Summary
Cobalt(II), nickel(II) and copper(II) complexes of 2-thiouracil and its arylazo derivatives were prepared. The elemental analysis suggest a range of 1∶1, 2∶1 and 1∶3 stoichiometries. Electronic spectra and magnetic susceptibility measurements were used to infer the structures and the i.r. spectra of the ligands and their complexes to identify the type of bonding.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. S. Masoud, F. A. Khalil and M. E. Kassem, Reactiv. Solids, 2, 269 (1986).
M. S. Masoud, S. A. Abou Ali, G. Y. Ali and T. M. Abed, Thermochim. Acta, 122, 209 (1987).
M. S. Masoud and Z. M. Zaki, Transition Met. Chem., 13, 321 (1988).
M. S. Masoud and S. A. Abou El-Enein, Thermochim. Acta, 140, 365 (1989).
M. S. Masoud, M. A. El-Dessouky, F. A. Aly and S. A. Abou El-Enein, Transition Met. Chem., 15, 443 (1990).
M. S. Masoud, S. S. Haggag, E. M. Soliman and M. E. El-Shabasy, J. Mat. Sci., 26, 1109 (1991).
M. S. Masoud, S. A. Abou El-Enein and E. El-Sherefeay, J. Therm. Anal., 37, 365 (1991).
M. S. Masoud and E. A. Khalil, J. Chem. Soc. Pak., 13, 161 (1991).
M. S. Masoud and S. S. Haggag, Thermochim. Acta, 196, 221 (1992).
J. P. Kokko, J. H. Goldstein and Leon Mandell, J. Am. Chem. Soc., 83, 2909 (1961).
J. P. Kokko, Leon Mandell and J. H. Goldstein, J. Am. Chem. Soc., 84, 1042 (1962).
M. S. Masoud, A. M. Kaddah, A. M. Khalil and N. I. Tawfik, Ind. J. Chem., 17A, 297 (1979).
S. Charberek and A. E. Martell, J. Am. Chem. Soc., 74, 5052 (1952).
A. R. Katritzky, F. W. Maine, Tetrahedron, 20, 299 (1964).
M. Gupta and M. N. Srivastava, Polyhydron, 4, 479 (1985).
M. Patel, M. M. Patel, A. Ray and H. R. Patel, J. Inorg. Nucl. Chem., 43, 509 (1981).
D. A. Baldwin, A. B. P. Lever and R. V. Parish, Inorg. Chem., 8, 107 (1969).
M. Mohan and P. Sharma, Inorg. Chim. Acta, 106, 117 (1985).
M. S. Masoud, A. M. Heiba and F. M. Ashmawy, Transition Met. Chem., 8, 124 (1983).
U. P. Singh, R. Ghose and A. K. Ghose, Transition Met. Chem., 13, 50 (1988).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, 2nd Edit., Wiley Interscience, New York, 1970.
L. G. Van Uitert and C. G. Hass, J. Am. Chem. Soc., 75, 451 (1953).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Masoud, M.S., El-Hamid, O.H.A. & Zaki, Z.M. 2-thiouracil-based cobalt(II), nickel(II) and copper(II) complexes. Transition Met Chem 19, 21–24 (1994). https://doi.org/10.1007/BF00166259
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00166259