Abstract
The deposit volume of steel slag in China exceeds 400 million tons, leading to the occupation of a large area of land and serious environment pollution. However, the current utilization rate of steel slag in China is only about 21%, which is far behind that of developed countries. Recycling and reusing these solid wastes are essential, not only for conserving metals and mineral resources but also for protecting the environment. The physical and chemical characteristics of steel slag are summarized, and the pretreatment progress of steel slag in steel industries as recycled raw material was introduced. The utilization aspects (circulation in metallurgical industry, cement additive and concrete admixture, materials for wastewater or gas treatment, construction materials, and fertilizer in agriculture production, and raw materials of glass and ceramics) are introduced.
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References
Zhao P (1999) Iron and steel energy saving technology analysis. Metallurgical Industry Press, Beijing
China Iron and Steel Application Association Metallurgical Slag Development and Utilization Working Committee (2016) 2015 iron and steel slag comprehensive utilization of the basic situation. China scrap steel (1):21
Xie J (2013) Research on the Preparation, Performance and Application of Basic Oxygen Furnace Slag Based Asphalt Concrete. Dissertation, Wuhan University of Technology
Zhao QL, Zhou MK, Wei M (2006) Iron and Steel Slags in German and Its Comprehensive Use. Bulletin of the Chinese Ceramic Society 25(6):165–171
Zhang ZH, Jiao ZY, Ju JT et al (2011) Analysis of Physicochemical and Mineralogical Properties of Converter Slag. Iron and Steel 46(21):76–80
Zhang YZ, Lei YB, Li JG et al (2011) Analysis of mineralogical composition in steel slag and its microstructure. Metallurgical Analysis 31(9):11–17
Yin SH, Guo H, Yu Q et al (2013) Steel slag reconstruction experiment by reduction FeOx and its mineral composition. Journal of the Chinese Ceramic Society 41(7):966–971
Zhang LL, Chen YH, Wei ZY et al (2014) Analysis of mineralogical phase and distribution of iron in converter slag. China Building Materials Science & Technology 23(5):97–99
Gong CC, Yu QJ, Wei JX, Li JX, Zhong G, Guo H (2010) Composition and Effectiveness of Activating Converter Steel Slag with Electric Furnace Slag. Journal of wuhan university of technology 32(14):1–5
Liu ZW, Li Y, Cang DQ (2003) Experimental research on efficient utilization of whole components in EAF oxidizing slag. Journal of wuhan university of technology 36(5):32–330
Essia B, Cécile D, André L (2012) Characterization and activation of Basic Oxygen Furnace slag. Cement and Concrete Composites 34:34–40
Ouyang D, XieYP, He JY (1991) Composition, mineral morphology and cementitiouspropeties of converter slag. Journal of the Chinese Ceramic Society 19(6):488–494
Hou GH, Guo W, Chen JH et al (2008) Microstructure and mineral phase of converter slag. Journal of the Chinese Ceramic Society 36(4):436–443
Hou XK, He N, Yuan JS, Dong YB et al (2013) Separation of Divalent Metal Oxides Solid Solution from Steel Slag. Journal of the Chinese Ceramic Society 41(8):1142–1150
Huang Y, Xu GP, Cheng HG et al (2014) Analysis on Chemical Composition,Micro-morphologyand Phase of Typical Steel Slag. Bulletin of the Chinese Ceramic Society 33(8):1902–1907
Zhang CH, Li LB, Wei WQ et al (2011) Comprehensive utilization of Metallurgical Resources. Metallurgical Industry Press, pp 106–107
Xu GP, Huang Y (2015) Research on f-CaO Content and Volume Stability of Typical Steel Slag. Industrial Safety and Environmental Protection 41(4):94–96
Li B, Jiang JH, Sui ZT (1997) Study on compositions and cementing property of steel slag. Building Energy Efficiency 4(35):4–5
Sun SB, Zhu GL et al (2007) The present situation of China’s steel processing and utilization and the way of “zero discharge” China scrap steel 2:21–28
Li X, Hu JX, Li D (2011) Technical Characteristic and Application of Steel Slag Treatment Processes. Gansu Metallurgy 33(6):44–48
