Skip to main content

Coupled Reaction and Flow in Subduction Zones: Silica Metasomatism in the Mantle Wedge

  • Chapter
Fluid Flow and Transport in Rocks

Abstract

Large quantities of H2O are carried to great depth during subduction of sediment and hydrated oceanic crust. Much of this H2O is bound in hydrous minerals. When dehydration reactions proceed, the liberated fluid may migrate back up the slab or into the overlying mantle wedge (e.g. Peacock, 1990a, 1993a,b; Bebout, 1991a,b). Regardless of the fluid’s trajectory, the strong dependence of mineral solubility on pressure and temperature suggests that this flow may lead to extensive metasomatism. This is supported by field and analytical data, which show that metasomatic redistribution of elements is common in subduction-zone settings (Moore, Liou and King, 1981; Wyllie and Sekine, 1982; Tatsumi, Hamilton and Nesbitt, 1986; Sorenson and Barton, 1987; Sorenson, 1988; Bebout and Barton, 1989, 1993).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Baumgartner, L. P. and Ferry, J. M. (1991) A model for coupled fluid-flow and mixed-volatile mineral reactions with applications to regional metamorphism. Contributions to Mineralalogy and Petrology, 106, 273–85.

    Article  Google Scholar 

  • Bebout, G. E. (1991a) Geometry and mechanisms of fluid flow at 15 to 45 kilometer depths in an early Cretaceous accretionary complex. Geophysical Research Letters, 18, 923–6.

    Article  Google Scholar 

  • Bebout, G. E. (1991b) Field-based evidence for devolatilization in subdivision zones: implications for arc magmatism. Science, 251, 413–16.

    Article  Google Scholar 

  • Bebout, G. E. and Barton, M. D. (1989) Fluid flow and metasomatism in a subduction zone hydrothermal system: Catalina Schist terrane, California. Geology, 17, 976–80.

    Article  Google Scholar 

  • Bebout, G. E. and Barton, M. D. (1993) Metasomatism during subduction: Products and possible paths in the Catalina Schist, California. Chemical Geology, 108, 61–92.

    Article  Google Scholar 

  • Berman, R. G. (1988) Internally-consistent thermodynamic data for minerals in the system Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2. Journal of Petrology, 29, 445–522.

    Google Scholar 

  • Berman, R. G., Engi, M., Greenwood, H. J. and Brown, T. H. (1986) Derivation of internally-consistent thermodynamic data by the technique of mathematical programming: A review with application to the system MgO-SiO2-H2O. Journal of Petrology, 27, 1331–64.

    Google Scholar 

  • Chernosky, J. V. (1975) Aggregate refractive indices and unit cell parameters of synthetic serpentine in the system MgO-Al2O3-SiO2-H2O. American Mineralogist, 60, 200–8.

    Google Scholar 

  • Chernosky, J. V., Berman, R. G. and Bryndzia, L. T. (1988) Stability, phase relations, and thermodynamic properties of chlorite and serpentine group minerals, in Hydrous Phyllosilicates (Exclusive of Micas) (ed. S. W. Bailey), Reviews in Mineralogy, 19, 293–346.

    Google Scholar 

  • Davies, J. H. and Stevenson, D. J. (1992) Physical model of source region of subduction zone volcanics. Journal of Geophysical Research, 97, 2037–70.

    Article  Google Scholar 

  • Dick, H. J. B., Fisher, R. L. and Bryan, W. B. (1984) Mineralogie variability of the uppermost mantle along mid-ocean ridges. Earth and Planetary Science Letters, 69, 88–106.

    Article  Google Scholar 

  • Ernst, W. G. (1990) Thermobarometric and fluid expulsion history of subduction zones. Journal of Geophysical Research, 95, 9047–53.

    Article  Google Scholar 

  • Evans, B. W. and Guggenheim, S. (1988) Talc, pyrophyllite, and related minerals, in Hydrous Phyllosilicates (Exclusive of Micas) (ed. S. W. Bailey), Reviews in Mineralogy, 19, 225–94.

    Google Scholar 

  • Ferry, J. M. (1995) Reply to comment by R. Brooks Hanson on “Role of fluid flow in the contact metamorphism of siliceous dolomitic limestones”. American Mineralogist, 80, 1226–8.

    Google Scholar 

  • Grove, M. and Bebout, G. E. (1995) Jurassic and Cretaceous tectonic evolution of coastal southern California: Insights from the Catalina schist. Tectonics, 14, 1290–1308.

    Article  Google Scholar 

  • Haar, L., Gallagher, J. S. and Kell, G. S. (1984) NBS/NRC Steam Tables, Hemisphere, New York.

    Google Scholar 

  • Hanson, R. B. (1995) Comment on “Role of fluid flow in the contact metamorphism of siliceous dolomitic limestones” by John M. Ferry: Conservation of energy in applications of reaction-flow models. American Mineralogist, 80, 1222–5.

