Abstract
The pie chart in Fig. 14-1 indicates the abundance of Fe relative to other major elements in the earth’s crust. It is the only one of the nine to bear a magnetic moment in its compounds. The bar chart compares the abundance of Fe with that of other magnetic ions, on a logarithmic scale. Since Fe is approximately forty times more abundant than all the others put together, it follows that magnetic properties of soils and clay minerals derive essentially from the Fe they contain. Magnetic measurements are highly specific to Fe, but, as we shall see, they are much more sensitive to some mineral forms (e.g., magnetite, maghemite, pyrrhotite) than to others.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Literature Cited
Artman, J. O., J. C. Murphy, and S. Foner. 1965. Magnetic anisotropy in antiferromagnetic corundum-type sesquioxides. Phys. Rev. 138:A912-A917.
Bacon, G.E. 1979. Neutron Diffraction, pp. 1–135. In G. M. Kalvius and R. S. Teble (eds.) Experimental Magnetism, Vol. 1. Wiley, Chichester.
Ballet, O. 1979. Fe2+ dans les silicates lamellaires--etude magnetique et Mössbauer. Thèse de Troisième Cycle, Université de Grenoble.
Ballet, O., and J. M. D. Coey. 1982. Magnetic properties of sheet silicates: 2:1 layer minerals. Phys. Chem. Miner. 8:218–229.
Ballet, O., J. M. D. Coey, P. Mangin, and M. G. Townsend. 1985a. Ferrous talc — a planar antiferromagnet. Solid State Comm. 55:787–790.
Ballet, O., J. M. D. Coey, and K. J. Burke. 1985b. Magnetic properties of sheet silicates: 2:1:1 layer minerals. Phys. Chem. Miner. 12:370–378.
Beausoleil, N., P. Lavallée, A. Yelon, O. Ballet, and J. M. D. Coey. 1983. Magnetic properties of biotite micas. J. Appl. Phys. 54:906–915.
Besser, P. J., A. H. Morrish, and C. W. Searle. 1967. Magnetocrys-talline anisotropy of pure and doped hematite. Phys. Rev 153:632–640.
Bonnin, D. 1981. Propriétés magnetiques liées aux desordres bidimensionnels dans un silicate lamellaire ferrique: la nontronite. Etude par spectrometrie Môssbauer, resonances magnetiques, magnetisme et EXAFS. These d’Etat, Université Pierre et Marie Curie, Paris.
Bleaney, R., and K. W. H. Stevens. 1953. Paramagnetic resonance. Rep. Prog. Phys. 16:131–136.
Burns, R. G. 1980. Does feroxyhite occur on the surface of Mars? Nature 285:647.
Carlin, R. L., and A. J. van Duyneveldt. 1977. Magnetic Properties of Transition Metal Compounds. Springer, Berlin.
Christensen, H., and A. N. Christensen. 1978. Hydrogen bonds in FeOOH. Acta Chem. Scand. A32:87–88.
Coey, J. M. D. 1971. Non-collinear spin arrangement in ultrafine ferrimagnetic crystallites. Phys. Rev. Letters 27:1140–1142.
Coey, J. M. D., A. H. Morrish, and G. A. Sawatzky. 1971. A Môssbauer study of conduction in magnetite. J Phys. 32, CI: 271–273.
Coey, J. M. D., and D. Khalafalla. 1972. Superparamagnetic γFe2O3. Phys. Stat. Sol. A11:229–241.
Coey, J. M. D., and P. W. Readman. 1973a. New spin structure in an amorphous ferric gel. Nature 246:476–478.
Coey, J. M. D., and P. W. Readman. 1973b. Characterisation and magnetic properties of natural ferric gel. Earth Planetary Sci. Lett. 21:45–51.
Coey, J. M. D. 1980. Clay minerals and their transformations studied with nuclear techniques. At. Energy Rev. 18:73–124.
Coey, J. M. D., O. Ballet, A. Moukarika, and J. L. Soubeyroux. 1981. Magnetic properties of sheet silicates: 1:1 layer minerals. Phys. Chem. Miner. 7:141–148.
Coey, J. M. D., A. Moukarika, and C. M. Monagh. 1982. Electron hopping in cronstedtite. Solid State Comm. 41:797–800.
