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Synthesis and structure of palladium(II) mixed complexes with DNA purine or pyrimidine bases and imidazole derivatives. Part I

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Summary

Palladium(II) mixed ligand complexes with purine or pyrimidine and imidazole derivatives were prepared and characterized by i.r., Raman and electronic spectroscopy. The compounds have the general formula [Pd(L1)(L2)(X2)]; where L1 = adenine, guanine, hypoxanthine, cytosine, 2-aminopyrimidine, 4(6)-hydroxypyrimidine; L2 = N-methylimidazole, N-ethylimidazole or N-propylimidazole; X = Cl or Br. The complexes are square planar with cis-halogens. The purine, pyrimidine and imidazole bases act as monodentate ligands coordinated via the N(7) of purine and N(3) of pyrimidine and imidazole.

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Authors and Affiliations

  1. N.S. Kurnakov General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prospect 31, 117907, Moscow, Russia

    Inessa A. Efimenko & Anna P. Kurbakova

  2. Chemistry Department, Science Faculty, University of Kragujevac, Radoja Domanovića 12, 34000, Kragujevac, Yugoslavia, Serbia

    Zoran D. Matović

  3. Dipartimento di Chimica e Tecnologie Inorganiche e Metallorganiche, Universitá di Cagliari, Cagliari, Italy

    Gustavo Ponticelli

Authors
  1. Inessa A. Efimenko
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  2. Anna P. Kurbakova
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  3. Zoran D. Matović
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  4. Gustavo Ponticelli
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Efimenko, I.A., Kurbakova, A.P., Matović, Z.D. et al. Synthesis and structure of palladium(II) mixed complexes with DNA purine or pyrimidine bases and imidazole derivatives. Part I. Transition Met Chem 19, 539–541 (1994). https://doi.org/10.1007/BF00136370

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  • DOI: https://doi.org/10.1007/BF00136370

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