Abstract
The toxicity of A1 to aquatic biota varies with speciation. Driscoll (1980) has developed a scheme for determining three A1 fractions using the ferron method (Smith, 1971) to detect Al. We have compared the results obtained with Driscoll's method with those obtained when pyrocatechol violet is the complexing agent. The agreement is generally satisfactory. The latter method is more sensitive and less influenced by interferences. Results for water samples, mainly from two streams in southern Norway, are discussed. For most samples the labile monomeric Al-fraction dominates, the major species being either A13+ or AIF2+. Possible equilibria between A13+ and some minerals and the temperature changes in these equilibria, are discussed.
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Anton, A.: 1960, Anal. Chem. 32, 725.
Baker, J. P. and Schofield, C. L.: 1980, in D. Drabløs and A. Tollan (eds.), Ecological Impact of Acid Precipitation, SNSF-project, Norwegian Inst. Water Research, Olso, p. 292.
Baker, J. P. and Schofield, C. L.: 1982, Water, Air, and Soil Pollut. 18, 289.
Brække, F. H.: 1981, ‘Hydrochemistry of high Attitude Catchments in South Norway, I. Effects of Summer Droughts and Soil-Vegetation Characteristics’, Rep. of the Norw. Forest Research Inst., 36.8, Ås, Norway.
Christophersen, N. and Wright, R. F.: 1981, Water Resour. Research 17, 377.
Christophersen, N., Seip, H. M., and Wright, R. F.: 1982, Water Resour. Research 18, 977.
Christophersen, N., Dymbe, L., Johannessen, M., and Seip, H. M.: 1983, Ecol. Model. (in press).
Cowling, E. B.: 1983, ‘The North American Acid Rain Situation, in Ecological Effects of Acid Deposition’, National Swedish Environ. Protection Board — Report PM 1636, 53.
Dale, T., Henriksen, A., Joranger, E., and Krog, S.: 1974, ‘Investigations of Precipitation and Runoff Chemistry at the Birkenes Catchment’, 20 July, 1972–30 April, 1973, SNSF-project TN 1/74 (in Norwegian), Norwegian Inst. Water Research, Oslo, 45 p.
Davenport, W. H.: 1949, Anal. Chem. 21, 710.
Dougan, W. K. and Wilson, A. L.: 1974, Analyst. 99, 413.
Driscoll, C. T.: 1980, ‘Chemical Characterization of some Dilute Acidified Lakes and Streams in the Acirondack Region of New York State’, Ph.D. Thesis, Cornell Univ., Ithaca, N.Y.
Driscoll, C. T.: 1984, Int. J. Environ. Anal. Chem. (in press).
Driscoll, C. T., Baker, J. P., Bisogni, J. J., and Schofield, C. L.: 1980, Nature 284, 161.
Driscoll, C. T., Baker, J. P., Bisogni, J. J., and Schofield, C. L.: 1983, in O. M. Bricker (ed.), Acid Precipitation: Geological Aspects, Ann Arbor Science, Ann Arbor, MI, p. 55.
Garrels, R. M. and Christ, C. L.: 1965, Solutions, Minerals and Equilibria, Harper and Row, John Weatherhill.
Hemingway, B. S. and Robie, R. A.: 1977a, U.S. Geol. Survey J. Res. 5, 413.
Hemingway, B. S. and Robie, R. A.: 1977b, Geochim. Cosmochim. Acta 41, 1402.
Hemingway, B. S., Robie, R. A., and Kittrick, J. A.: 1978, Geochim. Cosmochim. Acta 42, 1533.
Johnson, N. M., Driscoll, C. T., Eaton, J. S., Likens, G. E., and McDowell, W. H.: 1981, Geochim. Cosmochim. Acta 45, 1421.
LaZerte, B.: 1984, Can. J. Fish. Aquat. Sci. (in press).
May, H. M., Helmke, P. A., and Jackson, M. L.: 1979, Geochim. Cosmochim. Acta 43, 861.
Müller, L.: 1983, ‘Determination of Aliminium Species in Natural Water (in Norwegian)’, Cand.scient. Thesis, Univ. of Oslo, Department of Chemistry.
Muniz, I. P. and Leivestad, H.: 1980, in D. Drabløs and A. Tollan (eds.), Ecological Impact of Acid Precipitation, SNSF-project, Norwegian Inst. Water Research, Oslo, 84.
Naas, A.: 1982, ‘Determination of Aluminium Species in Natural Water (in Norwegian)’, Cand.scient. Thesis, Univ. of Oslo, Department of Chemistry.
Okura, T., Goto, K., and Yotuyanagi, T.: 1962, Anal. Chem. 34, 581.
Overrein, L. N., Seip, H. M., and Tollan, A.: 1980, ‘Acid Precipitation — Effects on Forest and Fish’, Final report of the SNSF-project 1972–1980, SNSF-project FR19/80, Norwegian Inst. Water Research, Oslo.
Rainwater, F. H. and Thatcher, L. L.: 1960, U.S. Geol. Survey Water-Supply Paper, No. 1454.
Roberson, C. E. and Hem, J. D.: 1969, U.S. Geol. Survey Water-Supply Paper, No. 1827-C.
Robie, R. A., Hemingway, B. S., and Fisher, J. R.: 1978, U.S. Geol. Survey Bull. 1452.
Smith, R. W.: 1971, Adv. in Chemistry Series 106, 250.
Smith, R. W. and Hem, J. D.: 1972, U.S. Geol. Survey Water-Supply Paper, No. 1827-D.
Swedish Min. Agric.: 1982, ‘Acidification Today and Tomorrow’, Swedish Ministry of Agriculture Environment 1982 Committee, 231 p.
Turner, R. C.: 1968, Can. J. Chem. 47, 2521.
Wilson, A. D. and Sergeant, G. A.: 1963, Analyst 88, 109.
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Seip, H.M., Müller, L. & Naas, A. Aluminium speciation: comparison of two spectrophotometric analytical methods and observed concentrations in some acidic aquatic systems in Southern Norway. Water Air Soil Pollut 23, 81–95 (1984). https://doi.org/10.1007/BF00185133
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DOI: https://doi.org/10.1007/BF00185133