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Rare-metal mineralization in granitic rocks of the Tongolo Anorogenic Complex — Northern Nigeria

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Abstract

The Tongolo Anorogenic Complex consists of peraluminous biotite granites and peralkaline riebeckite granites in which mineralization is spatially associated with the peraluminous biotite granites. Metallization is dominated by Nb-Sn and Sn-W types. Geochemical analyses of fresh bedrock samples indicate that the Tongolo biotite granites are characterized by enhanced values of a suite of trace elements (Sn, Nb, W, Zn, Rb, Li, F, Th, Y, U) which readily identify them as “specialized” granites. These geochemical data are also examined by R-mode factor analysis with the primary objective of isolating the significant factors accounting for the sample composition as derived from mineralization, alteration and lithology. The resulting orthogonal varimax solution yields a three-factor model that accounts for 79.7% of the total variance. These granite series are marked by what is interpreted as the “lithophile factor” (heavily loaded by Li, Rb, F, Th, Ga, Y, U) dominated by magmatic processes and metallization factors (Nb, Zr, Ga, U, Zn, Li and Sn, W, Rb, F, Th) which are dominated by postmagmatic processes.

The two dominant types of mineralization (Nb-Sn and Sn-W), although characterized by the same pattern of trace-element enrichments, can be discriminated on the basis of Rb/Zr and Sn-Li-F relationships.

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References

  • Aylett, B.J.: Group IIB. In: Comprehensive Inorganic Chemistry. Trotman-Dickson, A.F., Ed., Vol. 3, pp. 187–328 Pergamon Press, Oxford 1973

    Google Scholar 

  • Barsukov, V.L.: Sources of the ore substance of tin deposits. Trans. Inst. Mining Metallurgy, Sect. B. 76, B 220 (abstract). (1967)

  • Bowden, P., Kinnaird, J.A.: Younger granites of Nigeria a Zinc-rich tin province. Inst. Mining Metallurgy Trans. Sect. B. 87, B 66-B 69 (1978)

    Google Scholar 

  • Bowden, P., Bennett, J.N., Kinnaird, J.A., Whitley, J.E., Abaa, S.I.: Uranium in the Niger — Nigeria Younger Granite Province. Mineral. Magazine 44, 379–389 (1981)

    Google Scholar 

  • Bowden, P.: Magmatic evolution and mineralization in the Nigerian Younger Granite province. In: Metallization Associated with Acid Magmatism. Evans, A.M. Ed., pp. 51–61 John Wiley and Sons Ltd. 1982

  • Buchanan, M.S., MacLeod, W.N., Turner, D.C., Wright, E.P.: The geology of the Jos-Plateau, vol. 2. The Younger Granite Complexes: Nigeria Geol. Survey Bull No. 32, 160 p (1971)

  • Cotton, F.A., Wilkinson, G.: Advanced inorganic chemistry. John Wiley Interscience. New York (1980)

    Google Scholar 

  • Ficklin, W.H.: A rapid method for the determination of fluoride in rocks and soils using ion-selective electrode. U.S. Geol. Survey. Prof. Paper 700, 186–188 (1970)

  • Flinter, B.H.: Tin in acid granitoids: the search for a geochemical scheme of mineral exploration: Canadian Inst. Mining and Metallurgy Spec. Vol. II, 323–330 (1971)

    Google Scholar 

  • Flinter, B.H., Hesp, W.R., Rigby, D.: Selected geochemical mineralogical and petrological features of granitoids of the New England Complex, Australia and their relation to Sn, W, Mo and Cu mineralization. Econ. Geol. 67, 1241–1262 (1972)

    Google Scholar 

  • Gerasimovski, V.L.: Geochemistry of agpaitic repheline eyenites. Proc. 23rd International Geol. Congress Czechoslovakia 6, 259–265 (1968)

    Google Scholar 

  • Groves, D.I.: The geochemical evolution of tin-bearing granites in the Blue-Tier batholith, Tasmania. Econ. Geol. Vol. 67, p. 445–457 (1972)

    Google Scholar 

  • Groves, D.I.: Vertical geochemical zonation within tin-bearing granite sheets, Blue Tier Batholith, N.E. Tasmania. In: Stemprok, M., Ed., Metallization Associated with Acid Magmatism. Vol. 3, pp. 205–215 Stuttgart: Schweizerbart, 1978

