Abstract
Applications of small organic chemicals to soils and growing crops is part of a major industry. Some such chemicals are applied for the control of weeds, insects, and plant diseases, and for regulating plant growth. These may be applied directly to the soil as sprays, or incorporated in the soil as solids or vapors, or they may enter the soil as canopy drip from spray applications to crops. In the ideal system the soil applied chemical would be held close to the target species and available to it, and it would degrade or be biodegraded when the function for which it was intended is achieved. However, few chemicals follow the ideal behavior in soils. Some biocidal compounds do not adhere to the soil constituents and are transported readily as water moves through the soil profile. Others are strongly bound by soil colloids and may be unavailable to the plant or pest target.
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References
Adams, J.M., Clement, D.E. and Graham, S.H. 1983. Reactions of alcohols with alkenes over an aluminum-exchanged montmorillonite. Clays and Clay Minerals 31, 129–136.
Appelqvist, I.A. 1990. Adsorption of Metals by Humic Substances Using an Automated Continuous Flow System. PhD Thesis. The University of Birmingham. For submission.
Armstrong, D.E. and Chesters, G. 1968. Adsorption catalyzed chemical hydrolysis of atrazine. Environ. Sci. Technol. 2, 683–689.
Armstrong, D.E. and Konrad, J.G. 1974. Non-biological degradation of pesticides. In W.G. Guenzi (ed.), Pesticides in Soil and Water. Soil Sci. Soc. Amer., Madison, Wisconsin. pp. 123–130.
Ash, S.G., Brown, R. and Everett, D.H. 1973. A high-precision apparatus for the determination of adsorption at the interface between a solid and a solution. J. Chem Thermodynamics 5, 239–246.
Asti11, D.M., Hall, P.L. and McConnell, J.D.C. 1987. An automated vacuum microbalance for measurement of adsorption isotherms. J. Phys. Eng. Sci. Instrum. 20, 19–21.
Bailey, G.W., White, J.L. and Rothberg, T. 1968. Adsorption of organic herbicides by montmorillonite: Role of pH and chemical character of adsorbate. Soil Sci. Soc. Amer. Proc. 32, 222–234.
Bailey, G.W. and White, J.L. 1970. Factors influencing the adsorption, desorption, and movement of pesticides in soil. Residue Rev. 32, 29–92.
Banwart, W.L., Khan, A. and Hassett, J.J. 1980. Effect of sample pretreatment on sorption of acetophenone by soils and sediments. J. Environ. Sci. Health 15, 165–179.
Bartha, R. 1971. Fate of herbicide-derived chloroanilines in soil. J. Agric. Food Chem. 19, 385–387.
Benham, M. and Ross, D.K. 1989. Experimental determination of pressure composition isotherms for metal hydrogen systems using a computer controlled microbalance. Z. Physik. Chem. N.S. 163, 25–32.
Bowman, B.T. and Sans, W.W. 1977. Adsorption of parathion, fenitrothion, methyl-parathion, amino-parathion and paraoxon by Na+, Ca2+ and Fe3+ montmorillonte suspensions. Soil Sci. Soc. Amer. J. 41, 514–519.
Briggs, G.G. 1973. A simple relationship between soil adsorption of organic chemicals and their octanol/water partition coefficient. Proc. 7th Br. Insectic. Fungic. Conf. (Brighton) 3, 83–86.
Briggs, G.G. 1981. Theoretical and experimental relationships between soil adsorption, octanol-water partition coefficients, water solubilities, bioconcentration factors, and the parachor. J. Agric. Food Chem. 19, 1050–1059.
Briggs, G.G. 1984. Factors affecting the uptake of soil-applied chemicals by plants and other organisms. Monogr. British Crop Protection Council 27, 33–47.
Brown, C.B. and White, J.L. 1969. Reactions of 12 s-triazines with soil clays. Soil. Sci. Soc. Amer. Proc. 33, 863–867.
Brunauer, G., Emmett, P.H. and Teller, E. 1938. Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60, 309–319.
Burchill, S., Hayes, M.H.B. and Greenland, D.J. 1981. Adsorption. In D.J. Greenland and M.H.B. Hayes (eds.), The Chemistry of Soil Processes. Wiley, Chichester. pp. 221–400.
Burdon, J., Hayes, M.H.B. and Pick, M.E. 1977. The electron density distribution in pyridinium and bipyridinium compounds and its relevance to their adsorption by expanding lattice clays. J. Environ. Sci. Health B12, 37–51.
Burns, I.G., Hayes, M.H.B. and Stacey, M. 1973a. Studies of the adsorption of paraquat on soluble humic fraction by gel filtration and ultrafiltration techniques. Pestic Sci. 4, 629–641.
Burns, I.G., Hayes, M.H.B. and Stacey, M. 1973b. Some physico-chemical interactions of paraquat with soil organic materials and model compounds. II. Adsorption and desorption equilibria in aqueous suspensions. Weed Res. 13, 79–90.
Burns, I.G. and Hayes, M.H.B. 1974. Some physico-chemical principles involved in the adsorption of the organic cation paraquat by soil humic materials. Residue Rev. 52, 117–146.
Burns, R.G. 1975. Factors effecting pesticide loss from soil. In E.A. Paul and A.B. McLaren (eds.), Soil Biochemistry 4. Marcel Dekker, New York. pp. 103–141.
Cameron, R.S., Thornton, B.K., Swift, R.S. and Posner, A.M. 1972. Molecular weight and shape of humic acid from sedimentation and diffusion measurements on fractionated extracts. J. Soil Sci. 23, 394–408.
Cartmell, E. and Fowles, G.W.A. 1971. Valency and Molecular Structure. 3rd Edition. Butter-worths, London.
Cheshire, M.V. and Hayes, M.H.B. 1990. Composition, origins, structures and reactivities of soil polysaccharides. In M.F.L. De Boodt, M.H.B. Hayes, A. Herbillon, E.B.A. De Strooper and J.J. Tuck (eds.), Soil Colloids and Their Associations in Aggregates. Plenum, New York and London. pp. 307–336.
Chiou, C.T. and Kile, D.E. 1991. Interactions of nonionic organic compounds with dissolved humic substances. In P. MacCarthy, M.H.B Hayes, R.L. Malcolm and R.S. Swift (eds.), Humic Substances III. Interactions with Metals, Minerals, and Organic Chemicals. Wiley, Chichester. In press.
Chiou, C.T., Peters, L.J. and Freed, V.H. 1979. A physical concept of soil-water equilibria for nonionic organic compounds. Science 206, 831–832.
Chiou, C.W., Porter, P.E. and Schmeding, D.W. 1983. Partition equilibria of nonionic organic compounds between soil organic matter and water. Environ. Sci. Technol. 17, 227–231.
Crosby, D.G. 1970. The non-biological degradation of pesticides in soils. In Pesticides in the Soil: Ecologly, Degradation and Movement. Proc. Int. Sympos. on Pesticides in Soil. Michigan State University, East Lansing.
Denbigh, K. 1971. The Principles of Chemical Equilibrium,3rd edition. Cambridge University Press.
Deny, J.E. and Hamor, T.A. 1969. Stereochemistry of the diquat ion in the crystalline dibromide salt. Nature (London) 221, 464–465.
Diamond, S. and Kinter, E.B. 1963. Characterization of montmorillonite saturated with short chain amine cations. I. Interpretation of basal spacing measurements. Clays and Clay Minerals 10, 163–173.
Dölling, A.M. 1985. Studies of Interactions of some Imidazolinone Herbicides with Clays. MSc Thesis. The University of Birmingham.
El-Amamy, M.M. and Mill, T. 1984. Hydrolysis kinetics of organic chemicals on montmorillonite and kaolinite surfaces as related to moisture content. Clays and Clay Minerals 32, 67–73.
Everett, D.H. 1972. IUPAC Division of Physical Chemistry. Manual of samples and terminology of physicochemical quantities and units. Appendix II. Definitions, terminology and symbols in colloid and surface chemistry. Pure and Applied Chem. 31, 577–627.
