Abstract
We have obtained high quality Raman spectra for two H/D isotopically substituted hydrous aluminosilicate glasses with compositions along the NaAlSi3O8-SiO2 join. Consistent with the results of previous studies, the isotope shift for the band near 900 cm−1, whose intensity grows with increasing water content, is extremely small: v h /v d = 1.004 ± 0.004. The lack of a definite H/D isotope shift for this band does not, however, preclude its association with a vibration of a hydrous species in the glass, because of likely strong coupling between different vibrational modes of hydrated framework species. The 900 cm−1 band could well be due to a T — OH (T = Si, Al) stretching or bending vibration in the hydrous glass, as required by the presence of a combination band near 4500 cm−1 in near-infrared spectra.
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References
Farnan I, Kohn SC, Dupree R (1987) A study of the structural role of water in hydrous silica glass using cross-polarisation magic angle spinning NMR. Geochim Cosmochim Acta 51:2869–2873
Freund F (1982) Solubility mechanisms of H2O in silicate melts at high pressures and temperatures: a Raman spectroscopic study: discussion. Am Mineral 67:153–154
Hartwig CM, Rahn LA (1977) Bound hydroxyl in vitreous silica. J Chem Phys 67:4260–4261
Herzberg G (1945) Molecular Spectra and Molecular Structure. II. Infrared and Raman spectra of polyatomic molecules. Van Nostrand, New York
Hess AC, McMillan PF, O'Keeffe M (1988) Calculated torsional barriers and force fields in H4TO4 molecules and molecular ions (T = CBSiAl). J Phys Chem 92:1785–1793
Kohn SC, Dupree R, Smith ME (1989) A multinuclear magnetic resonance study of the structure of hydrous albite glass. Geochim Cosmochim Acta 53:2925–2935
McMillan P, Piriou B, Navrotsky A (1982) A Raman spectroscopic study of glasses along the joins silica-calcium aluminate silica-sodium aluminate and silica-potassium aluminate. Geochim Cosmochim Acta 46:2021–2037
McMillan P, Jakobsson S, Holloway JR, Silver LA (1983) A note on the Raman spectra of water-bearing quenched albite glasses. Geochim Cosmochim Acta 47:1937–1943
McMillan P, Remmele R (1986) Hydroxyl sites in SiO2 glass: A note on infrared and Raman spectra. Am Mineral 71:772–778
Mysen BO, Virgo D, Harrison WJ, Scarfe CM (1980a) Solubility mechanisms of H2O in silicate melts at high pressures and temperatures: a Raman spectroscopic study. Am Mineral 65:900–914
Mysen BO, Virgo D, Scarfe CM (1980b) Relations between the anionic structure and viscosity of silicate melts — a Raman spectroscopic study. Am Mineral 65:690–710
Mysen BO, Virgo D (1986a) Volatiles in silicate melts at high pressure and temperature. 1. Interaction between OH groups and Si4+Al3+Ca2+Na+ and H+. Chem Geol 57:303–331
Mysen BO, Virgo D (1986b) Volatiles in silicate melts at high pressure and temperature. 2. Water in melts along the join NaAlO2-SiO2 and a comparison of solubility mechanisms of water and fluorine. Chem Geol 57:333–358
Mysen BO (1988) Structure and properties of silicate melts. Elsevier, Amsterdam
Newman S, Stolper EM, Epstein S (1986) Measurement of water in rhyolitic glasses: calibration of an infrared spectroscopic technique. Am Mineral 71:1527–1541
Pichavant M, Holtz F, McMillan P (1992) Phase relations and compositional dependence of H2O solubility in quartz-feldspar melts. Chem Geol 96:303–319
Remmele R, Stanton T, McMillan P, Holloway JR (1986) Raman spectra of hydrous glasses along the quartz-albite join. Eos Trans Am Geophys Union 67:1274
Rudert V, Chou IM, Eugster HP (1976) Temperature gradients in rapid-quench cold-seal vessels. Am Mineral 61:1012–1015
Ryskin YI (1974) The vibrations of protons in minerals: hydroxyl water and ammonium. In: “The Infrared Spectra of Minerals: ed. VC Farmer, pp 137–181. Mineral Soc, London
Seifert F, Mysen BO, Virgo D (1982) Three-dimensional network structure of quenched melts (glass) in the systems SiO2-NaAlO2 SiO2-CaAl2O4 and SiO2-MgAl2O4. Am Mineral 67:696–717
Sharma SK, Simons B, Yoder HS (1983) Raman study of anorthite calcium Tschermak's pyroxene and gehlenite in crystalline and glassy states. Am Mineral 68:1113–1125
Silver LA, Ihinger PD, Stolper E (1990) The influence of bulk composition on the speciation of water in silicate glasses. Contrib Mineral Petrol 104:142–162
Stanton TR (1989) High pressure isotopic studies of the water diffusion mechanism in silicate melts and glasses. PhD Dissertation, Arizona State University
Stolen RH, Walrafen GE (1976) Water and its relation to broken bond defects in fused silica. J Chem Phys 64:2623–2631
Stolper EM (1982a) Water in silicate glasses: an infrared spectroscopic study. Contrib Mineral Petrol 94:178–182
Stolper EM (1982b) The speciation of water in silicate melts. Geochim Cosmochim Acta 46:2609–2620
Sykes D, Kubicki JD (1991) Infrared spectroscopy and ab-initio calculation of vibrational frequencies in hydrous albite glasses. Eos Trans Am Geophys Union 72:555
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McMillan, P.F., Poe, B.T., Stanton, T.R. et al. A Raman spectroscopic study of H/D isotopically substituted hydrous aluminosilicate glasses. Phys Chem Minerals 19, 454–459 (1993). https://doi.org/10.1007/BF00203185
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DOI: https://doi.org/10.1007/BF00203185