Zeng JM, Cui HY, Xiang H (2008) Development of steel slag treatment technology. Nanjing, Jiangsu Metallurgy 36(6):12–14
Zhang L, Wang F, Chen X (2006) Development and utilization of iron and steel slag resources. China scrap steel 1:42–44
Li LS (2011) Historical evolution and a vista of trend of converter slag recycling in future. World Iron & Steel 4:62–67
Zhang D (2012) The technology of steel slag hot pressing, crushing, magnetic separation and reuse. China steel 2:28–30
Xie CX, Lin PF (2011) Upgrading of the slag hot closed pot. Southern Metals 178(1):56–60
Zhang RP (2013) Production Practice of BX steelslag and fever treatment process. Bengang Technology 2:5–8
Xia JS, Sun HL, Liu JX et al (2009) Development and application of converter steel slag hot stifle technology in Jigang. Industrial Safety and Environmental Protection 35(3):45–46
Zhu GL, Sun SB (2005) The development of recycling economy, scientific selection of steel slag treatment technology and comprehensive utilization of steel slag to achieve “zero” emissions. Baiyin, China scrap steel (6):10–15
Chai YF, Peng J, An SL (2012) Overview on steel slag comprehensive utilization and steel slag hot stuffy technology. Journal of Inner Mongolia University of Science and Technology 30(3):250–253
Jin Q, Xu JY, Gao WB (2005) New technology of steel slag processing and its application as the second resource at baosteel. Baosteel Technology. 3:12–15
Zeng J, Li LS, Su SH et al (2006) The study about magnetic separation of LD slag. China Resources Comprehensive Utilization 9:33–35
Wang SQ, Luo L, Li CB et al (2000) Recovery of iron from steel slag by mineral processing. Nonferrous Metals (Mineral Processing Section) 4:26–30
Feng HD, Li X, Xu L et al (2011) Separation feature of iron-containing minerals during wet magnetic separation process. Industrial Heating 40(5):62–64
Wei Y, Lu D, Li ZF et al (2009) The research on comprehensive utilization of steel slag bymagnetic separation. Bulletin of the Chinese Ceramic Society 28(1):152–155
Fan YP, Wang S, Wang YB (2012) The effect of occurrence characteristics of mangerals in slag on sorting performance. Environmental Engineering 30(2):82–84
Lu YJ, Ye C (2012) The beneficiation process design and production practice of steel slag magnetic separation in kunming Iron & Steel. Yunnan Metallurgy 41(2):41–44
Wang DY, Li Y, Liu J (2011) A new design of Fe and P simultaneous recovery from steel slag. China Metallurgy 21(8):50–53
Fan J, Zhang Y, Li N et al (2012) Study on magnetic separation technology and equipment of converter steel slag. China Steel 12:26–29
Yang ZJ, Cang DQ, Guo WB et al (2011) Effect of basicity on extracting iron from converter slag by smelting reduction. Energy for Metallurgical Industry 30(4):51–56
Yang Y (2010) Study on thermodynamics of FeOx deoxidization, Fe recycled from steel slag and properties of residue. Dissertation, South China University of Technology
Jia JR, Ai LQ (2012) Reduction dephosphorization behavior of steelmaking slag in microwave heating field. Iron and Steel 47(8):70–73
Zhou CG, Ai LQ, Lv Y et al (2011) The influence of temperature characteristic of steel slag for microwave heating. Journal of North China University of Science and Technology (Natural Science Edition) 33(3):25–30
Zhang XF, Li BW, Jia XL et al (2013) Magnetic separator and magnetic separation method for reducing hematite mineral material by microwave. Beijing, Chinese Patent, 103447148A, 18 December. 2013
Wei ZY, Chen YH, Jiang L et al (2016) Experimental research on microwave reduction of slag by high-carbon fly-ash. Bulletin of the Chinese Ceramic Society 35(4):1062–1066
Semykina A, Shatokha V, Iwase M et al (2010) Kinetics of oxidation of divalent iron to trivalent state in liquid FeO–CaO–SiO2 slags. State of California Metallurgical and materials transactions B 41(6):1230–1239
Semykina A, Nakano J, Sridhar S, et al (2011) Confocal scanning laser microscopy studies of crystal growth during oxidation of a liquid FeO–CaO–SiO2 slag, Ohio The Minerals, Metals & Materials Society and ASM International B 42(3):471–476.
