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Magnetic measurements and spectral studies on copper(II) complexes of semicarbazones derived from isatin, benzoin and 2-hydroxy-naphthaldehyde

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Summary

The preparation and spectral properties of five copper(II) complexes of semicarbazones, derived from 2-hydroxy-naphthaldehyde (NPSCZ), benzoin (BZSCZ) and isatin (ISSCZ) are described. I.r., electronic, e.s.r. 1H and 13C n.m.r. spectra show that the semicarbazone's coordination is distorted trigonal bipyramidal for [Cu(BZSCZ-2H)(H2O)], distorted tetragonal pyramidal for [Cu(NPSCZ)2](ClO4)2 and dimeric for the other three complexes.

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Authors and Affiliations

  1. Department of Chemistry, University of Calabar, Calabar, Nigeria

    Narayan T. Akinchan & Richa Akinchan

  2. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West & YongHong Yang

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  1. Narayan T. Akinchan
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  2. Richa Akinchan
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  3. Douglas X. West
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  4. YongHong Yang
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Akinchan, N.T., Akinchan, R., West, D.X. et al. Magnetic measurements and spectral studies on copper(II) complexes of semicarbazones derived from isatin, benzoin and 2-hydroxy-naphthaldehyde. Transition Met Chem 19, 135–140 (1994). https://doi.org/10.1007/BF00161874

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  • DOI: https://doi.org/10.1007/BF00161874

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