Abstract
Carbonaceous particles produced by fossil fuel combustion can be found in considerable amounts in recent lake sediments. As these particles contain elemental carbon they are resistant to chemical decomposition and therefore both well preserved in sediments and possible to quantify. Sediment samples can be oxidized with H2O2 and digested with HF without the particles being destroyed. The pioneers in studying carbonaceous particles in lake sediments in relation to fossil fuel combustion were J. J. Griffin and E. D. Goldberg. They measured elemental carbon concentrations in Lake Michigan sediments, mainly by infrared assay. On the basis of these analyses, size distribution measurements and also morphological studies of single particles they concluded that the carbonaceous particle record reflected the onset of industrial activity and the increased intensities of fossil fuel combustion during the twentieth century. Similar results have been obtained from another lake in the USA by B. K. Kothari and M. Wahlen. We have counted spherical carbonaceous particles (larger than 5–10 µm), which are characteristic for oil and coal burning, in several lake sediments. In Swedish lakes, the annual accumulation of coarse carbonaceous spheres in varved sediments and the concentration stratigraphy in non-varved sediments, follow the same main pattern as statistical data for the Swedish coal and oil combustion over the last two centuries. Coarse carbonaceous spheres in two sediment profiles from Scottish lakes have also been counted. As for the USA and Sweden the sedimentary record was found to reflect the history of fossil fuel combustion.
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References
Alderton, D. H. M., 1985. Sediments. In Historical monitoring, MARC Report 31. Monitoring and Assessment Research Centre, University of London: 1–95.
Bacci, P., M. Del Monte, A. Longhetto, A. Piano, F. Prodi, P. Redaelli, C. Sabbioni & A. Ventura, 1983. Characterization of the particulate emission by a large oil fuel fired power plant. J. Aerosol Sci. 14: 557–572.
Battarbee, R. W., 1984. Diatom analysis and the acidification of lakes. Phil. Trans. r. Soc., Lond. B 305: 451–477.
Battarbee, R. W., et al. (in prep.)
Brosset, C. & A. Nyberg, 1971. Investigations of soot and particle-borne sulfur in Sweden. In H. M. Englund & W. T. Beery (eds), Proceedings of the Second International Clear Air Congress. Academic Press, New York: 481–489.
Cheng, R. J., V. A. Mohnen, T. T. Shen, M. Current & J. B. Hudson, 1976. Characterization of particulates from power plants. J. Air Pollut. Cont. Ass. 26: 787–790.
Darley, J., 1985. Particulate soot in Galloway lake sediments: its application as an indicator of environmental change and as a technique for dating recent sediments. Department of Geography, University College London, B 301 Project: 1–46.
Del Monte, M., C. Sabbioni, A. Ventura & G. Zappia, 1984. Crystal growth from carbonaceous particles. Sci. Total Envir. 36: 247–254.
Doyle, L. J., T. L. Hopkins & P. R. Betzer, 1976. Black magnetic spherule fallout in the eastern Gulf of Mexico. Science 194: 1157–1159.
Ericson, S.-O., M. Skaar, J. Tollin & T. Åbyhammar, 1983. Rening av rökgaser från koleldade anläggningar. Projekt Kol-Hälsa-Miljö, Teknisk Rapport 57: 1–371.
Flower, R. J., R. W. Battarbee & P. G. Appelby, in press. J. Ecol.
Goldberg, E. D., V. F. Hodge, J. J. Griffin & M. Koide, 1981. Impact of fossil fuel combustion on the sediments of Lake Michigan. Envir. Sci. Technol. 15: 446–471.
Goldstein, H. L. & C. W. Siegmund, 1976. Influence of heavy fuel oil composition and boiler combustion conditions on particulate emissions. Envir. Sci. Technol. 10: 1109–1114.
Griest, W. H. & B. A. Tomkins, 1984. Carbonaceous particles in coal combustion stack ash and their interaction with polycyclic aromatic hydrocarbons. Sci. Total Envir. 36: 209–214.
Griffin, J. J. & E. D. Goldberg, 1979. Morphologies and origin of elemental carbon in the environment. Science 206: 563–565.
