Skip to main content
SpringerLink
Log in

195Pt NMR of Pt309Phen *36 O30 Metallic Clusters

  • Chapter
Physics and Chemistry of Finite Systems: From Clusters to Crystals

Part of the book series: NATO ASI Series ((ASIC,volume 374))

Abstract

195Pt NMR lineshape and spin-lattice relaxation measurements at 77 K are presented for the polynuclear metallic cluster compound Pt309Phen *36 O30 Two peaks in the NMR lineshape are found centered at Ho/v0=1.110 G/kHz and 1.096 G/kHz. The high field peak is attributed to Pt spins located in the interior of the cluster which are in a metallic environment. The low field peak has its origin in platinum atoms that constitute the surface shell of the cluster. These atoms are involved in chemical bonds with the ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W.P.Halperin, Rev. Mod. Phys. 58, 533 (1986)

    Article  Google Scholar 

  2. G.Schmid, Structure and Bonding 62, 51 (1985); Endeavour, New Series 14 (Pergamon Press, Oxford, 1990); Aspects of Homogeneous Catalysis, 7, 1 (1990), Ed. R.Ugo (Kluwer Academic, Dordrecht )

    Google Scholar 

  3. L.J.de Jongh, J.A.O.de Aguiar, H.B.Brom, G.Longoni, J.M.van Ruitenbeek, G.Schmid, H.H.A.Smit, M.P.J.van Staveren and R.C.Thiel, Z.Phys.D 12, 445 (1989) and references cited therein.

    Google Scholar 

  4. I.Yu, A.A.V.Gibson, E.R.Hunt and W.P.Halperin, Phys. Rev. Lett. 44 348 (1980)

    Article  Google Scholar 

  5. I.Yu and W.P.Halperin, J.Low Temp. Phys. 45, 189 (1981)

    Article  Google Scholar 

  6. H.E.Rhodes, P.-K.Wang, H.T.Stokes, C.P.Slichter and J.H.Sinfelt, Phys. Rev. B 26, 3559 (1982)

    Article  Google Scholar 

  7. H.E.Rhodes, P: K.Wang, C.D.Makowka, S.L.Rudaz, H.T.Stokes, C.P.Slichter and J.H.Sinfelt, Phys. Rev. B 26, 3569 (1982)

    Article  Google Scholar 

  8. T.Stokes, H.E.Rhodes, P: K.Wang, C.P.Slichter and J.H.Sinfelt, Phys. Rev. B 26, 3575 (1982)

    Article  Google Scholar 

  9. J.J.van der Klink, J.Buttet and M.Graetzel, Phys. Rev. B 29, 6352 (1984)

    Article  Google Scholar 

  10. B.J.Pronk, H.B.Brom, A.Ceriotti and G.Longoni, Solid State Comm. 64, 7 (1987)

    Article  Google Scholar 

  11. C.D.Makowka, C.P.Slichter and J.H.Sinfelt, Phys. Rev. B 31, 5663 (1985)

    Article  Google Scholar 

  12. J.P.Bucher and J.J.van der Klink, Phys. Rev. B 38, 11038 (1988)

    Article  Google Scholar 

  13. J.P.Bucher, J.Buttet and J.J.van der Klink, Surf. Sci. 214, 347 (1989)

    Article  Google Scholar 

  14. C.Froidevaux and M.Weger, Phys. Rev. Lett. 12, 123 (1964)

    Article  Google Scholar 

  15. J.M. van Ruitenbeek, M.J.G.M.Jurgens, G.Schmid, D.A.van Leeuwen, H.W.Zandbergen and L.J.de Jongh, Z. Phys. D 19, 267 (1991)

    Article  Google Scholar 

  16. J.Baak, H.B.Brom, L.J.de Jongh and G.Schmid, This conference.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kamerlingh Onnes Laboratory, Leiden University, P.O. Box 9506, 2300 RA, Leiden, The Netherlands

    D. van der Putten, H. B. Brom, L. J. de Jongh & G. Schmid

  2. Institut für Anorganische Chemie, Universität Essen, Universitätsstrasse 5-7, D-4300, Essen 1, Germany

    G. Schmid

Authors
  1. D. van der Putten
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. B. Brom
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. J. de Jongh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Schmid
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Physics, Virginia Commonwealth University, Richmond, VA, USA

    P. Jena , S. N. Khanna  & B. K. Rao ,  & 

Rights and permissions

Reprints and permissions

Copyright information

© 1992 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

van der Putten, D., Brom, H.B., de Jongh, L.J., Schmid, G. (1992). 195Pt NMR of Pt309Phen *36 O30 Metallic Clusters. In: Jena, P., Khanna, S.N., Rao, B.K. (eds) Physics and Chemistry of Finite Systems: From Clusters to Crystals. NATO ASI Series, vol 374. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2645-0_136

Download citation

  • DOI: https://doi.org/10.1007/978-94-017-2645-0_136

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-017-2647-4

  • Online ISBN: 978-94-017-2645-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation