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Structure and Dynamics of Water in Confined Geometry

  • Chapter
Hydrogen Bond Networks

Part of the book series: NATO ASI Series ((ASIC,volume 435))

Abstract

Recent neutron scattering studies of the structure and single-particle dynamics of water molecules contained in micro-pores of Vycor glass and in hydrated amorphous protein powder are presented. In particular, results of neutron diffraction from D2O contained in both the Vycor glass and per-deuterated protein C-phycocyanin are analyzed to obtain the average structure factors and average pair-correlation functions as functions of the degree of hydration and temperature. Results of incoherent quasi-elastic and inelastic neutron scattering from H2O in these two same systems are analyzed to obtain the elastic incoherent structure factor (EISF), short-time self diffusion constant, resident time for jump diffusion, rotational relaxation time and proton density of states, as functions of coverage and temperature. Implications on the degree of confinement and slowing-down of the single particles motions are discussed in light of available NMR relaxation data and computer molecular dynamic simulation results.

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Author information

Authors and Affiliations

  1. Department of Nuclear Engineering, 24-211 Massachusetts Institute of Technology, Cambridge, MA, 02139, USA

    Sow-Hsin Chen

  2. Laboratoire Leon Brillouin, C.E. de Saclay, 91191, Gif sur Yvette Cedex, France

    Marie-Claire Bellissent-Funel

Authors
  1. Sow-Hsin Chen
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  2. Marie-Claire Bellissent-Funel
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Editor information

Editors and Affiliations

  1. Laboratoire Léon Brillouin (CEA/CNRS), C.E. Saclay, Gif-sur-Yvette, France

    Marie-Claire Bellissent-Funel

  2. Physics Laboratory, University of Kent at Canterbury, Canterbury, UK

    John C. Dore

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© 1994 Springer Science+Business Media Dordrecht

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Chen, SH., Bellissent-Funel, MC. (1994). Structure and Dynamics of Water in Confined Geometry. In: Bellissent-Funel, MC., Dore, J.C. (eds) Hydrogen Bond Networks. NATO ASI Series, vol 435. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8332-9_29

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  • DOI: https://doi.org/10.1007/978-94-015-8332-9_29

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4412-9

  • Online ISBN: 978-94-015-8332-9

  • eBook Packages: Springer Book Archive

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