    Google Scholar 

  • Groves, D.I., McCarthy, T.S.: Fractional crystallization and origin of tin deposits in granitoids. Mineral. Deposita 13, 11–26 (1978)

    Google Scholar 

  • Haapala, I.: Petrograph and geochemistry of the Eurojoki stock, a rapakivi granite complex with greisen-type mineralization in southwestern Finland Bull. geol. Survey Finland No. 286, 128 p. (1977)

  • Hesp, W.R.: Correlations between the tin content of granitic rocks and their chemical and mineralogical composition Can. Inst. Mining Metallurgy, Spec. Vol. II, 341–353 (1971)

    Google Scholar 

  • Hesp, W.R.: Geochemical features of Sn-Ta-Nb mineralization associated with granitic rocks in Southeastern Australia. In: Stemprok, M., Ed., Metallization Associated with Aid Magmatism Prague: Geol. Survey 170–180 (1974)

  • Horsnail, R.F.: The geology of Tungsten. In: Proceedings of the 1st International Tungsten Symposium, Stockholm: London, Mining Jour. Books Ltd, 18–31 (1979)

    Google Scholar 

  • Hosking, K.F.G.: The relationship between primary deposits and granitic rocks. In: Fox, W., Ed., Technical Conference on Tin, London, 1966: London, Internat. Tin Council, Vol. 1, pp. 267–311 (1967)

  • Hinter, D.R.: The tin mineralization project in Pretoriue D.A. (compiler) 13th annual report for 1971: Johannesburg, Univ. Witwatersrand, Econ, Geol. Research Unit, 34–37 (1972)

  • Imeokparia, E.G.: Ore-bearing potential of granitic rocks from one Jos — Bukuru Complex, northern Nigeria. Chem. Geol. 28, 69–88 (1980)

    Google Scholar 

  • Imeokparia, E.G.: Geochemistry and relationships to mineralization of granitic rocks from the Afu Younger Granite Complex Central Nigeria. Geol. Mag. 119, 39–56 (1982)

    Google Scholar 

  • Imeokparia, E.G.: Lithogeochemical dispersion associated with Ririwai Zinc — tin lode, northern Nigeria. Jour. Geochem. Exploration 19, 643–661 (1983)

    Google Scholar 

  • Ishihira, S.: Tin-Tungsten — molybdenum metallogenic provinces in East Asia and some problems involved in their plate tectonics interpretation. In: Stemprok, M., Brunal, L., Tischendorf, G., Ed. Metallization. Associated with Acid Magmatism: Prague Geol. Survey Czechoslovak Acad. Sci. 3, 29–37 (1978)

    Google Scholar 

  • Ivanova, GF.: Content of tin, tungsten and molybdenum in granites enclosing tin-tungsten deposits. Geochem. International 5, 492–500 (1963)

    Google Scholar 

  • Jarchovsky, T.: Geochemical characteristic of lithium granite from Krasno (Slavkowsky Les Mts). In: Semprok M., Ed., Metallization Associated with Acid Magmatism. Geol. Survey Prague 197–200 (1974)

  • Kaiser, H.F.: The varimax criteria for analytical relation in factor analysis — Psychology 23, 187–200 (1958)

    Google Scholar 

  • Lehmann, B.: Metallogeny of tin: magmatic differentiation versus geochemical heritage. Econ. Geol. 77, 50–59 (1982)

    Google Scholar 

  • Levinson, A.A.: Introduction to Applied Geochemistry. Applied Pub. Company, Calgary (1974)

    Google Scholar 

  • Manning, D.A.C.: An experimental study of the effects of fluorine on the crystallization of Granitic melts. In: Evans, A.M., Ed., Metallization Associated with Acid Magmatism. pp. 191–203, John Wiley and Sons Ltd., 1982

  • Nie, N.H., Hull, C.H., Jenkens, J.G., Steinbrenner, K., Bent, D.H.: Statistical package for the social sciences — McGraw-Hill, New York, 2nd ed., 675 p. (1975)

    Google Scholar 

  • Norrish, K., Hutton, J.T.: An accurate X-ray spectrographic method for the analysis of a wide range of geological samples, Geochim Cosmochim Acta 33, 431–454 (1969)

