Skip to main content

Recent Trends of the Use of Rare Earth Elements for Efficient Environmentally Compliant Corrosion Protection of Aluminum and Its Alloys

  • Conference paper
  • First Online:
Nanoscience and Nanotechnology in Security and Protection against CBRN Threats

Abstract

Aluminum and its alloys find various applications in both mass production and hi-tech industrial sectors. This metal is widely used in the form of both low and high-doped alloys. The low-doped Al-alloys are generally used for household and hi-tech applications since they do not possess satisfactory mechanical strength related properties. The extended mechanical properties of the high-doped alloys enable their use as construction materials for the aircraft and automotive industries, for marine transport, as well as for exterior and interior architectonic constructions. However, reliable long-term exploitation of the Al-based facilities and equipment is strongly restricted due to their aptitude to undergo corrosion, especially in neutral or alkaline media with dissolved O22− and Cl ions. Recently, cerium compounds were found to be efficient environmentally friendly corrosion inhibitors and protective primer layers. In this sense, the present brief review aims to comprise the recent trends in the field of cerium compounds use for the elaboration of advanced corrosion protective coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Rodič P, Milošev I (2016) Corrosion inhibition of pure Aluminium and alloys AA2024-T3 and AA7075-T6 by cerium(III) and cerium(IV) salts. J Electrochem Soc 163:C85–C93

    Google Scholar 

  2. Bethencourt M, Botana FJ, Calvino JJ, Marcos M, Rodriguez-Chacon MA (1998) Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review. Corros Sci 40:1803–1819

    Google Scholar 

  3. Zivkovic LS, Popic JS, Jegdic BV, Dohcevic-Mitrovuic Z, Bajat JB, Stankovic VBM (2014) Corrosion study of ceria coatings on AA6060 aluminum alloy obtained by cathodic electrodeposition: effect of deposition potential. Surf Coat Technol 240:327–335

    Google Scholar 

  4. Cotting F, Aoki I (2016) Smart protection provided by epoxy clear coating doped with polystyrene microcapsules containing silanol and Ce (III) ions as corrosion inhibitors. Surf Coat Technol 303:310–317

    Google Scholar 

  5. Figueira RB, Fontinha IR, Silva CJR, Pereira EV (2016) Hybrid sol-gel coatings: smart and green materials for corrosion mitigation. Coatings 6(12):1–19

    Google Scholar 

  6. Kozhukharov SV (2017) Chapter 10: advanced multifunctional corrosion protective coating systems for light-weight aircraft alloys – actual trends and challenges. In: Thirumalai J (ed) Thin film processes – artifacts on surface phenomena and technological facets. Intech Open, London, pp 179–210

    Google Scholar 

  7. Presuel-Moreno F, Jakab MA, Tailleart N, Goldman M, Scully JR (2008) Corrosion-resistant metallic coatings, mater. Today 11:11–23

    Google Scholar 

  8. Kozhukharov SV, Girginov CA Chapter 1: classical and modern methods for corrosion impact rate determination for aluminium and strengthened aircraft alloys. Fundamentals and practical applications. In: Gergely A (ed) Phenomena and theories in corrosion science, Methods of prevention. NOVA Sci. Publ, Hauppauge, pp 3–150

    Google Scholar 

  9. Scholes FH, Soste C, Huges AE, Hardin SG, Curtis PR (2006) The role of hydrogen peroxide in the deposition of cerium-based conversion coatings. Appl Surf Sci 253:1770–1780

    ADS  Google Scholar 

  10. Aldykiewicz AJ, Davenport AJ, Isaacs HS (1996) Studies of the formation of cerium-rich protective films using X-ray absorption near-edge spectroscopy and rotating disk electrode methods. J Electrochem Soc 143:147–154

    Google Scholar 

  11. Matter EA, Kozhukharov S, Machkova M, Kozhukharov V (2012) Comparison between the inhibition efficiencies of Ce(III) and Ce(IV) ammonium nitrates against corrosion of AA2024 aluminum alloy in solutions of low chloride concentration. Corros Sci 62:22–33

