Summary
Facile reaction of 2,2′,6′,2″-terpyridine (L; terpy) with copper or zinc powders or their mixtures, in the presence of an excess of H2O2, leads to novel complexes [Cu(L)-(O2 2−)]·3H2O, [Zn(L)(O 2−2 )]·H2O and [Cu,Zn(L)2(O 2−2 )2]· 4H2O, respectively, which were isolated and characterized by elemental and micro- analysis, e.s.r., electronic, i.r. and thermogravimetric analysis in air and argon.
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Sastry, M.S., Gupta, S.S. & Singh, A.J. Copper(II), zinc(II) and mixed metal copper(II)-zinc(II) peroxocomplexes containing 2,2′,6′,2″-terpyridine. Transition Met Chem 19, 421–425 (1994). https://doi.org/10.1007/BF00139319
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DOI: https://doi.org/10.1007/BF00139319