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Magnetic Molecular Materials

  • Book
  • © 1991

Overview

Editors:
  1. Dante Gatteschi

    1. University of Florence, Florence, Italy

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  2. Olivier Kahn

    1. University of Paris Sud, Orsay, France

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  3. Joel S. Miller

    1. Du Pont, Wilmington, USA

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  4. Fernando Palacio

    1. CSIC, University of Zaragoza, Zaragoza, Spain

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Part of the book series: NATO Science Series E: (NSSE, volume 198)

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Table of contents (28 chapters)

  1. Front Matter

    Pages i-ix
    Download chapter PDF

  2. Lectures

    1. Front Matter

      Pages 1-387
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    2. From Ferromagnetic Interactions to Molecular Ferromagnets: An Overview of Models and Materials

      • Fernando Palacio
      Pages 1-34

    3. Design of Molecular-Based Compounds Exhibiting a Spontaneous Magnetization; Strategies and Achievements

      • Olivier Kahn
      Pages 35-52

    4. An Approach to Organic Ferromagnets. Synthesis and Characterization of Polymers Due to 1-Phenyl-1, 3-Butadiynes Carrying a Substituent in Doublet or Triplet State on the Phenyl Ring

      • H. Iwamura, S. Sasaki, N. Sasagawa, K. Inoue, N. Koga
      Pages 53-66

    5. Magnetic Coupling in High Spin Carbenes

      • Koichi Itoh
      Pages 67-86

    6. Intermolecular Ferromagnetic Coupling in Organic Radical Crystals

      • Minoru Kinoshita
      Pages 87-103

    7. Approaches to Magnetic Organic Materials

      • D. A. Dougherty, R. H. Grubbs, D. A. Kaisaki, W. Chang, S. J. Jacobs, D. A. Shultz et al.
      Pages 105-120

    8. Stable Polyradicals with High Spin Ground States

      • J. Veciana, C. Rovira
      Pages 121-132

    9. Superdegeneracies and Orbital Delocalization in Extended Organic Systems

      • Timothy Hughbanks, Kyeong Ae Yee
      Pages 133-144

    10. Magnetism of Radical Cation Salts Based on the Organic Donor Tetramethoxy-Hexa-Meta-Phenylene

      • T. Bjørnholm, K. Bechgaard, P. Sommer-Larsen, G. Rindorf, N. Thorup
      Pages 145-149

    11. Recent Advances in the Structure-Magnetic Coupling Relationships for Metallocene-Acceptor Based Electron Transfer Complexes

      • Joel S. Miller, Arthur J. Epstein
      Pages 151-158

    12. Physics of the 1-D Molecular Ferromagnet Decamethylferrocenium Tetracyanoethanide, [DMeFc].+[TCNE].-

      • Arthur J. Epstein, Joel S. Miller
      Pages 159-169

    13. Models for Magnetic Coupling in Metallocene Based Donor/Acceptor Complexes

      • David A. Dixon, Andris Suna, Joel S. Miller, Arthur J. Epstein
      Pages 171-190

    14. Magnetic Properties of Some Biradicals of D2d (or Approximate D2d) Symmetry, Extended-Dioxygen Analogs

      • A. Rassat, R. Chiarelli
      Pages 191-202

    15. Coordination Chemistry of the Imino Nitroxides. Ferromagnetic Behavior of Some First Row Transition Metal Complexes

      • P. Rey, D. Luneau, A. Cogne
      Pages 203-214

    16. Structural Magnetic Correlations in Phase Transitions of Molecular Magnets

      • Andrea Caneschi, Dante Gatteschi, Roberta Sessoli
      Pages 215-232

    17. Magnetic Molecular Materials Containing Rare Earths

      • C. Benelli, A. Caneschi, D. Gatteschi, L. Pardi
      Pages 233-244

    18. Magnetism of Liquid Crystals

      • W. Haase, B. Borchers
      Pages 245-253

    19. Molecular Ferromagnetism in Organic and Inorganic Complexes; Influence of Orbital Effects

      • M. Drillon, J. L. Paillaud, P. Legoll
      Pages 255-266
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Keywords

About this book

One of the major challenges of science in the last few years of the second millennium is learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the possibilities of success are not ne~li~ble provided that all the different expertises merge to overcome the limits of eXIsting disciplines and forming new paradigms science. The NATO Advanced Research Workshop on "Magnetic Molecular Materials" was organized with the above considerations in mind in order to determine which are the most appropriate synthetic strategies, experimental techniques of investigation, and theoretical models which are needed in order to develop new classes of magnetic materials which are based on molecules rather than on metallic or ionic lattices. Why molecules? The answer may be obvious: molecular chemistry in principle fine can tune the structures and the properties of complex aggregates, and nature already provides a large number of molecular aggregates which can perform the most disparate functions. The contributions collected in this book provide a rather complete view of the current research accomplishments of magnetic molecular materials. There are several different synthetic approaches which are followed ranging from purely organic to inorganic materials. Some encouraging successes have already been achieved, even if the critical temperatures below which magnetic order is observed still are in the range requiring liquid helium.

Editors and Affiliations

  • University of Florence, Florence, Italy

    Dante Gatteschi

  • University of Paris Sud, Orsay, France

    Olivier Kahn

  • Du Pont, Wilmington, USA

    Joel S. Miller

  • CSIC, University of Zaragoza, Zaragoza, Spain

    Fernando Palacio

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