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Formate and acetate levels compared in monsoon and winter rainwater at Dayalbagh, Agra (India)

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Abstract

A total of 59 rainwater samples were collected during the winter and monsoon (1991–92) at Dayalbagh, Agra. This site is relatively free from the influence of anthropogenic emissions and the volume-weighted average concentrations (VWA) of formate in the winter and monsoon were 22.5±6, 16.1±3 while acetate VWAs were 17.1±5 and 13.8±3 μmol l-1, respectively. Although the VWAs varied between seasons, it was not statistically different. Total deposition (in mmol m-2) varied between season (winter formate, 1.4; acetate, 1.1; monsoon formate, 7.4; acetate, 6.4). A difference in VWA values may have occurred as a result of the dilution factor; the total rain depth from collected samples in the monsoon was 46 cm while that in winter was 6.3 cm. Sources at this site may be anthropogenic and natural; scavenging from the vapour phase, washout of soil particles and emissions from vegetative sources are probably important sources for formate and acetate.

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References

  • Andreae, M. O., Talbot, R. W., and Li, S. M., 1987, Atmospheric measurements of pyruvic and acetic acids, J. Geophys. Res. 92, 6635–6641.

    Google Scholar 

  • Andreae, M. O., Talbot, R. W., Andreae, T. W., and Harris, R. C., 1988, Formic and acetic acid over the central Amazon region, Brazil, J. Geophys. Res. 93, 1616–1624, 1988.

    Google Scholar 

  • AveryJr., G. B., Willey, J. D., and Wilson, C. A., 1991, Formic and acetic acids in rainwater of North Carolina, Environ. Sci. Technol. 25, 1875–1880.

    Google Scholar 

  • Calvert, J. G., Su, F., Bottenheim, J. W., and Strausz, O. P., 1978, Mechanism of the homogenous oxidation of sulphur dioxide in the troposphere, Atmos. Environ. 12, 197–226.

    Google Scholar 

  • Chameides, W. L. and Davis, D. D., 1983, Aqueous-phase source for formic acid in clouds, Nature 304, 427–429.

    Google Scholar 

  • Dawson, G. A., Farmer, J. C., and Moyers, J. L., 1980, Formic and acetic acids in the atmosphere of the southwest, USA, Geophys. Res. Lett. 7, 725–728.

    Google Scholar 

  • Durana, N., Casado, H., Garcia, C., Ezcurra, A., Lacaux, J. P., and Encinas, D., 1992, Organic acids in precipitation in the Basque country (North of Spain), Atmos. Res. 28, 93–101.

    Google Scholar 

  • Finlayson-Pitts, B. J. and PittsJr., J. N., 1986, Atmospheric Chemistry: Fundamentals and Experimental Techniques, Wiley, New York, 1098 pp.

    Google Scholar 

  • Kawamura, K., Ng, L. L., and Kaplan, I. R., 1985, Determination of organic acids (C1–C10) in the atmosphere motor exhaust and engine oils, Environ. Sci. Technol. 19, 1082–1086.

    Google Scholar 

  • Keene, W. C. and Galloway, J. N., 1988, The biogeochemical cycling of formic and acetic acids through the troposphere: an overview of current understanding, Tellus 40B, 322–334.

    Google Scholar 

  • Keene, W. C. and Galloway, J. N., 1986, Considerations regarding sources for formic and acetic acids in the troposphere, J. Geophys. Res. 91, 14,466–14,474.

    Google Scholar 

  • Keene, W. C. and Galloway, J. N., 1984, Organic acidity in precipitation of North America, Atmos. Environ. 18, 2491–2497.

    Google Scholar 

  • Keene, W. C., Galloway, J. N., and Holdren, D. D., 1983, Measurement of weak organic acidity from remote areas of the world, J. Geophys. Res. C 9, 5122–5130.

    Google Scholar 

  • Kumar, N., Kulshrestha, V. C., Saxena, A., Kumari, K. M., and Srivastava, S. S., 1993. Formate and acetate in monsoon rainwater of Agra, India, J. Geophys. Res. 98, 5135–5137.

    Google Scholar 

  • Likens, G. E. and Galloway, J. N., 1983, The composition and deposition of organic carbon in precipitation, Tellus 35B, 16–24.

    Google Scholar 

  • Madronich, S., Chatfield, R. B., Calvert, J. G., Moortgat, G. K., Veyret, B., and Lesclaux, R., 1990, A photochemical origin of acetic acid in the troposphere, Geophys. Res. Lett. 17, 2361–2364.

    Google Scholar 

  • Miller, R. L. and Kahn, J. S., 1962, Statistical Analysis in the Geological Sciences, Wiley, New York, 483 pp.

    Google Scholar 

  • Sakugawa, H. and Kaplan, I. R., 1993, Measurements of H2O2, aldehydes and organic acids in Los Angeles rainwater: Their sources and deposition rates, Atmos. Environ. 27B, 203–219.

    Google Scholar 

  • Sanhueza, E., Arias, M. C., Donoso, L., Graterol, N., Hermoso, M., Marti, I., Romero, J., Rondon, A., and Santana, M., 1992, Chemical composition of acid rains in the Venezuelan savannah region, Tellus 44B, 54–62.

    Google Scholar 

  • Schultz Tokos, J. J., Tanaka, S., Morikami, T., Shigetani, H., and Hashimoto, Y., 1992, Gaseous formic and acetic acids in the atmosphere of Yokohama, Japan, J. Atmos. Chem. 14, (1–4), 85–94.

    Google Scholar 

  • Talbot, R. W., Stein, K. M., Harriss, R. C., and CoferIII, W. R., 1988, Atmospheric geochemistry of formic and acetic acids at a mid-latitude temperate site, J. Geophys. Res. 93, 1638–1652.

    Google Scholar 

  • Talbot, R. W., Harriss, R. C., Browell, E. V., Gregory, G. L., Sebacher, D. I., and Beck, S. M., 1986, Distribution and geochemistry of aerosols in the tropical North Atlantic troposphere: Relations to Saharan dust, J. Geophys. Res. 91, 5173–5182.

    Google Scholar 

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Kumar, N., Kulshrestha, U.C., Saxena, A. et al. Formate and acetate levels compared in monsoon and winter rainwater at Dayalbagh, Agra (India). J Atmos Chem 23, 81–87 (1996). https://doi.org/10.1007/BF00058705

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  • DOI: https://doi.org/10.1007/BF00058705

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