    Google Scholar 

  12. Pernas JE, Kozhukharov S, Salve AA, Matter E, Machkova M (2012) A Comparative research on hybrid nano-composite protective primary coatings for AA2024 aircraft alloy. J Univ Chem Technol Metall 47(3):311–318

    Google Scholar 

  13. Machkova M, Matter EA, Kozhukharov S, Kozhukharov V (2013) Effect of the anionic part of various Ce(III) salts on the corrosion inhibition efficiency of AA2024 aluminium alloy. Corros Sci 69:396–405

    Google Scholar 

  14. Coelho LB, Taryba M, Alves M, Noirfalise X, Montemor MF, Olivier M-G (2019) The corrosion inhibition mechanisms of Ce(III) ions and triethanolamine on graphite—AA2024-T3 galvanic couples revealed by localised electrochemical techniques. Corros Sci 150:207–217

    Google Scholar 

  15. Coelho LB, Mouanga M, Druart M-E, Recloux I, Cossement D, Olivier M-G (2016) A SVET study of the inhibitive effects of benzotriazole and cerium chloride solely and combined on an aluminium/copper galvanic coupling model. Corros Sci 110:143–156

    Google Scholar 

  16. Liu J, Wang D, Gao L, Zhang D (2016) Synergism between cerium nitrate and sodium dodecylbenzenesulfonate on corrosion of AA5052 aluminium alloy in 3 wt.% NaCl solution. Appl Surf Sci 389:369–377

    ADS  Google Scholar 

  17. Zhu C, Yang HX, Wang YZ, Zhang DQ, Chen Y, Gao LX (2019) Synergistic effect between glutamic acid and rare earth cerium (III) as corrosion inhibitors on AA5052 aluminum alloy in neutral chloride medium. Ionics 25:1395–1406

    Google Scholar 

  18. Udoh II, Shi H, Liu F, Han E-H (2020) Microcontainer-based waterborne epoxy coatings for AA2024-T3: effect of nature and number of polyelectrolyte multilayers on active protection performance. Mater Chem Phys 241:. 122404:1–15

    Google Scholar 

  19. Nnaji N, Nwaji N, Fomo G, Mack J, Nyokong T (2019) Corrosion resistance of aluminum against AcidActivation: impact of Benzothiazole-substituted gallium Phthalocyanine. Electrocatalysis 24:. pp. 207:1–22

    Google Scholar 

  20. Shehu NU, Gaya UI, Muhammad AA (2019) Influence of side chain on the inhibition of aluminium corrosion in HCl by α-amino acids. Appl Sci Eng Prog 12(3):186–197

    Google Scholar 

  21. Coelho LB, Cossement D, Olivier M-G (2018) Benzotriazole and cerium chloride as corrosion inhibitors for AA2024-T3: an EIS investigation supported by SVET and ToF-SIMS analysis. Corros Sci 130:177–189

    Google Scholar 

  22. Hu T, Shi H, Wei T, Liu F, Fan S, Han E-H (2015) Cerium tartrate as a corrosion inhibitor for AA 2024-T3. Corros Sci 95:152–161

    Google Scholar 

  23. Zheng T, Wang L, Liu J (2020) Corrosion inhibition of levofloxacin and Ce(NO3)3 for AA2024-T4 in 3.5% NaCl, Corros. Eng. Sci. Technol 55(1):75–82

    Google Scholar 

  24. Rodič P, Milošev I (2019) The influence of additional salts on corrosion inhibition by cerium(III) acetate in the protection of AA7075-T6 in chloride solution. Corros Sci 149:108–122

    Google Scholar 

  25. Rodič P, Milošev I, Lekka M, Andreatta F, Fedrizzi L (2019) Study of the synergistic effect of cerium acetate and sodium sulphate on the corrosion inhibition of AA2024-T3, Electrochim. Acta 308:337–349

    Google Scholar 

  26. Riazaty P, Naderi R, Ramezanzadeh B (2019) Synergistic corrosion inhibition effects of benzimidazole-samarium (III) molecules on the steel corrosion prevention in simulated seawater. J Molec Liq 296: pp. 111801:1–14

    Google Scholar 

  27. Umoren SA, Solomon MM (2017) Synergistic corrosion inhibition effect of metal cations and mixtures of organic compounds: a review. J Environ Chem Eng 5:246–273

