977, The OECD Programme on Long Range Transport of Air Pollutants: Measurements and Findings, Organization for Economic Co-operation and Development, Paris.
Persson, G.: 1982, Acidification Today and Tomorrow, Swedish study prepared for the 1982 Stockholm conference on acidification of the environment, Ministry of Agriculture Environment Committee, Stockholm.
Petersen, L.: 1976, Podzols and Podzolization, DSR Forlag, Copenhagen.
Prenzel, J.:1983, ‘A Mechanism for Storage and Retrieval of Acid in Acid Soils’, in B. Ulrich and J. Pankrath (eds)., Effects of Accumulation of Air Pollutants in Forest Ecosystems D. Reidel Publ. Co., Dordrecht, Holland, pp. 157–170.
Rippon, J. E.: 1984, Properties of Soil Used in Monolith Lysimeters and Pot Experiments and a Comparison with Some European soils, CERL Lab. Note TPRD/L/2668/N84, Central Electricity Research Laboratories, Leatherhead, England.
Rippon, J. E., Foster, D. J., and Skeffington, R. A.: 1985, Installation and Operation of the CERL Lysimeters, CERL Lab. Note TPRD/L/2847/N85, Central Electricity Research Laboratories, Leatherhead, England.
Skeffington, R. A.: 1981, Tillingbourne Catchment—Interim Report, CERL Lab. Note RD/L/2083N81, Central Electricity Research Laboratories, Leatherhead, England.
Skeffington, R. A.: 1983, ‘Soil Properties Under Three Species of Tree in Southern England In Relation to Acid Deposition in Throughfall‘, in B. Ulrich and J. Pankrath (eds.), Effects of Air Pollutants on Forest Ecosystems D. Reidel Publ. Co., Dordrecht, pp. 219–231.
Skeffington, R. A.: 1984, ‘Acid Precipitation, Nutrient Cycling and Forest Soil Acidity — Some Investigations in SE England’, in J. Löbel and W. R. Thiel (Eds.), Acid Precipitation — Origin and Effects, VDI Berichte 500, Düsseldorf, West Germany, pp. 337–340.
Skeffington, R. A. and Brown, K. A.: 1986, Water, Air, and Soil Pollut. (in press).
Strayer, R. F. and Alexander, M.: 1981, J. Env. Qual. 10, 460.
Troedsson, T.: 1980, ‘Ten Years Acidification of Swedish Forest Soils’, in D. Drabløs and A. Tollan (eds.), Ecological Impact of Acid Precipitation, Proceedings of an International Conference, Sandefjord, Norway 11–14 March, 1980, SNSF Project, Oslo, p. 184.
Ulrich, B.: 1983, ‘Interaction of Forest Canopies with Atmospheric Constituents: SO2, Alkali and Alkaline Earth Cations and Chloride’, in B. Ulrich and J. Pankrath (eds.), Effects of Accumulation of Air Pollutants in Forest Ecosystems D. Reidel Publ. Co., Dordrecht, Holland, pp. 33–34.
Vick, C. M.: 1975, ‘Air Pollution on Merseyside’, Ph.D. Thesis, Liverpool University.
Wiant, H. V.: 1967a, J. For. 65, 902.
Wiant, H. V.: 1967b, J. For. 65, 489.
Williams, C. H. and Steinbergs, A.: 1962, Plant Soil 17, 279.
Wilson, M. J.: 1983, personal communication.
Witkamp, M.: 1966, Ecology 47, 492.
Witkamp, M.: 1969, Ecology 50, 922.
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Brown, K.A. Chemical effects of pH 3 sulphuric acid on a soil profile. Water Air Soil Pollut 32, 201–218 (1987). https://doi.org/10.1007/BF00227694
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DOI: https://doi.org/10.1007/BF00227694