Wang C, Yang J (2012) Development and present situation of high value utilization technology of iron and steel slag. China scrap steel 1:42–53
Han FG et al (2006) Influence of basicity on sinter strength and sintering process of vanadium-titanium magnetite. Sintering and Pelletizing 31(5):15–18
Jin ZG (2011) Design practice of producing green cement with steel slag. Paper reported on 11 provinces and cities of China Silicate development conference. Jinan, 29–30 March. 2011
Wen M, Zhou YH, Li B (2012) Study on the comprehensive utilization of steel slag in Chongqing area. Paper presented at National steelmaking continuous casting production technology conference, pp 955–957, Chinese Society for Metals. Chongqing 17–20, July,2012
Zhang G (2006) Status of comprehensive utilization of steel slag at baostee. Baosteel Technology 6:18–22
Zhou XW, Li JM (2006) Comprehensive utilization of meterllurgical slag in the liangang. China scrap steel 6:16–18
Su XW, Yang LH, Cui JX et al (2009) Recycle utilization of metallurgy slag-replacement for converter flux with LF refining slag. China scraps stee l3:61–63
Jin ZG, Shi NF, Yang SM (2011) Production practice of sintering steel slag in Handan Iron and Steel Co. Paper presented at Collection of steelmaking technology and academic conference, Hebei, pp 111–113. Herbei Society of metallgy, Xintai, 8–9 September, 2011
Wu WW, Yang SR (2009) Research progress on hydraulic activity of steel slag and its application in cement and concrete. Fly Ash Comprehensive Utilization 6:51–54
Xu Q, Xu YF, Gao QY (1993) Study on the production of 425# steel slag road cement with steel slag. Cement 2: 1–4
Li ZL, Li BS, Lü JF (2016) Current status and innovation of steel slag processing technology and equipment. Mining & Processing Equipment 44(2):1–6
Li BX, Wang YF, Zhong M (2016) Practice of producing superfine steel slag powder by ball milling double closed circuit process. Cement Engineering 4:33–36
Yuan FY, Qiong HJ, Zhang ZY et al (2013) Practice and analysis of HRM steel slag vertical mill grinding. China Cement 9:82–85
Shi GP, Chai XT, Xu F (2006) Slag Powder Production By Roller Press Combined Grinding. Cement Technology 43(5):17–22
Zhao X, Chen KM, Wang JD (2011) Application of KHM type horizontal roller mill in steel slag grinding system. Paper presented at 2011 Annual Meeting of China cement technology and the Thirteenth National Conference on Cement Technology,pp 96–101. Chinese Society of Silicate Yichang, 26–29 October 2011
Chen XY (2011) Research on Slag Pulverizing Process Technology. CFHI Technology, 1:1–5
Luo F (2015) Grinding test of steel slag and analysis of its influencing factors. Cement 5:19–23
Hou G, Li WF, Wang JG (2009) Difference of grindability and cementitious performance among minerals in steel slag. Journal of the Chinese Ceramic Society 37(10):1613–1617
Zhao SY, Li WS, Lin YQ et al (2006) Trial study on grinding dynamics coverter of steel slag. Cement Engineering 2:5–8
Feng CH, Li DX, Miao C et al (2010) Effects of grinding aids on activation and fineness of steel slag. Journal of the Chinese Ceramic Society 38(7):1160–1166
Li WF, Ma SH, Zheng JL et al (2012) Effect of grinding aids on grinding and performance of steel slag. Concrete 4:34–35
Liu S, Li CH (2011) Experimental study on selectivity of grinding aids for steel slag. Wuhan Iron and Steel Corporation Technology 49(1):18–20