Coey, J. M. D. 1984. Mössbauer spectroscopy of silicate minerals, p. 443–509. In G. J. Long (ed.) Mössbauer Spectroscopy Applied to Inorganic Chemistry, Vol. 1. Plenum, New York.
Crangle, J. 1977. The Magnetic Properties of Solids. Arnold, London.
Curi, N., and D. P. Franzmeier. 1984. Toposequence of oxisols from the central plateau of Brazil. Soil Sci. Soc. Am. J. 48:341–346.
de Grave, E., L. H. Bowen, and S. B. Weed. 1982. Mössbauer study of aluminum-substituted hematites. J. Magn. Mag. Mat. 27:98–108.
Fleisch, J., R. Grimm, J. GrĂ¼bler, and P. Gutlich. 1980. Determination of the aluminium content of natural and synthetic aluminogoethites. J. Phys. 41, CI: 160–170.
Forsyth, J. B., I. G. Hedley, and C. E. Johnson. 1968. The magnetic structure and hyperfine field of goethite (αFeOOH). J. Phys. 29, CI: 179–188.
Fysh, S. A., J. D. Cashion, and P. E. Clark. 1983. Mössbauer effect studies of iron in kaolin. Clays Clay Miner. 31:285–292.
Gibb, T. C. 1985. Introduction to Mössbauer Spectroscopy. Chapman and Hall, London.
Goodenough, J. B. 1963. Magnetism and the Chemical Bond. Wiley-Interscience, New York.
Goodenough, J. B. 1980. The Verwey transition revisited, p. 413–425. In D. B. Brown (ed.) Mixed Valence Compounds. D. Reidel, Dordrecht.
Goodman, B. A. 1980. Mössbauer Spectroscopy in Advanced Chemical Methods for Soil and Clay Mineral Research, p. 1–92. In J. W. Stucki and W. L. Banwart (eds.) D. Reidel, Dordrecht.
Groupe de Diffusion des Neutrons. 1971. Experimental determination of exchange integrals in magnetite. J. Phys. 32, CI:1182–1183.
Hallam, A. 1973. A Revolution in the Earth Sciences. Oxford University Press, Oxford.
Hedley, I. G. 1971. The weak ferromagnetism of goethite (αFeOOH). Z. Geophys. 37:409–420.
Heller-Kallai, L., and I. Rozenson. 1981. The use of Mössbauer spectroscopy of iron in clay mineralogy. Phys. Chem. Miner. 7:223–23.
Hutchings, M. T. 1964. Point-charge calculations of energy levels of magnetic ions in crystalline electric fields. Solid State Phys. 16: 227–273.
Ingalls, R. 1964. Electric field gradient tensor in ferrous compounds. Phys. Rev. 133 (3A):A787-A795.
Lindsley, D. H. 1976. The crystal chemistry and structure of oxide minerals as exemplified by the Fe-Ti oxides, p. 1–52. In D. Rumble (ed.) Oxide Minerals. Reviews in Mineralogy, Vol. 3. Mineralogical Society of America, Washington, D. C.
Martin, D. H. 1967. Magnetism in Solids. Iliffe, London.
Moorjani, K., and J. M. D. Coey. 1984. Magnetic Glasses. Elsevier, Amsterdam.
Mørup, S. 1983. Magnetic hyperfine splitting in Mössbauer spectra of microcrystals. J. Magn. Mag. Mat. 37:39–50.
Mørup, S., J. A. Dumesic, and H. Topsøe. 1980. Magnetic micro-crystals. p. 1–45. In R. L. Cohen (ed.) Applications of Mössbauer Spectroscopy. Vol. 2. Academic Press, New York.
Miyamoto, H. 1976. The magnetic properties of Fe(OH)2. Mat. Res. Bull. 11:329–336.
Mullins, C. E. 1977. Magnetic susceptibility of the soil and its significance in soil science - a review. J. Soil Sci. 28:223–246.
Murad, E. 1979. Mossbauer and X-ray data on OH. Clay Miner. 14: 273–283.