Fusi, P., Ristori, G.G., Cecconi, S. and Franci, M. 1983. Adsorption and degradation of fenarimol on montmorillonite. Clays and Clay Minerals 31, 312–314.
Fripiat, J.J., Jelli, A.N., Poncelet, G. and André, J. 1965. Thermodynamic properties of adsorbed water molecules and electrical conduction in montmorillonites and silicas. J. Phys. Chem. 69, 2185–2197.
Fripiat, J.J., Pennequin, M., Poncelet, G. and Cloos, P. 1969. Influence of the Van der Waal force on the infrared spectra of short aliphatic alkylammonium cations held on montmorillonite. Clay Minerals 8, 119–134.
Gamble, D.S. 1970. Titration curves of fulvic acid. The analytical chemistry of a weak acid polyelectrolyte. Can. J. Chem. 48, 2662–2669.
Gerstl, Z. and Mingelgrin, U. 1979. A note on the adsorption of organic molecules on clays. Clays and Clay Minerals 27, 285–290.
Gilmour, J.T. and Coleman, N.T. 1971a. s-Triazine adsorption studies: Ca-H-humic acid. Soil Sci. Soc. Amer. Proc. 35, 256–259.
Gilmour, J.T. and Coleman, N.T. 1971b. Buffer curves and acid strength of humic acid and two resins. Soil Sci. Soc. Amer. Proc. 35, 710–714.
Goring, C.A.I. 1967. Physical aspects of soil in relation to the action of soil fungicides. Ann. Rev. Phytopathol. 5, 285–318.
Greenland, D.J. and Mott, C.J.B. 1978. Surfaces of soil particles. In D.J. Greenland and M.H.B. Hayes (eds.), The Chemistry of Soil Constituents. Wiley, Chichester. pp. 321–353.
Grice, R.E. and Hayes, M.H.B. 1970. Methods for studying the adsorption of organic chemicals by soil organic matter preparations. Proc. 10th British Weed Control Conf. (Brighton) 3, 1089–1100.
Grice, R.E., Hayes, M.H.B. and Lundie, P.R. 1973. Adsorption of organophosphorus compounds by soil constituents and by soil. Proc. 7th British Insecticide and Fungicide Conf. (Brighton) 1, 73–81.
Hall, P.L. and Astill, D.M. 1987. Adsorption of water by homoionic exchange forms of Wyoming montmorillonite (SWy-1). Clays and Clay Minerals 37, 355–363.
Hamaker, J.W. 1975. The interpretation of soil leaching experiments. In V.H. Freed (ed.), Evironmental Dynamics of Pesticides. Plenum, New York and London. pp. 115–139.
Hartley, G.S. 1961. Physico-chemical aspects of the availability of herbicides in soils. In K.K. Woodford and G.R. Sagar (eds.), Herbicides in the Soil. Blackwells, Oxford and New York.
Hartley, G.S. 1964. Herbicide behavior in the soil. I. Physical factors and action through the soil. In L.J. Audus (ed.), The Physiology and Biochemistry of Herbicides. Academic Press, New York.
Häusler, M.J. 1986. Studies of Interactions of some Imidazolinone Herbicides with whole Soils, Oxyhydroxides, and with Natural and Synthetic Humic Acids. Ph.D. Thesis. The University of Birmingham.
Hayes, M.H.B. 1970. Adsorption of triazine herbicides on soil organic matter, including a short review on soil organic matter chemistry. Residue Rev. 32, 131–174.
Hayes, M.H.B. 1984. Chemical nature and reactivities of soil organic polymers. In B. Yaron, G. Dagan and J. Goldshmid (eds.), Pollutants in Porous Media. Springer Verlag, Heidelberg. pp. 126–142.
Hayes, M.H.B. 1985. Extraction of humic substances from soils In G. Aiken, D. McKnight, R.L. Wershaw and P. MacCarthy (eds.), Humic Substances in Soil, Sediment, and Water. Wiley, New York. pp. 329–362.
Hayes, M.H.B. 1987. Sorption and chemical transformation proceses of small organic chemicals in soil. Trans XIII Congress Internat. Soc. Soil Sci. (Hamburg, 1986) 6, 584–595.
