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Experimental Studies of Compressed Fluids

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High Pressure Chemistry and Biochemistry

Part of the book series: NATO ASI Series ((ASIC,volume 197))

Abstract

With high pressures at elevated and supercritical temperatures fluids can be studied over a very wide range of density. Fluids with strongly interacting polar molecules - for example water - are of particular interest. Results for several thermophysical properties are presented. PVT-data of sodium, high pressure-high temperature viscosity of decane and the dielectric constant of supercritical water-benzene mixtures are discussed. The continuous transition from ionic to metallic states is shown with the cesium-cesium hydride system to 800 °C. High pressure far-infrared spectroscopy reveals the dynamics of compressed polar methyl halides. Quantitative determinations of the solubility of solids in dense supercritical gases are presented. A number of phase diagrams and critical curves of binary aqueous systems to 400 °C and 2000 bar have been determined. A new rational equation of state for such systems is presented. “Hydrothermal” combustion of methane in supercritical water is possible and a flame, burning at 1000 bar is shown.

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Author information

Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Karlsruhe, Kaiserstraße 12, D7500, Karlsruhe, Federal Republic of Germany

    E. U. Franck

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  1. E. U. Franck
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Editors and Affiliations

  1. Institute for Physical and Theoretical Chemistry, Johann Wolfgang Goethe University, Frankfurt am Main, Germany

    R. van Eldik

  2. Department of Chemistry, University of Illinois, Urbana, Illinois, USA

    J. Jonas

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© 1987 D. Reidel Publishing Company

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Franck, E.U. (1987). Experimental Studies of Compressed Fluids. In: van Eldik, R., Jonas, J. (eds) High Pressure Chemistry and Biochemistry. NATO ASI Series, vol 197. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3827-4_4

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  • DOI: https://doi.org/10.1007/978-94-009-3827-4_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8203-7

  • Online ISBN: 978-94-009-3827-4

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