Abstract
This chapter focuses on recent advances in the field of ion-exchanger-based voltammetric sensors, whose widespread use has given rise to a new electroanalytical technique named ion exchange voltammetry (IEV). The chapter starts with a brief historical overview and a short introduction to voltammetric methods of analysis, followed by the presentation of the fundamentals of ion exchange voltammetry. Analytical advantages and limits up to the most recent developments in the technique are then presented and discussed. Typical examples of application to determinations of trace concentrations of inorganic and organic electroactive molecules of interest for environmental and biomedical analysis are finally given along with future prospects.
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References
Oyama N, Anson FC (1980) Electrostatic binding of metal complexes to electrode surfaces coated with highly charged polymeric films. J Electrochem Soc 127:247–250
Rubinstein I, Bard AJ (1980) Polymer films on electrodes. 4. Nafion-coated electrodes and electrogenerated chemiluminescence of surface-attached tris(2,2′-bipyridine)ruthenium(2+). J Am Chem Soc 102:6641–6642
Murray RW (1981) Modified electrodes. Chemically modified electrodes for electrocatalysis. Philos Trans R Soc Lond A 302:253–265
Murray RW (1984) Chemically modified electrodes. In: Bard AJ (ed) Electroanalytical chemistry, vol 13. Marcel Dekker, New York, pp 191–368
Espenscheid MW, Ghatak-Roy AR et al (1986) Sensors from polymer modified electrodes. J Chem Soc Faraday Trans I 82:1051–1070
Ugo P, Moretto LM (1995) Ion-exchange voltammetry at polymer modified electrodes: principles and analytical prospects. Electroanalysis 7:1105–1113
(a) Ugo P, Moretto LM, Vezzà F (2002) Ionomer-coated electrodes and nanoelectrode ensembles as electrochemical environmental sensors: recent advances and prospects. Chem Phys Chem 3:917–925; (b) Ugo P, Moretto LM, Vezzà F (2003) Ionomer-coated electrodes and nanoelectrode ensembles as electrochemical environmental sensors: recent advances and prospects. In: Baltes H, Fedder GK, Korvink JG (eds) Sensors update, vol 12. Wiley-VCH, Weinheim, pp 121–140
Zen JM, Kumar AS, Tsai DM (2003) Recent updates of chemically modified electrodes in analytical chemistry. Electroanalysis 15:1073–1087
Arrigan DWM (1994) Voltammetric determination of trace metals and organics after accumulation at modified electrodes. Analyst 119:1953–1966
Ulman A (1991) Ultrathin organic films. Academic, San Diego
Decher G (1997) Toward layered polymeric multicomposites. Science 277:1232–1237
Marquette CA, Bouteille F, Corgier BP et al (2009) Disposable screen-printed chemiluminescent biochips for the simultaneous determination of four point-of-care relevant proteins. Anal Bioanal Chem 393:1191–1198
Willner I, Katz E (eds) (2005) Bioelectronics. Wiley VCH, Weinheim
Thorp HH, Loomis CR, Napier ME (1999) Polymer-electrodes for detecting nucleic acid hybridization and method of use thereof. US Patent 5,968,745
Drummond TG, Hill MG, Barton JK (2003) Electrochemical DNA sensors. Nat Biotechnol 21:1192–1199
Dill K, Montgomery DD, Ghindilis AL et al (2004) Immunoassays and sequence-specific DNA detection on a microchip using enzyme amplified electrochemical detection. J Biochem Biophys Methods 59:181–187
Heller A, Feldman B (2010) Electrochemistry in diabetes management. Acc Chem Res 43:963–973
Svancara I, Vytras K, Kalcher K et al (2009) Carbon paste electrodes in facts, numbers, and notes: a review on the occasion of the 50-years jubilee of carbon paste in electrochemistry and electroanalysis. Electroanalysis 21:7–28
Bard AJ, Faulkner L (2000) Electrochemical methods, 2nd edn. Wiley, New York
Wang J (2000) Analytical electrochemistry, 2nd edn. VCH, Weinheim
Fatouros N, Simonin JP, Chevalet J et al (1986) Theory of multiple square wave voltammetry. J Electroanal Chem 213:1–16
Krulic D, Fatouros N, Chevalet J (1990) Multiple square wave voltammetry: experimental verification of the theory. J Electroanal Chem 287:215–227
Moretto LM, Ugo P, Lacasse R et al (1999) Determination of methylmercury at Nafion® coated electrodes by single and multiple pulse voltammetric techniques. J Electroanal Chem 467:193–202
Moretto LM, Chevalet J, Mazzocchin GA et al (2001) Advances in multiple square wave techniques for ion-exchange voltammetry at ultratrace levels: the europium(III) case. J Electroanal Chem 498:117–126
Brainina Kh, Neyman E (1993) Electroanalytical stripping methods in chemical analysis. Wiley, New York
Wang J (1989) Voltammetry following nonelectrolytic preconcentration. In: Bard AJ (ed) Electroanalytical chemistry, vol 16. Marcel Dekker, New York, pp 1–88
Buffle J (1988) Complexation reactions in aquatic systems – an analytical approach. Ellis Horwood, Chichester