Hayes, M.H.B. and Himes, F.L. 1986. Nature and properties of humus-mineral complexes. In P.M. Huang and M. Schnitzer (eds.), Interactions of Soil Minerals with Natural Organics and Microbes. SSSA Special Publications No. 17. Soil Sci. Soc. Amer. Inc., Madison, Wisconsin. pp. 103–158.
Hayes, M.H.B., Isaacson, P.J., Lees, A.M. and Yormah, T.B.R. 1984. Vapor phase sorption and desorption of monomethylhydrazine by homoionic-exchanged clays. J. Colloid Interface Sci. 97, 48–54.
Hayes, M.H.B., MacCarthy, P., Malcolm, R.L. and Swift, R.S. 1989. Structures of humic substances: The emergence of `forms’. In M.H.B. Hayes, P. MacCarthy, R.L. Malcolm and R.S. Swift (eds.), Humic Substances II. In Search of Structure. Wiley, Chichester, pp. 689–733.
Hayes, M.H.B., Lundie, P.R. and Stacey, M. 1972. Interactions between organophosphorus compounds and soil materials. I. Adsorption of ethyl methylphosphorofluoridate by clay and organic matter preparations and by soils. Pestic. Sci. 3, 619–629.
Hayes, M.H.B., Pick, M.E. and Toms, BA. 1975. Interactions between clay minerals and bipyridinium herbicides. Residue Rev. 57, 1–25.
Hayes, M.H.B., Pick, M.E. and Toms, B.A. 1978a. The influence of organocation structure on the adsorption of mono-and of bipyridinium cations by expanding lattice clay minerals. I. Adsorption by Na+-montmorillonite. J. Colloid Interface Sci. 65, 254–265.
Hayes, M.H.B., Pick, M.E. and Toms, B.A. 1978b. The influence of organocation structure on the adsorption of mono-and of bipyridinium cations by expanding lattice clay minerals. II. Adsorption by Nat-vermiculite. J. Colloid Interface Sci. 65, 266–275.
Hayes, M.H.B., Stacey, M. and Thompson, J.M. 1968. Adsorption of s-triazine herbicides by soil organic matter preparations. I.A.E.A., Isotopes and Radiation in Soil Organic Matter Studies (Vienna), pp. 75–90.
Hayes, M.H.B. and Swift, R.S. 1978. The chemistry of soil organic colloids. In D.J. Greenland and M.H.B. Hayes (eds.), The Chemistry of Soil Constituents. Wiley, Chichester. pp. 179–320.
Hayes, M.H.B. and Swift, R.S. 1990. Genesis, isolation, composition and structures of soil humic substances. In M.F.L. De Boodt, M.H.B. Hayes, A. Herbillon, E.B.A. De Strooper and J.J. Tuck (eds.), Soil Colloids and Their Associations in Aggregates. Plenum, New York and London. pp. 245–305.
Helfferich, F. 1962. Ion Exchange. McGraw-Hill, New York.
Hummel, J.P. and Dreyer, W.J. 1962. Measurement of protein binding phenomena by gel filtration. Biochern. Biophys. Acta 63, 530–531.
Hurle, K. and Walker A. 1980. Persistence and its prediction. In R.J. Hance (ed.), Interactions Between Herbicides and the Soil. Academic Press, London, pp. 83–122.
Isaacson, P.J. and Frink C.R. 1984. Nonreversible sorption of phenolic compounds by sediment ractions: The role of sediment organic matter. Environ. Sci. Technol. 18, 43–48.
Isaacson, P.J. and Hayes, M.H.B. 1984. The interaction of hydrazine hydrate with humic acid preparations at pH 4. J. Soil Sci. 35, 72–92.
Jordan, L.S. 1970. Foreword. In F.A. Gunther (ed.), The Triazine Herbicides. Residue Reviews 32, vii-xiii.
Karickhoff, S.W. 1981. Semi-empirical estimation of sorption of hydrophobic pollutants on natural sediments and soils. Chemosphere 10, 833–846.