    Google Scholar 

  • Hemley, J. J., Montoya, J. W., Christ, C. L. and Hostetier, P.B. (1977a) Mineral equilibria in the MgO-SiO2-H2O system: I Talc—chrysotile—forsterite—brucite stability relations. American Journal of Science, 277, 322–51.

    Article  Google Scholar 

  • Hemley, J. J., Montoya, J. W., Shaw, D. R. and Luce, R. W. (1977b) Mineral equilibria in the MgO-SiO2-H2O system: II Talc—antigorite—forsterite—anthophyllite—enstatite stability relations and some geologic implications in the system. American Journal of Science, 277, 322–51.

    Article  Google Scholar 

  • Manning, C. E. (1994) The solubility of quartz in H2O in the lower crust and upper mantle. Geochimica et Cosmochimica Acta, 58, 4831–9.

    Article  Google Scholar 

  • Manning, C. E. (1996a) Effect of sediments on aqueous silica transport in subduction zones, in Dynamics of Subduction (eds G. E. Bebout et al.), American Geophysical Union Monograph, in press.

    Google Scholar 

  • Manning, C. E. (1996b) Phase-equilibrium controls on SiO2 metasomatism by aqueous fluid in subduction zones: reaction at constant pressure and temperature. International Geology Review, submitted.

    Google Scholar 

  • Moore, D. E., Liou, J. G. and King, B.-S. (1981) Chemical modifications accompanying blueschist facies metamorphism of Franciscan conglomerates, Diablo Range, California. Chemical Geology, 33, 237–63.

    Article  Google Scholar 

  • Peacock, S. M. (1990a) Fluid processes in subduction zones. Science, 248, 329–37.

    Article  Google Scholar 

  • Peacock, S. M. (1990b) Numerical simulation of metamorphic pressure-temperature-time paths and fluid production in subducting slabs. Tectonics, 9, 1197–211.

    Article  Google Scholar 

  • Peacock, S. M. (1993a) The importance of blueschist → eclogite dehydration reactions in subducting oceanic slabs. Geological Society of America Bulletin, 105, 684–94.

    Article  Google Scholar 

  • Peacock, S. M. (1993b) Large-scale hydration of the lithosphere above subducting slabs. Chemical Geology, 108, 49–59.

    Article  Google Scholar 

  • Peacock, S. M., Rushmer, T. and Thompson, A. B. (1994) Partial melting of subducting oceanic crust. Earth and Planetary Science Letters, 121, 227–44.

    Article  Google Scholar 

  • Sorenson, S. S. (1988) Petrology of amphibolite-facies mafic and ultramafic rocks from the Catalina Schist, southern California: metasomatism and migmatization in a subduction zone metamorphic setting. Journal of Metamorphic Geology, 6, 405–35.

    Article  Google Scholar 

  • Sorenson, S. S. and Barton, M. D. (1987) Metasomatism and partial melting in a subduction complex: Catalina Schist, southern California. Geology, 15, 115–18.

    Article  Google Scholar 

  • Tatsumi, Y., Hamilton, D. L. and Nesbitt, R. W. (1986) Chemical characteristics of fluid phase released from a subducted lithosphere and origin of arc magmas: evidence from high-pressure experiments and natural rocks. Journal of Volcanology and Geothermal Research, 29, 293–309.

    Article  Google Scholar 

  • Thompson, A. B. and Connolly, J. A. D. (1992) Migration of metamorphic fluid: some aspects of mass and heat transfer. Earth Science Reviews, 32, 107–21.

    Article  Google Scholar 

  • Walther, J. V. and Helgeson, H. C. (1977) Calculation of the thermodynamic properties of aqueous silica and the solubility of quartz and its polymorphs at high pressures and temperatures. American Journal of Science, 277, 1315–51.

    Article  Google Scholar 

  • Wicks, F. J. and O’Hanley, D. S. (1988) Serpentine minerals: structures and petrology, in Hydrous Phyllosilicates (Exclusive of Micas) (ed. S.W. Bailey), Reviews of Mineralogy, 19, 91–167.

    Google Scholar 

  • Wyllie, P. J. and Sekine, T. (1982) The formation of mantle phlogopite in subduction zone hybridization. Contributions to Mineralogy and Petrology, 79, 375–80.

    Article  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Chapman & Hall

About this chapter

Cite this chapter

Manning, C.E. (1997). Coupled Reaction and Flow in Subduction Zones: Silica Metasomatism in the Mantle Wedge. In: Jamtveit, B., Yardley, B.W.D. (eds) Fluid Flow and Transport in Rocks. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1533-6_8

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-1533-6_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7184-0

  • Online ISBN: 978-94-009-1533-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics