Skip to main content
SpringerLink
Log in

Copper(II) complexes of 6-methyl-2-formylpyridine 4N-substituted thiosemicarbazones

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

Copper(II) complexes of 6-methyl-2-formylpyridine thiosemicarbazone, and its 4N-methyl-, 4N-ethyl-, 4N-phenyl-,4 N-dimethyl-, 4N-diethyl-, 4N-dipropyl-, 3-pyrrolidinyl, 3-piperidinyl- and 3-hexamethyleneiminylthiosemicarbazone derivatives were prepared and characterized. I.r., electronic and e.s.r. spectra of the complexes, as well as 1H and 13C n.m.r. spectra of the thiosemicarbazones, were obtained. The thiosemicarbazones and their copper(II) complexes show either modest or no growth inhibitory activity against Aspergillus niger, but the 4N-dialkyl- and 3-azacyclo-derivatives exhibit considerable activity against Paecilomyces variotii.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. P. Scovill, D. L. Klayman and C. F. Franchino, J. Med. Chem., 25, 1261 (1982).

    Article  CAS  Google Scholar 

  2. C. F. Bell, K. A. K. Lott and N. Hearn, Polyhedron, 6, 39 (1987).

    Article  CAS  Google Scholar 

  3. W. E. Antholine, J. M. Knight and D. H. Petering, Inorg. Chem., 16, 569 (1977); H. Beraldo and L. Tosi, Inorg. Chim. Acta, 125, 173 (1986); A. G. Bingham, H. Bogge, A. Muller, E. W. Ainscough and A. M. Brodie, J. Chem. Soc., Dalton Trans., 493 (1987); H. K. Parwana and G. Singh, Ind. J. Chem., 26A, 581 (1987).

    Article  CAS  Google Scholar 

  4. M. A. Malik and D. J. Phillips, J. Inorg. Nucl. Chem., 36, 2229 (1974).

    Article  CAS  Google Scholar 

  5. P. S. N. Reddy and B. V. Agarwala, Synth. React. Inorg. Met.-org. Chem., 17, 585 (1987).

    CAS  Google Scholar 

  6. D. X. West, D. L. Huffman, J. S. Saleda and A. E. Liberta, Transition Met. Chem., 16, 565 (1991).

    Article  CAS  Google Scholar 

  7. D. X. West, J. S. Saleda and A. E. Liberta, Transition Met. Chem., 17, 568 (1992).

    CAS  Google Scholar 

  8. D. X. West, C. S. Carlson, A. E. Liberta, J. N. Albert and C. R. Daniel, Transition Met. Chem., 15, 341 (1990) and references therein.

    Article  CAS  Google Scholar 

  9. D. X. West, C. S. Carlson, A. E. Liberta and J. P. Scovill, Transition Met. Chem., 15, 383 (1990).

    Article  CAS  Google Scholar 

  10. B. Holmberg and B. Psilanderhielm, J. Prakt. Chem., 82, 440 (1910).

    Article  Google Scholar 

  11. J. P. Scovill, Phosph. Sulf. Silic., 60, 15 (1991).

    CAS  Google Scholar 

  12. K. R. Koch, J. Coord. Chem., 22, 289 (1991).

    Article  CAS  Google Scholar 

  13. D. X. West, B. L. Mokijewski, H. Gebremedhin and T. J. Romack, Transition Met. Chem., 17, 384 (1992).

    Article  CAS  Google Scholar 

  14. M. Biddau, M. Massacesi, R. Pinna and G. Ponticelli, Transition Met. Chem., 3, 153 (1978).

    Article  CAS  Google Scholar 

  15. S. K. Nag and D. S. Joarder, Can. J. Chem., 54, 2827 (1976); S. K. Sengupla, S. K. Sahni and R. N. Kapoor, Acta Chim. Acad. Sci. Hungary, 104, 89 (1980); R. Roy, M. Chaudhury, S. K. Mondal and K. Nag, J. Chem. Soc., Dalton Trans., 1681 (1984); A. Z. El-Sonbati, E. M. Mabrouk and H. E. Magahed, Transition Met. Chem., 16, 80 (1991).

    Article  CAS  Google Scholar 

  16. M. B. Ferrari, G. G. Fava, M. Lafranchi, C. Pelizzi and P. Tarasconi, Inorg. Chim. Acta, 181, 253 (1991).

    Article  Google Scholar 

  17. S. F. Mason in A. R. Kalzitizky (Ed.), Physical Methods in Heterocyclic Chemistry, Vol. II, Chapt. 7, Academic Press, New York, 1963.

    Google Scholar 

  18. E. Ainscough, A. M. Brodie and N. G. Larsen, Inorg. Chim. Acta, 60, 25 (1982); L. Soto, A. Sancho and J. Borras, Synth. React. Inorg. Met.-org. Chem., 16, 595 (1986).

    Article  CAS  Google Scholar 

  19. P. L. Dedert, J. S. Thompson, J. A. Ibers and T. J. Marks, Inorg. Chem., 21, 969 (1982).

    Article  CAS  Google Scholar 

  20. M. Suzuki, H. Kanatomi, H. Koyama and I. Murase, Bull. Chem. Soc. Jpn, 53, 1961 (1980); D. Kovala-Demertzi, J. M. Tsangaris and N. Hadjiliadis, Transition Met. Chem., 8, 140 (1983); M. Suzuki, H. Kanatomi, Y. Demura and I. Murase, Bull. Chem. Soc. Jpn, 57, 1003 (1984).

    Article  CAS  Google Scholar 

  21. D. X. West, C. S. Carlson, A. E. Liberta, J. N. Albert and C. R. Daniel, Transition Met. Chem., 15, 341 (1990).

    Article  CAS  Google Scholar 

  22. A. S. Kumbhar, S. B. Padhye, D. X. West and A. E. Liberta, Transition Met. Chem., 16, 271 (1991); A. S. Kumbhar, S. B. Padhye, D. X. West and A. E. Liberta, Transition Met. Chem., 17, 247 (1992).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West, Shari L. Dietrich, Imporn Thientanavanich & Christine A. Brown

  2. Department of Biological Sciences, Illinois State University, 61761, Normal, IL, USA

    A. E. Liberta

Authors
  1. Douglas X. West
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shari L. Dietrich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Imporn Thientanavanich
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Christine A. Brown
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. E. Liberta
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

West, D.X., Dietrich, S.L., Thientanavanich, I. et al. Copper(II) complexes of 6-methyl-2-formylpyridine 4N-substituted thiosemicarbazones. Transition Met Chem 19, 195–200 (1994). https://doi.org/10.1007/BF00161888

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00161888

Keywords

Search

Navigation