Karickhoff, S.W. and Morris, K.R. 1985. Sorption dynamics of hydrophobic pollutants in sediment suspensions. Environ. Toxicol. Chem. 4, 469–479.
Khan, S.U. 1974. Humic substances reactions involving bipyridinium herbicides in soil and aquatic environments. Residue Rev. 52, 1–26.
Khan, S.U. 1978. The interaction of organic matter with pesticides. In M. Schnitzer and S.U. Khan (eds.), Soil Organic Matter. Elsevier, Amsterdam. pp. 137–173.
Khan, S.U. 1982. Bound pesticide residues in soil and plants. Residue Rev. 84, 1–25.
Kim, Y.T. 1970. The adsorption of substituted urea compounds on montmorillonite. Diss. Abst. 30, 5326-B.
Kinter, E.B. and Diamond, S. 1983. Characterization of montmorillonite saturated with short chain amine cations: II. Interlayer surface coverage by the amine cations. Clays Clay Minerals 10, 163–173.
Konrad, J.G., Armstrong, D.E. and Chesters, G. 1967. Soil degradation of diazinon, a phosphorothioate insecticide. Agron. J. 59, 591–594.
Konrad, J.G. and Chesters, G. 1969. Degradation in soils of ciodrin, an organophosphate insecticide. J. Agr. Food Chem. 17, 226–230.
Laby, R.H. and Walker, G.F. 1972. Hydrogen bonding in primary alkylammonium-vermiculite complexes. J. Phys. Chem. 74, 2369–2370.
Lagaly, G. 1984. Clay-organic interactions. In L. Fowden, R.M. Barrer and P.B. Tinker (eds.), Clay Minerals: Their Structure, Behavior and Use. The Royal Society, London. pp. 95–332.
Lahav, N., White, D. and Chang, S. 1978. Peptide formation in the prebiotic era: Thermal condensation of glycine in fluctuating clay environments. Science 201, 67–69.
Lambert, S.M. 1967. Functional relationship between sorption in soil and chemical structures. J. Agric. Food Chem. 15, 572–576.
Langmuir, I. 1918. The adsorption of gases on plane surfaces on glass, mica and platinum. J. Am. Chem. Soc. 40, 1361–1403.
Lapen, A.J. and Seitz, W.R. 1982. Fluorescence polarization studies of the conformation of soil fulvic acid. Anal. Chem. Acta 134, 31–38.
Law, I.A., Tuck, J.J., Graham, C.L. and Hayes, M.H.B. 1990. An automated method for obtaining sorption and desorption isotherms by a combined continuous-flow injection analysis process. Anal. Chimica Acta. Accepted for publication.
Law, I.A. 1988. The Extraction, Fractionation and Characterization of Humic Substances, and Their Sorption Behavior Towards Metal Cations. Ph.D. Thesis, University of Birmingham.
Leenheer, JA. and Ahlrichs, J.L. 1971. A kinetic and equilibrium study of the adsorption of carbaryl and parathion upon soil organic matter surfaces. Soil. Sci. Amer. Proc. 35, 700–705.
Lindsay, W.L. 1979. Chemical Equilibria in Soils. Wiley, New York. Lopez-Gonzales, J. De D. and Valenzuela-Calahorro, C. 1970. Associated decomposition of
DDT to DDE in the diffusion of DDT on homionic clays. J. Agric. Food Chem. 18 520–523.
Lundie, P.R. 1971. Adsorption of Organophosphorus Compounds by Soils and by Soil Colloids. Ph.D. Thesis, The University of Birmingham.
Macalady, D.L. and Wolfe, N.L. 1985. Effects of sediment sorption on abiotic hydrolyses. I. Organophosphorothioate esters. J. Agric. Food Chem. 33, 167–173.
MacEwan, D.M.C. 1948. Complexes of clays with organic compounds. I. Complex formation between montmorillonite and halloysite and certain organic liquids. Trans Faraday Soc. 44, 349–367.
Mackintosh, E.E., Lewis, D.G. and Greenland, D.J. 1971. Dodecylammonium mica complexes. I. Factors affecting the exchange reaction. Clays and Clay Minerals 19, 209–219.
Maes, A. Marynen, P. and Cremers. A. 1977. Stability of metal uncharged ligand complexes in ion exchangers. Part 1. Quantitative characterization and thermodynamic basis. J. Chem. Soc Faraday Trans. 173, 1297–1301.
Maes, A. Peigneur, P. and Cremers. A. 1978. Stability of metal uncharged ligand complexes in ion exchangers. Part 2. The copper + ethylenediamine complex in montmorillonite and sulphonic acid resins. J. Chem. Soc Faraday Trans 174, 182–189.
McAuliffe, C. and Coleman, N.T. 1955. Hydrogen-ion catalysis by acid clays and exchange resins. Soil Sci. Soc. Amer. Proc. 19, 156–160.
McBain, J.W. and Bakr, A.M. 1926. A new sorption balance. J. Am. Chem. Soc. 48, 690–695.
McBride, M.B. 1985. Surface reactions of 3,3’,5,5’-tetramethyl benzidine on hectorite. Clays and Clay Minerals 33, 510–516.
Mills, A.C. and Biggar, J.W. 1969. Adsorption of 1,2,3,4,5,6–hexachiorocyciohexane from solution: The differential heat of adsorption applied to adsorption from dilute solutions on organic and inorganic interfaces. J. Colloid Interface Sci. 29, 720–731.
Mingelgrin, U. and Gerstl, Z. 1983. Re-evaluation of partitioning as a mechanism for non-ionic chemicals adsorption in soils. J. Environ. Qual. 12, 1–11.
Mingelgrin, U. and Prost, R. 1989. Surface interactions of toxic organic chemicals with minerals. In Z. Gerstl, Y. Chen, U. Mingelgrin and B. Yaron (eds.), Toxic Organic Chemicals in Porous Media. Springer-Verlag, Berlin. pp. 91–135.
Mingelgrin, U. and Saltzman, S. 1979. Surface reactions of parathion on clays. Clays and Clay Minerals 27, 72–78.
Mingelgrin, U., Saltzman, S. and Yaron, B. 1977. A possible model for the surface-induced hydrolysis of organophosphorous pesticides on kaolinite clays. Soil Sci. Soc. Amer. J. 41, 519–523.
Mingelgrin, U., Yariv, S. and Saltzman, S. 1978. Differential infrared spectroscopy in the study of parathion-bentonite complexes. Soil Sci. Soc. Amer. J. 42, 664–665.
Mingelgrin, U. and Yaron, B. 1974. The effect of calcium salts on the degradation of parathion in sand and soil. Soil. Sci. Soc. Amer. Proc. 38, 914–917.
Moreale, A. and Van Bladel, R. 1979. Soil interactions of herbicide-derived analine residues: A thermodynamic approach. Soil Sci. 127, 1–9.
Mortland, M.M. 1966. Urea complexes with montmorillonite: An infrared absorption study. Clay Minerals 6, 143–156.
Mortland, M.M. 1970. Clay-organc complexes and interactions. Adv. Agron. 22, 75–117.
Mortland, M.M. and Raman, K.V. 1967. Catalytic hydrolysis of some organic phosphate peciticides by copper(II). J. Agric. Food Chem. 15, 163–167.
Nash, R.G., Harris, W.G. and Lewis, C.C. 1973. Soil pH and metallic amendment effects of DDT conversions to DDE. J. Environ. Qual. 2, 390–394.
Newman, A.C.D. and Hayes, M.H.B. 1990. Some properties of clays and of other soil colloids and their influences on soils. In M.F.L. De Boodt, M.H.B. Hayes, A. Herbillon, E.BA. De Strooper and J.J. Tuck (eds.), Soil Colloids and Their Associations in Aggregates. Plenum, New York and London. pp. 39–55.
Nichol, L.W. and Winsor, D.J. 1972. Migration of Interacting Systems. Clarendon Press, Oxford.
Ostazeski, S.A. and Means, J.C. 1984. The sorption of pyrene on estuarine sediments. J. Am. Chenu. Soc. 24, 60–61.
Raupach, M., Emerson, W.W. and Slade, P.G. 1979. The arrangement of paraquat bound by vermiculite and montmorillonite. J. Colloid Interface Sci. 69, 398–408.
Rausell-Colom, J.A. and Serratosa, J.M. 1987. Reactions of clays with organic substances. In A.C.D. Newman (ed.), Chemistry of Clays and Clay Minerals. Longman Scientific, Harlow, Essex, and the Mineralogical Society, London. pp. 371–422.
Ristori, G.G., Fusi, P. and Franci, M. 1981. Montmorillonite-asulam interactions. II. Catalytic decomposition of asulam adsorbed on Mg, Ba, Ca, Li, Na, K and Cs-clay. Clay Minerals 16, 125–137.
Romelt, P.M. and Seitz, W.R. 1982. Fluorescence polarization studies of perylene-fulvic acid binding. Environ. Sci. Technol. 16, 613–616.
Rosen, M.J. 1978. Surfactants and Interfacial Phenomena. Wiley, New York and Chichester.
Rosenfield, C. and Van Valkenburg, W. 1965. Decomposition of (O,O-dimethyl-O-2,4,5-trichlorophenyl) phosphorothioate (ronnel) adsorbed on bentonite and other clays. J. Agric. Food Chem. 13, 68–72.
Ross, S. and Olivier, J.P. 1964. On Physical Adsorption. Interscience, New York.
Rupert, J.P., Granquist, W.T. and Pinnavaia, T.J. 1987. Catalytic properties of clay minerals. In A.C.D. Newman (ed.), Chemistry of Clays and Clay Minerals. Longman Scientific, Harlow, Essex, and the Mineralogical Society, London. pp. 275–318.
Russell, J.D. Cruz, M. and White, J.L. 1968a. Mode of chemical degradation of s-triazines by montmorillonite. Science 160 1340–1342.
Russell, J.D., Cruz, M. and White, J.L. 1968b. The adsorption of 3–aminotriazole by montmorillonite. J. Agric. Food Chem. 16, 21–24.
Saltzman, S., Kliger, L. and Yaron, B. 1972. Adsorption-desorption of parathion as affected by soil organic matter. J. Agric. Food Chem. 20, 1224–1226.
Saltzman, S., Mingelgrin, U. and Yaron, B. 1976. Role of water in the hydrolysis of parathion and methylparathion on kaolinite. J. Agric. Food Chem. 24, 739–743.
Saltzman, S., Yaron, B. and Mingelgrin, U. 1974. The surface catalyzed hydrolysis of parathion on kaolinite. Soil Sci. Soc. Amer. Proc. 38, 231–234.
Sanchez Camazano, M. and Sanchez Martin, M.J. 1983b. Montmorillonite catalyzed hydrolysis of phosmet. Soil Sci. 136, 89–93.
Schnitzer, M. and Khan, S.U. 1972. Humic Substances in the Environment. Marcel Dekker, New York.
Schwarzenbach, R.P. and Westall, J. 1981. Transport of nonpolar organic compounds from surface water to ground water. Laboratory sorption studies. Environ. Sci. Technol. 15, 1360–1367.
Schwertmann, U., Kodama, H. and Fischer, W.R. 1986. Mutual inteactions between organics and iron oxides. In P.M. Huang and M. Schnitzer (eds.), Interactions of Soil Minerals with Natural Organics and Microbes. SSSA Special Publication 17. Soil Sci. Soc. of Amer. Inc., Madison, Wisconsin. pp. 223–250.
Senesi, N. and Steelink, C. 1989. Application of ESR spectroscopy to the study of humic substances. In M.H.B. Hayes, P. MacCarthy, R.L. Malcolm and R.S. Swift (eds.), Humic Substances IL In Search of Structure. Wiley, Chichester, pp. 373–408.
Senesi, N. and Testini, C. 1982. Physico-chemical investigations of interaction mechanisms between s-triazine herbicides and soil humic acids. Geodenna 28, 129–146.
Senesi, N. and Testini, C. 1983. Spectroscopic investigation of electron donor-acceptor processes involving organic free radicals in the adsorption of substituted area herbicides by humic acids. Pestic. Sci. 14, 79–89.
Skipper, H.D., Volk, V.V., Mortland, M.M. and Raman, K.V. 1978. Hydrolysis of atrazine on soil colloids. Weed Sci. 26, 46–51.
Skujins, J.J. 1967. Enzymes in soil. In A.D. McLaren and G.H. Peterson (eds.), Soil Biochemistry. Edward Arnold, London, and Marcel Dekker, New York. pp. 371–414.
Slade, P.G., Raujpach, M. and Emerson, W.W. 1978. The ordering of cetylpyridinium bromide on vermiculite. Clays and Clay Minerals 16, 125–134.
Solomon, D.H. and Rosser, M.J. 1965. Reactions catalyzed by minerals. I. Polymerization of styrene. J. Appl. Polymer Sci. 9, 1261–1271.
Sposito, G. 1984. The Surface Chemistry of Soils. Oxford University Press.
Stevenson, F.J. 1972. Role and function of humus in soil with emphasis on adsorption of herbicides and chelation of micronutrients. Bio Science 22, 643–650.
Stevenson, F.J. 1982. Humus Chemistry. Wiley, New York.
Stevenson, F.J. 1985. Geochemistry of soil humic substances. In G.R. Aiken, D.M. McKnight, R.L. Wershaw, and P. MacCarthy (eds.), Humic Substances in Soil, Sediment and Water. Wiley, New York.
Sullivan, J.D. Jr and Felbeck, G.T. 1968. The interaction of s-triazine herbicides with humic acids from three different soils. Soil Sci. 106, 45–52.
Theng, B.K.G. 1974. The Chemistry of Clay-Organic Reactions. Adam Hilger, London.
Theng, B.K.G. 1979. Formation and Properties of Clay-Polymer Complexes. Elsevier. Amsterdam and New York.
Theng, B.K.G. 1982. Clay-activated organic reactions. Proc. Intern. Clay Conf. (1981). Developments in Sedimentology 35, 197–238.
Theng, B.K.G., Greenland, D.J. and Quirk, J.P. 1967. Adsorption of alkylammonium cations by montmorillonite. Clay Minerals 7, 1–7.
Tsvetkov, F., Mingelgrin, U. and Lahav, N. 1990. Cross-linked hydroxy-Al-montmorillonite as a stationary phase in liquid chromatography. Clays and Clay Minerals 38, 380–390.
Van de Vault, D. 1943. The theory of chromatography. J. Chenu. Soc. 65, 532–540.
Vansant, E.F. and Uytterhoeven, J.B. 1972. Thermodynamics of the exchange of n-alkylam-monium ions on Na-montmorillonite. Clays and Clay Minerals 20, 47–54.
Waite, T.D. 1991. Redox chemistry of metal-humic interactions. In P. MacCarthy, M.H.B. Hayes, R.L. Malcolm, and R.S. Swift (eds.), Humic Substances III. Interactions with Metals, Minerals, and Organic Chemicals. Wiley, Chichester. In Press.
Walker, G.F. 1959. Diffusion of exchangeable cations in vermiculite. Nature 184, 1392–1394.
Weber, J.B. 1970. Mechanisms of adsorption of s-triazines by clay colloids and factors affecting plant availability. Residue Reviews 32, 93–130.
Weber, J.B., Weed, S.B. and Ward, T.M. 1969. Adsorption of s-triazines by soil organic matter. Weed Sci. 17, 417–421.
Weiss, A. 1969. Organic derivatives of clay minerals. In G. Eglinton and M.T.J. Murphy (eds.), Organic Geochemistry. Springer-Verlag, Berlin, New York. pp. 737–781.
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Hayes, M.H.B., Mingelgrin, U. (1991). Interactions between Small Organic Chemicals and Soil Colloidal Constituents. In: Bolt, G.H., De Boodt, M.F., Hayes, M.H.B., McBride, M.B., De Strooper, E.B.A. (eds) Interactions at the Soil Colloid — Soil Solution Interface. NATO ASI Series, vol 190. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-1909-4_11
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