Skip to main content

Elements No. 70, 71 and 72: Discoveries and Controversies

  • Chapter
Episodes from the History of the Rare Earth Elements

Part of the book series: Chemists and Chemistry ((CACH,volume 15))

Abstract

The history of the discovery of the two last rare earth elements, ytterbium and lutetium, is a history of two priority disputes separated by a period of 16 years. The principal concern of the later and more bitter controversy was element 72, which is not a rare earth, but a zirconium homologue. Nonetheless, from a historical point of view the discovery of hafnium is an integral part of the discovery histories of the rare earths, which would be incomplete without hafnium. The two main contestants in the priority disputes, Georges Urbain and Carl Auer von Welsbach, were specialists in rare earth chemistry and highly regarded for their many contributions to this branch of chemistry. As an indication of their stature in the chemical community, both were nominated several times for a Nobel prize. Auer was nominated 10 times between 1918 and 1929, and Urbain 56 times between 1912 and 1936 (Crawford et al. 1987). All of Auer’s nominations came from either Germans or Austrians, and almost all of Urbain’s nominations were French. Their disagreements over the discoveries of elements did not, apparently, hurt their reputation. But it may well have contributed to the Swedish Nobel Committee’s decision not to award either of them the valued award.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Auer von Welsbach, C. (1905), “Vorläufiger Bericht über die Zerlegung des Ytterbiums in seine Elemente,” Anzeiger der mathematisch-naturwissenschaftliche Klasse der kaiserlische Akademie der Wissenschaften 42, 122.

    Google Scholar 

  • Auer von Welsbach, C. (1906a), “Über die Elemente der Yttergruppe,” Sitzungsberichte der mathematisch-naturwissenschaftliche Klasse der kaiserlische Akademie der Wissenschaften 115, IIb, 737–47.

    Google Scholar 

  • Auer von Welsbach, C. (1906b), “Bemerkungen Ober die Anwendung der Funkenspectren bei Homogenitätsprüfungen,” [Liebig’s] Annalen der Chemie 351, 458–66

    Google Scholar 

  • Auer von Welsbach, C. (1907), “Die Zerlegung des Ytterbiums in seine Elemente,” Sitzungsberichte der mathematisch-naturwissenschaftliche Klasse der kaiserlische Akademie der Wissenschaften 116, IIb, 1425–69.

    Google Scholar 

  • Auer von Welsbach, C. (1910), “Zur Zerlegung des Ytterbiums,” Sitzungsberichte der mathematisch-naturwissenschaftliche Klasse der kaiserlische Akademie der Wissenschaften 118, IIb, 507–12.

    Google Scholar 

  • Auer von Welsbach, C. (1926), “Über einige Versuche zur Auffindung des Elementes Nr. 61,” Chemiker-Zeitung 50, 990.

    Google Scholar 

  • Bassett, H. (1892), “A tabular expression of the periodic relations of the elements,” Chemical News 65, 3–4, 19.

    Google Scholar 

  • Benedicks, C. (1904), “Über die Atomvolumina der seltenen Erden und deren Bedeutung für das periodische System,” Zeitschrift fur anorganische Chemie 39, 41–48.

    Article  Google Scholar 

  • Bohr, N. (1922), “The structure of the atom,” pp. 7–44 in Nobel Lectures, Physics, 1922–1941 ( Amsterdam: Elsevier, 1965 ).

    Google Scholar 

  • Bohr, N. and Coster, D. (1922), “Röntgenspektren und periodisches System der Elemente,” Zeitschrift für Physik 12, 342–37.

    Article  Google Scholar 

  • Brannigan, A. (1981), The Social Basis of Scientific Discoveries ( Cambridge: Cambridge University Press).

    Google Scholar 

  • Brante, T. and Elzinga, A. (1990), “Towards a theory of scientific controversies,” Science Studies 3: 2, 33–46.

    Google Scholar 

  • Brauner, B. (1902), “Über die Stellung der Elemente der seltenen Erden im periodischen System von Mendelejeff,” Zeitschriftfür anorganische Chemie 32, 1–30.

    Article  Google Scholar 

  • Brauner, B. (1908), “Über die Stellung der Elemente der seltenen Erden im periodischen System,” Zeitschriftfür Elektrochemie 14, 525–28.

    Article  CAS  Google Scholar 

  • Brauner, B. (1923), “Hafnium or celtium,” Chemistry & Industry 42, 884–85.

    Article  CAS  Google Scholar 

  • Clarke, F. W. et al. (1909), “Report of the Intemational Committee on Atomic Weights, 1909,” Journal of the American Chemical Society 31, 1–6.

    Article  CAS  Google Scholar 

  • Coster, D. and Hevesy, G. (1923a), “On the missing element of atomic number 72,” Nature 111, 79.

    Article  CAS  Google Scholar 

  • Coster, D. and Hevesy, G. (1923b), “On celtium and hafnium,” Nature 111, 462–63.

    Article  CAS  Google Scholar 

  • Crawford, E., Heilbron, J. L. and Ullrich, R. (1987), The Nobel Population 1901–1937 ( Berkeley: Office for History of Science and Technology ).

    Google Scholar 

  • Crookes, W. (1888), “Elements and meta-elements,” Journal of the Chemical Society 53, 487–504.

    Google Scholar 

  • D’Ans, J. (1931), “Carl Freiherr Auer von Welsbach,” Berichte der deutsche chemische Gesellschaft 64, 59–92.

    Article  Google Scholar 

  • Dauvillier, A. (1922), “Sur les séries L du lutécium et de l’ytterbium et sur l’identification du celtium avec l’élément de nombre atomique 72,” Comptes Rendus 174, 1347–49.

    CAS  Google Scholar 

  • Demarçay, E. A. (1900), “Les spectres du samarium et du gadolinium,” Comptes Rendus 131, 387–90.

    Google Scholar 

  • Eder, J. M. (1915), “Der Bogenspektrum des Cassiopeiums, Aldebaraniums, Erbiums und des in weitere Elemente gespaltenen Thuliums,” Sitzungsberichte der mathematisch-naturwissenschaftliche Klasse der kaiserliche Akademie der Wissenschaften 124, IIa, 707–828.

    Google Scholar 

  • Eder, J. M. (1923), “Die Spektralanalyse der seltenen Erden,” Annalen der Physik 71, 12–18.

    Article  CAS  Google Scholar 

  • Exner, F. and Haschek, E. (1899), “Über die ultravioletten Funkenspektra der Elemente,” Sitzungsberichte der mathematisch-natuHwissensthaft[ithe Klasse der kaiserliche Akademie der Wissenschaften 108, IIa, 1123–51.

    Google Scholar 

  • Exner, F. and Haschek, E. (1904), We11enIängetabellenfür Spektralanalytische Untersuchungen auf Grund der Ultravioletten Bogenspektren der Elemente (Vienna: F. Deuticke).

    Google Scholar 

  • Exner, F. and Haschek, E. (1911), Spektraltafeln (Vienna: F. Deuticke).

    Google Scholar 

  • Figurowski, N. (1981), Die Entdeckung der chemischen Elemente und der Ursprung ihrer Namen (Köln: Aulis Verlag).

    Google Scholar 

  • Friman, E. (1916), “On the high-frequency spectra (L-series) of the elements lutecium-zinc,” Philosophical Magazine 32, 497.

    CAS  Google Scholar 

  • Hansen, H. M. and Werner, S. (1923), “On Urbain’s celtium lines,” Nature 111, 461.

    Article  Google Scholar 

  • Heilbron, J. L. (1974), H. G. J. Moseley. The Life and Letters of an English Physicist 1887–1915 (Berkeley: University of California Press).

    Google Scholar 

  • Heimann, P. M. (1967), “Moseley and celtium: The search for a missing element,” Annals of Science 23, 249–60.

    Article  CAS  Google Scholar 

  • Hevesy, G. (1925), “Recherches sur les propriétés du Hafnium,” Kongelige Danske Videnskabernes Selskab Meddelelser, VI: 7, 1–147.

    Google Scholar 

  • Hevesy, G. (1927a), Die Seltenen Erden vom Standpunkte des Atombaues (Berlin: Julius Springer).

    Google Scholar 

  • Hevesy, G. (1927b), Das Element Hafnium (Berlin: Julius Springer).

    Google Scholar 

  • Hönigschmid, O. et al. (1924), “Vierter Bericht der Deutschen Atomgewichtskommission,” Berichte der deutschen chemische Gesellschaft 57 B, I-XXXVI.

    Google Scholar 

  • Iddles, H. A. (1930), “The Charles James Hall of Chemistry of the University of New Hampshire,” Journal of Chemical Education 7, 812–20.

    Article  CAS  Google Scholar 

  • JACS (1925), Journal of the American Chemical Society 47, 597.

    Article  Google Scholar 

  • JACS (1931), Journal of the American Chemical Society 53, 1627.

    Article  Google Scholar 

  • Job, P. (1939), “Notice sur la Vie et les Travaux de Georges Urbain,” Bulletin de la Societé Chimique de France 6, 744–66.

    Google Scholar 

  • Karpenko, V. (1980), “The discovery of supposed new elements: two centuries of errors,” Ambix 27, 77–102.

    CAS  Google Scholar 

  • Kragh, H. (1979), “Niels Bohr’s second atomic theory,” Historical Studies in the Physical Sciences 10, 123–86.

    Google Scholar 

  • Kragh, H. (1980), “Anatomy of a priority conflict: The case of element 72,” Centaurus 23, 275–301.

    Article  Google Scholar 

  • Kragh, H. (1982), “Julius Thomsen and 19th-century speculations on the complexity of atoms,” Annals of Science 39, 37–60.

    Article  CAS  Google Scholar 

  • Kragh, H. and Robertson, P. (1979), “on the discovery of element 72,” Journal of Chemical Education 56, 456–59.

    Article  CAS  Google Scholar 

  • Kragh, H. (1987), An Introduction to the Historiography of Science (Cambridge: Cambridge University Press).

    Book  Google Scholar 

  • Mellor, J. W. (1924), A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Vol. 5 (London: Longmans, Green & Co.)

    Google Scholar 

  • Mel’nikov, V. P. (1983), “Some details in the prehistory of the discovery of element 72,” Centaurus 26, 317–22.

    Article  Google Scholar 

  • Meyer, S. (1908), “Magnetisiergszahlen seltener Erden,” Sitzungsberichte der mathematisch-naturwissenschaftliche Klasse der kaiserliche Akademie der Wissenschaften 117, IIa, 955–61.

    Google Scholar 

  • Nature (1914), Nature, 94, 353.

    Google Scholar 

  • Nishina, Y. (1925), “On the L-absorption spectra of the elements from Sn(50) to W(74) and their relation to the atomic constitution,” Philosophical Magazine 49, 521–37.

    CAS  Google Scholar 

  • Paneth, F. (1922), “Das periodische System der chemischen Elemente,” Ergebnisse der exakten Naturwissenschaften 1, 362–402.

    Article  Google Scholar 

  • Paneth, F. (1923), “Über das Element 72 (Hafnium),” Ergebnisse der exakten Naturwissenschaften 2, 163–76.

    Article  Google Scholar 

  • Partington, J. R. (1972), A History of Chemistry, Vol. 4 (London: Macmillan ).

    Google Scholar 

  • Perrin, J. et al. (1939), Hommage à Georges Urbain (Paris: Hermann & Cie.).

    Google Scholar 

  • Rancke-Madsen, E. (1975), “The discovery of an element,” Centaurus 19, 299–313.

    Article  CAS  Google Scholar 

  • Retgers, J. W. (1895), “Beiträge zur Kenntnis des Isomorphismus, XI,” Zeitschrift für physikalische Chemie 16, 577–658.

    Google Scholar 

  • Rose, H. (1926), Das Hafnium (Braunschweig: Vieweg & Sohn).

    Google Scholar 

  • Rudorf, G. (1904), Das periodische System. Seine Geschichte und Bedeutungfür die chemische Systematik (Hamburg: L. Voss).