Wojclechowski M, Go W, Osteryoung J (1985) Square-wave anodic stripping analysis in the presence of dissolved oxygen. Anal Chem 57:155–158
Colombo C, van den Berg C (1988) In-line deoxygenation for flow analysis with voltammetric detection. Anal Chim Acta 377:229–240
Mikkelsen Ǿ, Schrǿder KH (2000) Dental amalgam in voltammetry – some preliminary results. Anal Lett 33:3253–3269
Wang J, Lu J, Kirgoz UA et al (2001) Insights into the anodic stripping voltammetric behavior of bismuth film electrodes. Anal Chim Acta 434:29–34
Helfferich F (1962) Ion-exchange. McGraw-Hill, New York
Naegeli R, Redepenning J, Anson FC (1986) Influence of supporting electrolyte concentration and composition on formal potentials and entropies of redox couples incorporated in Nafion coatings on electrodes. J Phys Chem 90:6227–6232
Redepenning J, Anson FC (1987) Permselectivities of polyelectrolyte electrode coatings as inferred from measurements with incorporated redox probes or concentration cells. J Phys Chem 91:4549–4553
Ugo P, Anson FC (1989) Poly(2-vinylpyrazine) as a soluble polymeric ligand and as an electrode coating. Reactions with pentacyanoferrate(II). Anal Chem 61:1799–1805
Toniolo R, Comisso N, Bontempelli G et al (1994) Potential shifts at electrodes coated with ion-exchange polymeric films. Talanta 41:473–478
Ugo P, Moretto LM, De Boni A et al (2002) Iron(II) and iron(III) determination by potentiometry and ion-exchange voltammetry at ionomer-coated electrodes. Anal Chim Acta 474:147–160
Hillman AR (1987) Reactions and applications of polymer modified electrodes. In: Linford RG (ed) Electrochemical science and technology of polymers, vol 1. Elsevier Applied Science, London, Chap 5
Majda M (1992) Dynamics of electron transport in polymeric assemblies of redox centers. In: Murray R (ed) Molecular design of electrode surfaces. Wiley, New York, pp 159–206
Oyama N, Ohsaka T (1992) Voltammetric diagnosis of charge transport on polymer coated electrodes. In: Murray R (ed) Molecular design of electrode surfaces. Wiley, New York
Szentirmay MN, Martin CR (1984) Ion-exchange selectivity of Nafion films on electrode surfaces. Anal Chem 56:1898–1902
Ugo P, Ballarin B, Daniele S et al (1992) Electrochemical behaviour and preconcentration of uranyl(VI) at Nafion-coated glassy carbon electrodes. J Electroanal Chem 324:145–159
Kaufman FB, Engler EM (1979) Solid-state spectroelectrochemistry of crosslinked donor bound polymer films. J Am Chem Soc 101:547–549
Facci J, Murray RW (1981) Charge transport by electron exchange cross reaction in cyclic voltammetry of IrCl 3−6 - Fe(CN) 3−6 mixtures trapped in polycationic films on electrodes. J Phys Chem 85:2870–2873
Buttry DA, Anson FC (1983) Effects of electron exchange and single-file diffusion on charge propagation in Nafion films containing redox couples. J Am Chem Soc 105:685–689
Anson FC, Blauch DN, Saveant JM et al (1991) Ion association and electric field effects on electron hopping in redox polymers. Application to the tris(2,2′-bipyridine)osmium(3+)/tris(2,2′-bipyridine)osmium(2+) couple in Nafion. J Am Chem Soc 113:1922–1932
Dahms HI (1968) Electronic conduction in aqueous solution. J Phys Chem 72:362–364
Ruff I, Friedrich VJ (1971) Transfer diffusion. I. Theoretical. J Phys Chem 75:3297–3302
Whiteley LD, Martin CR (1989) Fresh look at transport in perfluorosulfonate ionomers: ultramicroelectrode investigations of Nafion and the Dow ionomers. J Phys Chem 93:4650–4658
Kuo K-N, Murray RW (1982) Electrocatalysis with ferrocyanide electrostatically trapped in an alkylaminesiloxane polymer film on a Pt electrode. J Electroanal Chem 131:37–60
Majda M, Faulkner LR (1984) Electrochemical behaviour of tris(2,2′-bipyridine)ruthenium complexes in films of poly(styrenesulfonate) on electrodes. J Electroanal Chem 169:77–95
Martin CR, Rubinstein I, Bard AJ (1982) Polymer films on electrodes. 9. Electron and mass transfer in Nafion films containing tris(2,2′-bipyridine)ruthenium(2+). J Am Chem Soc 104:4817–4824
Shi M, Anson FC (1997) Some consequences of the significantly different mobilities of hydrophilic and hydrophobic metal complexes in perfluorosulfonated ionomer coatings on electrodes. Anal Chem 69:2653–2660
Daniele S, Ugo P, Bragato C et al (1996) Use of Nafion® coated carbon disk microelectrodes in solution without and with different concentrations of supporting electrolyte. J Electroanal Chem 418:29–34
Amatore C, Sella C, Thouin L (2003) Effects of chemical environment on diffusivities within thin Nafion® films as monitored from chronoamperometric responses of generator–collector double microband assemblies. J Electroanal Chem 547:151–161
Kroschwitz JI (1990) Concise encyclopedia of polymer science and engineering. Wiley, New York
Yeo RS, Yeager HL (1985) Structural and transport properties of perfluorinated ion-exchange membranes. In: Conway BE, White RE, Bockris JO’M (eds) Modern aspects of electrochemistry, vol 16. