Abstract
Sample of VX stored for a long time in glass container was investigated using GC/MS system. A variety of age decomposition products including O-alkyl and N,N-diisopropylamino- substituted thiophosphonic esters and acids as well as phosphonic anhydrides were identified. Diazomethane methylation was used to obtain derivatives convenient to GC process. Retention parameters and EI-MS spectra were obtained and presented in the paper.
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P.A. D’agostino, L.R. Provost, J. Visentini, J.Chromatogr., 402 (1987) 221–232
E.R.J. Wils, A.G. Hulst, J.Chromatogr., 532(1990) 151–161
W.K. Fowler, J.E. Smith Jr., J.Chromatogr., 478 (1989) 51–61
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© 1997 Springer Science+Business Media Dordrecht
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Sliwakowski, M. (1997). GC/MS Investigation of Ethyl S-2-diisopropyl Aminoethyl Methylphosphonothiolate (VX) Age Decomposition Products. In: Heyl, M., McGuire, R. (eds) Analytical Chemistry Associated with the Destruction of Chemical Weapons. NATO ASI Series, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5600-4_11
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DOI: https://doi.org/10.1007/978-94-011-5600-4_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6362-3
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