Chen Z, Li Q, Tao D et al (2011) Study on the Effect of Steel Slag Grinding Aids. Fly Ash Comprehensive Utilization 2:3–6
Li YX (2003) Study on Composition, Structure and Properties of Cement and Concrete with Steel-making Slag Powder Mineral Additive. Dissertation, China Building Materials Academy
Yi LS, Wen J, Wang Z et al (2013) Influences of the particle size distribution on the cementing properties of steel slag cement. Metal Mine 6:165–167
Shang JL, Xu XD (2015) Analysis on activation kinetics mechanism of steel slag by asorption. Bulletin of the Chinese Ceramic Society 34(1):79–83
Hu SG, Wei JX, Ding QJ (2001) Research on excitation principle of sodium silicate to steel slag cement. Cement Engineering 5:1–6
Han FH, Zhang ZQ, Yan PY (2014) Early hydration properties of steel slag under high alkalinity. Journal of Chinese Electron Microscopy Society 33(4):343–348
Ding Z, Wang SP, Zhang M et al (2008) Study on the activation of steel slag, Create Living 4:48–51
Feng CH, Dou Y, Li DX (2011) Steel slag used as admixture in composite cement. Journal of Nanjing Tech University (Natural Science Edition) 33(1):7–79
Yan PY, Wang Q (2009) Effect of high temperature curing on the early hydration characteristics of a complex binder containing steel slag. Journal of Tsinghua University (Natural science edition)49(6):774–777
Guan SB (2008) Research on active&cementitious capacity of steel-making slag and its concrete properties. Dissertation, Wuhan University of Technology
Guo H, Yin SH, Yu QJ et al (2016) Reconstructing steel slag based on the chemical compositions of cement clinker. Journal of the Chinese Ceramic Society 33(3):819–823
Li JX (2010) Effect of modification at high temperature on the composition, structure and property of steel slag. Dissertation, South China University of Technology
Hu TL, Yang JL, Zhu GL et al (2013) Research of chemical composition and cementitiousproperties of remelt and modified steel slag. China scrap stee l4:19–21
Hao HJ, Yu QJ, Wei JX et al (2010) Study on improvement of steel slag property with fly ash added at high temperature. Bulletin of the Chinese Ceramic Society 29(3):572–576
Zhang ZS, Lian F, Liao HQ et al (2012) Modifying the properties of steel slag by iron tailings at high temperature. Journal of University of Science and Technology Beijing 34(12):1079–1084
Li CH, Liu S, Chen L (2011) Study on steel slag used as AC-10I type fine aggregate of asphalt concrete. Wuhan Iron and Steel Corporation Technology 3:34–36
Liu GW, Zhu LJ, Jin Q (2016) Research Progress of Steel Slag Asphalt Concrete, Multipurpose Utilization of Mineral Resource 2:11–16
Yang YL, Wu JM, Hang JQ (2016) Research on mix design and pavement performance of SMA-13asphalt mixture with steel slag. Road Machinery & Construction Mechanization 7:36–40
Yang D, Zhang YL, Liu MD et al (2008) Silicon liberation characteristics of soil and its effect factors after applying slag mucks II relationship between silicon liberation and pH. Chinese Journal of Soil Science 6:32–36
Wu ZH, Zou ZS, Wang CZ (2005) Reutilization of converter steel slag in agricultural production. Multipurpose Utilization of Mineral Resources 6:25–28
Ning DF, Liang YC (2015) Si-releasing character of slag-based silicon fertilizer and impact factors. Journal of Plant Nutrition and Fertilizer 21(2):500–508