    Google Scholar 

  28. Conde A, Arenas MA, de Frutos A, de Damborenea J (2008) Effective corrosion protection of 8090 alloy by cerium conversion coatings. Electrochim Acta 53:7760–7768

    Google Scholar 

  29. Rodríguez DS, Kozhukharov S, Machkova M, Kozhukharov V (2013) Influence of the deposition conditions on the properties of D16 AM clad alloy, dip-coated in Ce-containing baths. Bulg Chem Commun 45-A:24–32

    Google Scholar 

  30. Kozhukharov S, Ayuso JAP, Rodríguez DS, Acuña OF, Machkova M, Kozhukharov V (2013) Optimization of the basic parameters of cathodic deposition of Ce-conversion coatings on D16 AM clad alloy. J Chem Technol Metall 48(3):296–307

    Google Scholar 

  31. Ayuso JAP, Kozhukharov S, Machkova M, Kozhukharov V (2013) Electrodeposition of cerium conversion coatings for corrosion protection of D16 AM clad alloy. Bulg Chem Commun 45-A:33–40

    Google Scholar 

  32. Gil TP, Kozhukharov S, Girginov C (2014) Deposition of cerium conversion coatings on AA2024-T3 aircraft alloy at fixed potentials. Ann Proc Univ Ruse (Bulgaria) 53(10.1):9–13

    Google Scholar 

  33. Kozhukharov S, Milanes M, Girginov C, Machkova M (2016) Comparative evaluation of cerium oxide primers electrodeposited on AA2024-T3 and D16 AM aircraft alloys. Mater Corros 67(7):710–720

    Google Scholar 

  34. O’Keefe MJ, Geng S, Joshi S (2007) Cerium-based conversion coatings as alternatives to hex chrome. Meta:25–28

    Google Scholar 

  35. Castano CE, Fahrenholtz WG, O’Keefe MJ (2020) Ceria-based coatings and pigments. Metal Oxides 6:211–257

    Google Scholar 

  36. Alba-Galvín JJ, González-Rovira L, Bethencourt M, Botana FJ, Sánchez-Amaya JM (2019) Influence of aerospace standard surface pretreatment on the intermetallic phases and CeCC of 2024-T3 Al-cu alloy. Metals 9:. pp. 320:1–21. https://doi.org/10.3390/met9030320

    Article  Google Scholar 

  37. Andreeva R, Stoyanova E, Tsanev A, Datcheva M, Stoychev D (2018) On the role of pre-treatment of aluminum substrate on deposition of cerium based conversion layers and their corrosion-protective ability. Int J Electrochem Sci 13:5333–5351. https://doi.org/10.20964/2018.06.71

    Article  Google Scholar 

  38. Kozhukharov S, Girginov C (2018) Enhancement of the cerium oxide primer layers deposited on AA2024-T3 aircraft alloy by preliminary anodization. J Electrochem Sci Eng 8(2):113–127. https://doi.org/10.5599/jese.478

    Article  Google Scholar 

  39. Kozhukharov SV, Samichkov VI, Girginov CA, Machkova MS (2017) Actual trends in the elaboration of advanced multifunctional coating systems for the efficient protection of lightweight aircraft alloys. Corros Rev 35(6):383–396. ISSN (Online) 2191–0316

    Google Scholar 

  40. Matter E, Kozhukharov S, Machkova M, Kozhukharov V (2009) Influence of the interactions between the corrosion inhibitor and nano-containers over the corrosion protective capability of hybrid nano-composite pre-treatments. Ann Proc Univ Ruse 48:19–23. Accessible via: http://conf.uni-ruse.bg/bg/docs/cp09/9/9-3.pdf

    Google Scholar 

  41. Abdeen DH, El Hachach M, Koc M, Atieh MA (2019) A review on the corrosion behaviour of Nanocoatings on metallic substrates. Materials 12(210):1–42. https://doi.org/10.3390/ma12020210

    Article  Google Scholar 

  42. Zheludkevich ML, Shchukin DG, Yasakau KA, Möhwald H, Ferreira MGS (2007) Anticorrosion coatings with self-healing effect based on Nanocontainers impregnated with corrosion inhibitor. Chem Mater 19(3):402–411. https://doi.org/10.1021/cm062066k

    Article  Google Scholar 

  43. Suleiman R, Khalil A, Khaled M, El Ali B (2019) Chapter 4, hybrid organosilicone materials as efficient anticorrosive coatings in marine environment. In: Marine coatings and membranes. Central West Publishing, Australia, pp 81–114

    Google Scholar 

  44. Noiville R, Jaubert O, Gressier M, Bonino J-P, Taberna P-L, Fori B, Menua M-J (2018) Ce(III) corrosion inhibitor release from silica and boehmite nanocontainers. Mater Sci Eng 229:144–154

    Google Scholar 

  45. Liu MM, Hu HX, Zheng YG, Wang JQ, Gan ZH, Qiu S (2019) Effect of sol-gel sealing treatment loaded with different cerium salts on the corrosion resistance of Fe-based amorphous coating. Surf Coat Technol 367:31–326

    Google Scholar 

  46. Matsuda T, Kashi KB, Fushimi K, Gelling VJ (2019) Corrosion protection of epoxy coating with pH sensitive microcapsules encapsulating cerium nitrate. Corros Sci 148:188–197

    Google Scholar 

  47. Owczarek E (2019) Methods of modifying anticorrosive protective properties of Silane films. Acta Phys Polon 135:147–152. https://doi.org/10.12693/APhysPolA.135.147

    Article  Google Scholar 

  48. Suzuki K, Kato M, Sunaoshi T, Uno H, Carvajal-Nunez U, Nelson AT, McClellan KJ (2019) Thermal and mechanical properties of CeO2. J Amer Ceram Soc 102:1994–2008

    Google Scholar 

  49. Mohammed H, Reddy MP, Ubaid F, Shakoor A, Mohamed AMA (2018) Structural and mechanical properties of CeO2 reinforced Al matrix Nanocomposites. Adv Mater Lett 9:602–605

    Google Scholar 

  50. Sharma VK, Kumar V, Joshi RS (2019) Effect of RE addition on wear behavior of an Al-6061 based hybrid composite. Wear 426(427):961–974

    Google Scholar 

  51. Finny SA, Othman FA, Andreescu S (2020) Chapter 7. Cerium oxide nanoparticles for chemical and biological sensors: properties, sensing designs, and applications. Metal Oxides:259–277

    Google Scholar 

  52. Nenova Z, Kozhukharov S, Nenov T, Nedev N, Machkova M (2016) Combined influence of titania and silica precursors on the properties of thin film humidity sensing elements prepared via a sol–gel method. Sensors Actuators B-224:143–152

    Google Scholar 

  53. Kozhukharov S, Nenova Z, Nenov T, Machkova M, Kozhukharov V (2013) Influence of Ce(III)/Ce(IV) - supplements on the characteristics of humidity sensors with TiO2 films prepared via a sol-gel method. Bol Soc Esp Cerám Vidrio 52:71–78

    Google Scholar 

  54. Petkov LN, Yosifov KS, Tsanev AS, Stoychev D (2013) Glassy carbon (GC) electrode modified with electrodeposited ZrO2 and ZrO2 + Ce2O3 + Y2O3 nanostructures as a cathode in the obtaining of active chlorine. Bulg Chem Commun 45-A:122–128

    Google Scholar 

  55. Salinas D, Pecchi G, Fierro JLG (2016) K2O supported on sol-gel CeO2-Al2O3 and La2O3-Al2O3 catalysts for the transesterification reaction of canola oil. J Molec Catal A-423:503–510

    Google Scholar 

Download references

Acknowledgments

The present work is developed under the financial support of the Bulgarian National Research Fund under contract КП-06-М38/1 (2019) “Characterization of the physical properties of functional oxide layers, formed on aluminum and its alloys”.

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature B.V.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Kozhukharov, S., Girginov, C. (2020). Recent Trends of the Use of Rare Earth Elements for Efficient Environmentally Compliant Corrosion Protection of Aluminum and Its Alloys. In: Petkov, P., Achour, M., Popov, C. (eds) Nanoscience and Nanotechnology in Security and Protection against CBRN Threats. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-2018-0_35

Download citation

Publish with us

Policies and ethics