    Google Scholar 

  • Rutherford, E. (1922), “Identification of a missing element,” Nature 109, 781.

    Article  Google Scholar 

  • Scott, A. (1923), “Isolation of the oxide of a new element,” Journal of the Chemical Society, Transactions 123, 311–12.

    Article  CAS  Google Scholar 

  • Spencer, J. F. (1919), The Metals of the Rare Earths (London: Longmans, Green and Co.).

    Google Scholar 

  • Thalén, T. R. (1881), “Sur les raies brillantes spectrales des métaux scandium, ytterbium, erbium et thulium,”Öftersigt af Kungliga Vetenskaps Akademiens Handlingar 38, no. 6, 13–21.

    Google Scholar 

  • Thomsen, J. (1895), “Classifications des corps simples,” Kongelige Danske Videnskabernes Selskab, Oversigt, 132–36.

    Google Scholar 

  • Urbain, G. (1898), Recherches sur la Séparation des Terres Rares (University of Paris dissertation).

    Google Scholar 

  • Urbain, G. (1907), “Un nouvel élément: le lutécium, résultant du dédoublement de l’ytterbium de Marignac,” Comptes Rendus 145, 759–62.

    CAS  Google Scholar 

  • Urbain, G. (1908a), “Sur le lutécium et le néoytterbium,” Comptes Rendus 146, 406–08.

    CAS  Google Scholar 

  • Urbain, G. (1908b), “Zur Zerlegung des Ytterbiums in seine Komponenten,” Chemiker-Zeitung 32, 730.

    CAS  Google Scholar 

  • Urbain, G. (1909a), “Europium, gadolinium, terbium, dysprosium, neoytterbium und lutetium,” Chemiker-Zeitung 33, 745–46.

    Google Scholar 

  • Urbain, G. (1909b), “Révision des poids atomiques des terres rares,” Bulletin de la Société Chimique de France 5, 133–72.

    CAS  Google Scholar 

  • Urbain, G. (1910), “Lutetium and neoytterbium or cassiopeium and aldebaranium,” Zeitschriftfür anorganische Chemie 68, 236–42.

    Article  CAS  Google Scholar 

  • Urbain, G. (1911), “Sur un nouvel élément qui accompagne le lutécium et le scandium dans les terres de gadolinite: le celtium,” Comptes Rendus 152, 141–43.

    CAS  Google Scholar 

  • Urbain, G. (1922), “Les numéros atomiques du néo-ytterbium, du lutécium et du celtium,” Comptes Rendus 174, 1349–51.

    CAS  Google Scholar 

  • Urbain, G. and Boulanger, C. (1922), “Sur la composition et les caractères chimiques de la thortveitite de Madagascar,” Comptes Rendus 174, 1442–43.

    Google Scholar 

  • Urbain, G. (1925a), “Twenty five years of research on the yttrium earths,” Chemical Reviews 1, 143–85.

    Article  Google Scholar 

  • Urbain, G. (1925b), “Discours sur les éléments chimiques et les atomes. Hommage au Professeur Bohuslav Brauner,” Recoil des Travaux Chimiques des Pays-Bas 44, 281–95.

    CAS  Google Scholar 

  • Van Spronsen, J. W. (1969), The Periodic System of Chemical Elements: A History of the First Hundred Years (Amsterdam: Elsevier).

    Google Scholar 

  • Weeks, M. E. and Leicester, H. M. (1968), Discovery of the Elements (7th edn., Easton, Pa.: Journal of Chemical Education).

    Google Scholar 

  • Wenzel, F. (1909), “Zur Spaltung des Ytterbiums,” Zeitschrift für anorganische Chemie 64, 119–20.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Kluwer Academic Publishers

About this chapter

Cite this chapter

Kragh, H. (1996). Elements No. 70, 71 and 72: Discoveries and Controversies. In: Evans, C.H. (eds) Episodes from the History of the Rare Earth Elements. Chemists and Chemistry, vol 15. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0287-9_5

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-0287-9_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6614-3

  • Online ISBN: 978-94-009-0287-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics