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Measurements of N2O photolysis coefficients in the stratosphere: Comparison with model calculations

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Abstract

A balloon-borne continuous actinometer has been developed which measures stratospheric N2O photolysis coefficients, % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOAamaaBa% aaleaacaGGobWaaSbaaWqaaiaaikdaaeqaaSGaci4taiabg2da9iab% gkHiTiGacsgaciGGSbGaaiOBaiaacIcaciGGobWaaSbaaWqaaiaaik% daaeqaaSGaci4taiGacMcacaGGVaGaciizaiaadshaaeqaaaaa!44F2!\[j_{N_2 \operatorname{O} = - \operatorname{d} \ln (\operatorname{N} _2 \operatorname{O} )/\operatorname{d} t} \], with a time resolution of approximately 100 s, and a lower detection limit approaching 10-10 s-1. The instrument performed successfully, or was at least partially successful, on five stratospheric balloon flights between October 1982 and September 1986. The experimental profiles are compared with model calculations of % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOAamaaBa% aaleaacaGGobWaaSbaaWqaaiaaikdaaeqaaSGaci4taaqabaaaaa!39A3!\[j_{N_2 \operatorname{O} } \]. The model takes full account of the sphericity of the atmosphere and of the specific flight conditions, but neglects scattering, which should have a negligible effect on % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOAamaaBa% aaleaacaGGobWaaSbaaWqaaiaaikdaaeqaaSGaci4taaqabaaaaa!39A3!\[j_{N_2 \operatorname{O} } \]. The quantitative results, particularly the altitude and solar zenith angle dependences under extreme conditions, support the low absorption cross-sections of oxygen in the Herzberg continuum as recommended by WMO in 1986 and are inconsistent with Ackerman's tabulations of 1971. It is shown that the altitude dependence of Brewer and Wilson's historical irradiance measurements in the stratospheric window region is well reproduced by our model, but should be multiplied by a factor of 1.75.

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  1. Chemie der Universität Bonn, Wegelerstr. 12, D-5300, Bonn 1, F.R.G.

    D. Marić, W. Hans & U. Schurath

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  1. D. Marić
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Marić, D., Hans, W. & Schurath, U. Measurements of N2O photolysis coefficients in the stratosphere: Comparison with model calculations. J Atmos Chem 8, 19–40 (1989). https://doi.org/10.1007/BF00053814

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