Griffin, J. J. & E. D. Goldberg, 1981. Sphericity as a characteristic of solids from fossil fuel burning in a Lake Michigan sediment Geochim. Cosmochim. Acta 45: 763–769.
Griffin, J. J. & E. D. Goldberg, 1983. Impact of fossil fuel combustion on sediments of Lake Michigan: a reprise. Envir. Sci. Technol. 17: 244–245.
Haynes, B. S. & H. G. Wagner, 1981. Soot formation. Prog. Energy Combust. Sci. 7: 229–273.
Holdren, G. R. Jr., T. M. Brunelle, G. Matisoff & M. Wahlen, 1984. Timing the increase in atmospheric sulphur deposition in the Adirondack Mountains. Nature 311: 245–248.
Kahl, J. S. & S. A. Norton, 1983. Metal input and mobilisation in two acid-stressed lake watersheds in Maine. Land and Water Resources Center, University of Maine at Orono, Completion Report Project A-053-Me: 1–70.
Kothari, B. K. & M. Wahlen, 1984. Concentration and surface morphology of charcoal particles in sediments of Green Lake, N.Y: implications regarding the use of energy in the past. Northeastern Environ. Sci. 3: 24–29.
Lindskog, A. & E. Brorström, 1981. Determination of polycyclic aromatic hydrocarbons in airborne particulate matter in Göteborg. Nordic PAH Project, Report 11: 1–15.
McCrone, W. G. & J. G. Delly, 1973. The Particle Atlas, II. Ann Arbor Science, Ann Arbor, 267 pp.
Ogren, J. A. & R. J. Charlson, 1984. Elemental carbon in the atmosphere: cycle and lifetime. Tellus 35B: 241–254.
Ogren, J. A. & R. J. Charlson, 1984. Wet deposition of elemental carbon and sulfate in Sweden. Tellus 36B: 262–271.
Oldfield, F., C. Barnosky, E. B. Leopold & J. P. Smith, 1983. Mineral magnetic studies of lake sediments: A brief review. Hydrobiologia 103: 37–44.
Oldfield, F., J. Bloemendal, L. Barker, A. Hunt, J. M. Jones, M. H. D. Jones, R. Maxted, N. Richardson, J. Sahota & K. Tolonen, 1984. Magnetic measurements of atmospheric particulates and ombrotrophic peat: a review. In S. A. Norton (ed.), Proceedings of a Workshop on Paleolimnological Studies of the History and Effects of Acid Precipitation. University of Maine at Orono: 409–441.
Peterson, K. F., 1972. Stoftbildning vid oljeeldning. Dr Thesis, The Royal Institute of Technology: 1–229.
Renberg, I., 1984. Förbränning och försurning går hand i hand. Forskning och Framsteg 4/84: 36–40.
Renberg, I. & M. Wik, 1985a. Carbonaceous particles in lake sediments-pollutants from fossil fuel combustion. Ambio 14: 161–163.
Renberg, I. & M. Wik, 1985b. Soot particle counting in recent lake sediments; an indirect dating method. Ecol. Bull. 37: 53–57.
Rosen, H., T. Novakov & B. A. Bodhaine, 1981. Soot in the Artic. Atmos. Environ. 15: 1371–1374.
Schure, M. R., P. A. Soltys, D. F. S. Natusch & T. Mauney, 1985. Surface area and porosity of coal fly ash. Envir. Sci. Technol. 19: 82–86.
Shen, T., R. J. Cheng, V. A. Mohnen, M. Current & J. B. Hudson, 1977. Characterization of differences between oil-fired and coal-fired power plant emissions. International Clean Air Congress, 4. Tokyo: 386–391.
Smith, D. M., J. J. Griffin & E. D. Goldberg, 1975. Spectrometric method for the quantitative determination of elemental carbon. Analyt. Chem. 47: 233–238.
Tolonen, K., 1986. Charred particle analysis. In B. E. Berglund (ed.), Handbook of Holocene Palaeoecology and Palaeohydrology. John Wiley & Sons Ltd., Chichester: 485–496.
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Wik, M., Renberg, I. & Darley, J. Sedimentary records of carbonaceous particles from fossil fuel combustion. Hydrobiologia 143, 387–394 (1986). https://doi.org/10.1007/BF00026687
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DOI: https://doi.org/10.1007/BF00026687