Summary
An i.r. study of Fe complexes prepared from salicylaldehyde benzoyl hydrazone and seven similar chelating agents allowed the assignment of some iron-ligand bands. The amide I and Φ—O band shifts indicate that the ligand O atoms are directly linked to Fe. The analogy between FeII and FeIII complexes in the mid-i.r. range and the chiefly identical frequencies in the far-i.r. range provide evidence that oxidation of FeIIhas occurred. The bands directly involved in complexation are shifted compared to the free hydrazones, and all are medium or weak.
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References
B. Modell and V. Berdoukas, The Clinical Approach to Thalassemia, Grune and Stratton, New York (1984).
P. Ponka, J. Borova, J. Neuwirt and O. Fuchs, FEBS Lett., 97, 317 (1979).
P. Ponka, J. Borova, J. Neuwirt, O. Fuchs and E. Necas, Biochim. Biophys. Acta, 586, 278 (1979).
A. Huang and P. Ponka, Biochim. Biophys. Acta, 757, 306 (1983).
P. Ponka, R. W. Grady, A. Wilczynska and H. M. Schulman, Biochim. Biophys. Acta, 802, 477 (1984).
P. Ponka, D. Richardson, E. Baker, H. M. Schulman and J. T. Edward, Biochim. Biophys. Acta, 967, 122 (1988).
C. Hershko, S. Avramovici-Grisaru, G. Link, L. Gelfand and S. Sarel, J. Lab. Clin. Med., 98, 99 (1981).
S. Avramovici-Grisaru, S. Sarel, S. Cohen and R. E. Bauminger, Isr. J. Chem., 25, 288 (1985).
J. E. Dubois, H. Fakhrayan, J. P. Doucet and J. M. El Hage Chahine, Inorg. Chem., 31, 853 (1992).
D. R. Richardson, L. M. Wis Vitolo, G. T. Hefter, P. M. May, B. W. Clare, J. Webb and P. Wilairat, Inorg. Chim. Acta, 170, 165 (1990).
L. M. Wis Vitolo, G. T. Hefter, B. W. Clare and J. Webb, Inorg. Chim. Acta, 170, 171 (1990).
T. B. Murphy, D. K. Johnson, N. J. Rose, A. Aruffo and V. Schomaker, Inorg. Chim. Acta, 66, L67 (1982).
A. A. Aruffo, T. B. Murphy, D. K. Johnson, N. J. Rose and V. Schomaker, Inorg. Chim. Acta, 67, L25 (1982).
A. A. Aruffo, T. B. Murphy, D. K. Johnson, N. J. Rose and V. Schomaker, Acta Crystallogr., C40, 1164 (1984).
T. B. Murphy, N. J. Rose, V. Schomaker and A. Aruffo, Inorg. Chim. Acta, 108, 183 (1985).
L. Pickart, W. H. Goodwim, T. B. Murphy and D. K. Johnson, J. Cell. Biochem. Suppl., 6, L482 (1982).
A. Lyubchova, A. Cossé-Barbi, J. P. Doucet, J. P. Souron, F. Robert and M. Quarton, Acta Crystallogr., in press.
C. Colonna, A. Massat, R. BenAbdelmoumène, A. Cossé-Barbi and J. P. Doucet, Bull. Soc. Chem. Belg., 102, 411 (1993).
C. Colonna, J. P. Doucet and A. Cossé-Barbi, Spectrosc. Lett., 27, 1153 (1994).
C. Colonna, A. Cossé-Barbi, A. Massat and J. P. Doucet, Spectrosc. Letters, 26, 1065 (1993).
J. R. Ferraro, Low-Frequency Vibrations of Inorganic and Coordination Compounds, Plenum Press, New York, 1971, p. 104.
P. Domiano, A. Musatti, M. Nardelli and C. Pelizzi, J. Chem. Soc., Dalton Trans., 295 (1975)
M. Nardelli, C. Pelizzi and G. Predieri, Transition Met. Chem., 3, 233 (1978).
D. Lin-Vien, N. B. Colthrup, W. G. Fateley and J. G. Grasselli, The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, Academic Press, San Diego (1991).
A. R. Katritzky, Quart. Rev. Chem. Soc., 13, 353 (1959).
C. Colonna, J. P. Doucet and A. Cossé-Barbi, Spectrochimica Acta, to be published.
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Colonna, C., Doucet, JP. & Cossé-Barbi, A. Infrared study of complexes between iron, salicylaldehyde benzoyl hydrazone and seven analogous derivatives. Transition Met Chem 20, 338–343 (1995). https://doi.org/10.1007/BF00139124
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DOI: https://doi.org/10.1007/BF00139124