Hua XZ, Cheng B, Zhao RF et al (2015) Effect of steel slag application on onion production in farmland. Journal of Shanxi Agricultural Sciences 43(3):293–296
Liu HY (2010) Steel slag is the optimum additive for FCMP. Phosphate & Compound Fertilizer 4:77–75
Xiao HN, Deng CM, Peng WQ (2001) Effects of processing conditions on the microstructures of glass-ceramics prepared from iron and steel slag. Journal of Hunan University 28(1):32–35
Zhao GZ, Li Y, Dai WB et al (2014) Preparation mechanism of glass-ceramics based on steel slag using one-step sintering process. Bulletin of the Chinese Ceramic Society 33(12):3288–3294
Xiong HH, Guo WB (2015) Influence of crystallization temperature and forming pressure on property of glass-ceramics based steel slag. Bulletin of the Chinese Ceramic Society 34(1):222–226
Wang W, Dong HQ, Wang B et al (2014) Sintering mechanism of ceramics prepared from BOF slag. Journal CIESC 65(9):3732–3737
Wang W, Wang KZ, Dong HQ et al (2014) Effect of steel slag powder with different contents on properties of ceramic floor tile. Chinese Journal of Environmental Engineering 8(10):4463–4467
Zhao LH, Cang DQ, Liu P et al (2011) Preparation and microstructure analysis of CaO-MgO-SiO2 steel-slag ceramics. Journal of University of Science and Technology Beijing 33(8):995–1000
Ai XB, Li Y, Guo DL et al (2015) Sintering mechanism of SiO2-CaO-Al2O3 ceramic from steel slag. Journal of central south university ( natural science edition ) 46(5):1583–1587
Zhang YF, Jiang DY, Zhang ZY (2016) Application of steel slag in the treatment of industrial wastewater. Ningbo Chemical Industry 1:1–6
Zheng LS, Wang SL, Liu H (1999) Treating wastewater which contains chromium with slag. Materials Protection 5:40–43
Cheng FQ, Gao R, Song HP (2011) Treatment of low concentration ammonia nitrogenwastewater with modified steel slag. Chinese Journal of Environmental Engineering 6(11):4028–4033.
Wei LH, Li JG, Zhang YZ (2012) Review on pollutants removal from wastewater by steel slag. Environmental Science & Technology 35(2):73–78
Yu J, Gao K, Wang L et al (2012) Study on phosphorus adsorption from wastewater by steel slag powder. Environmental Engineering 30:40
Song JM (2008) Discussion on feasibility of adsorbing carbon dioxide by steelmaking slag. Environmental Engineering 28(S):241–247
Yi YR, Han MF (2013) Study on Reaction Mechanism of CO2 Capture by Wet Steel Slag. Environmental Science & Technology 36(6):159–163
Wang S, Yue CS, Chen Y et al (2016) Reserch Process and Review on Steel Slag carbonation used for CO2 Emission Reduction. Materials Review 30(1):111–114
Chang EE, Pan SY, Chen YH et al (2012) Accelerated carbonation of steelmaking slags in a high gravity ratating packed bed. Journal hazard materials 97:227–228
Wang CY, Bao WJ, Xu DH et al (2016) Reaction characteristics of steelmaking slag carbonation in dilute alkali medium. Iron & Stee l51(6):87–93
Chen W, Dong S, Gu HX et al (2016) Study on SO2 removal efficiency of steel slag powder based on wet flue gas desulphurization. Environmental Engineering 34:557–559
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Han, F., Wu, L. (2019). Comprehensive Utilization Technology of Steel Slag. In: Industrial Solid Waste Recycling in Western China. Springer, Singapore. https://doi.org/10.1007/978-981-13-8086-0_6
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