    Google Scholar 

  • Olade, M.A.: Geochemical characteristics of tin-bearing and tin-barren granites, northern Nigeria. Econ. Geol. 75, 71–82 (1980)

    Google Scholar 

  • Simpson, P.R., Brown, G.C., Plant, J., Ostle, D.: Uranium mineralization and granite magmatism in the British Isles. Royal Soc. (London) Philos. Trans. A 291, 385–412 (1979)

    Google Scholar 

  • Smith, T.E., Tunek, A.: Tin-bearing potential of some Devonian granitic rocks in S.W. Nova Scotia. Mineral. Deposita 11, 234–245 (1976)

    Google Scholar 

  • Stemprok, M.: Geochemical association of tin. In: Fox, W., Ed., Technical Conference on Tin, 2nd Bangkok, 1969 London Internat. Tin Council, vol. 1, 118–124 (1970)

  • Stemprok, M.: Petrochemical features of tin-bearing granites in the Krusne Hory Mts. Czechoslovakia, Soc. Mining Geol. Jampan. Spec. Issue 2, 112–118 (1971)

    Google Scholar 

  • Stemprok, M., Sulcek, Z.: Geochemical profile through an orebearing lithium granite. Econ. Geol. 64, 392–404 (1969)

    Google Scholar 

  • Streckeisen, A.: To each plutonic rocks its proper name. Earth-Science Rev. 12, 1–33 (1976)

    Google Scholar 

  • Strong, D.F.: Granitoid rocks and associated mineral deposits of eastern Canada and western Europe Geol. Assoc. Canada Spec. Paper 20, 741–769 (1980)

  • Strong, D.F.: Ore deposit models — 5: A model for granitophile mineral deposits. Geoscience Canada 8 (4), 155–161 (1981)

    Google Scholar 

  • Tauson, L.V., Kozlov, V.D.: Distribution functions and ratios of trace-element concentrations as estimators of the ore-bearing potential of granites. Geochem. Exploration 1972: Inst. Mining and Metallurgy, London England, pp. 37–44 (1973)

    Google Scholar 

  • Taylor, R.G.: Geology of Tin deposits: Amsterdam Elsevier 543 p (1979)

    Google Scholar 

  • Tischendorf, G.: The metallurgenic basis of tin exploration in the Erzgebirge. Trans. Inst. Min. Metallurgy (Sect. B) 87, B 9-B 24 (1973)

    Google Scholar 

  • Tischendorf, G., Schust, F., Lange, H.: Relation between granites and tin deposits in the Erzgebirge, GDR. In: Stemprok, M., Burnol, L., Tischendorf, G., Ed., Metallization Associated with Acid Magmatism vol. 3, pp. 123–138 Stuttgart: Schweizerbart 1978

    Google Scholar 

  • Turekian, K.K., Wedepohl, K.H.: Distribution of the elements in some major units of the earth crust: Geol. Soc. Amer. Bull. 72, 175–192 (1961)

    Google Scholar 

  • Tuttle, O.F., Bowen, N.L.: Origin of granites in the light of experimental studies in the system Na AlSi3O8-KAlSi3O8-SiO2-H2O. Geol. Soc. Amer. Memoir 74, 153 p (1958)

    Google Scholar 

  • Ward, F.N., Nakagawa, H.M., Haims, T.F., Vansike G.H.: Atomic absorption methods of analysis useful in geochemical exploration. U.S. Geol. Survey. Bull. 1289 (1969)

  • Watson, E.B.: Zircon saturation in felsic liquids: experimental results and applications to trace-element geochemistry. Contrib. Mineral. Petrol. 70, 417–419 (1979)

    Google Scholar 

  • Wilson, M.R., Akerblom, G.: Uranium-enriched granites in Sweden Sveriges Geologiska Undersokning Rapporter ech meddlanden nr 19, 30 p (1980)

  • Yeats, A.N., Wyatt, B.W., Tucker, D.H.: Application of gamma — ray spectrometry to prospecting for tin and tungsten granites, particularly within the Lachlan Fold Belt, New South Wales. Econ. Geol. 77, 1725–1738 (1982)

    Google Scholar 

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Imeokparia, E.G. Rare-metal mineralization in granitic rocks of the Tongolo Anorogenic Complex — Northern Nigeria. Mineral. Deposita 20, 81–88 (1985). https://doi.org/10.1007/BF00204314

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