Murad, E. 1987. Characterization of Fe oxides by Mossbauer spectroscopy. p. 309–350. In Joseph W. Stucki, Bernard A. Goodman, and Udo Schwertmann (eds.) Iron in Soils and Clay Minerals. D. Reidel, Dordrecht. (This Volume)
Murad, E., and U. Schwertmann. 1980. The Mossbauer spectrum of ferrihydrite and its relation to those of other iron oxides. Am. Mineral. 65:1044–1049.
Murad, E., and U. Schwertmann. 1984. The influence of crystallinity on the Mossbauer spectrum of lepidocrocite. Mineral. Mag. 48:507–511
Néel, L. 1949. Théorie de l’aimantation thermoremanente. Ann. Geophys. 5:99–150.
Nishitani, T., and M. Kono. 1983. Curie temperature and lattice constant of oxidized titanomagnetite. Geophys. J. Royal Ast. Soc. 74:585–600.
Okamoto, S. 1968. Structure of δFOH. J. Am. Ceram. Soc. 51: 594–599.
O’Reilly, W. 1984. Rock and Mineral Magnetism. Blackie, Glasgow.
Parkomenko, E. I. 1982. Electrical resistivity of minerals and rocks at high temperature and pressure. Rev. Geophys. Space Phys. 20: 193–218.
Pernet, M., X. Obradors, J. Fontcuberta, J. C. Joubert, and J. Tejada. 1984. Magnetic structure and superparamagnetic properties of δFOH. IEEE Trans. Mag., MAG 20:1524–1525.
Readman, P. W., and W. O’Reilly. 1972. Magnetic properties of oxidized titanomagnetites (Fe,Ti)3O4. J. Geomag. Geoelectr. 24:69–90.
Resende, M., J. M. D. Coey, and J. E. M. Allan. 1986. The Magnetic Soils of Brazil. Earth Planet. Sci. Lett. 78:322–326.
Samuelson, E. J., and G. Shirane. 1970. Inelastic neutron scattering investigation of spin waves and magnetic interactions in Fe2O3. Phys. Stat. Sol. 42:241.
Shirane, G., S. J. Pickart, R. Nathans, and Y. Ishikawa. 1959. Neutron diffraction study of antiferromagnetic FeTi03 and its solid solution with αFe2O3. J. Phys. Chem. Solids 10:35–43.
Smart, J. S. 1966. Effective Field Theories of Magnetism. Saunders, Philadelphia.
Spender, M. R., J. M. D. Coey, and A. H. Morrish. 1972. The magnetic properties and Mossbauer spectra of synthetic samples of Fe3S4. Can. J. Phys. 50:2313–2326.
Stryjewski, E., and N. Giordani. 1977. Metamagnetism. Adv. Phys. 26:487–650.
Townsend, M. G., A. H. Webster, J. L. Harwood, and H. Roux-Buisson. 1979. Ferrimagnetic transition in Fe0.9S: magnetic, thermodynamic and kinetic aspects. J. Phys. Chem. Solids 40: 183–189.
Turner, G. M., and R. Thompson. 1981. Lake sediment record of the secular geomagnetic variation in Britain during holocene times. Geophys. J. Royal Astr. Soc. 65:703–725.
Varret, F. 1976. Crystal field effects on high-spin ferrous iron. J. Phys. 37, C6:437–456.
Wertheim, G. K. 1984. Mössbauer Effect: Principles and Applications. Academic Press, New York.
Young, A. P. 1981. Renormalization Group Theory and magnetic phase transitions, p. 393–436. In A. P. Cracknell and R. A. Vaughan (eds.) Magnetism in Solids. SUSSP, Edinburgh.
Zallen, R. 1983. The Physics of Amorphous Solids. Wiley-Interscience, New York.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1988 D. Reidel Publishing Company, Dordrecht, Holland
About this chapter
Cite this chapter
Coey, J.M.D. (1988). Magnetic Properties of Iron in Soil Iron Oxides and Clay Minerals. In: Stucki, J.W., Goodman, B.A., Schwertmann, U. (eds) Iron in Soils and Clay Minerals. NATO ASI Series, vol 217. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4007-9_14
Download citation
DOI: https://doi.org/10.1007/978-94-009-4007-9_14
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8278-5
Online ISBN: 978-94-009-4007-9
eBook Packages: Springer Book Archive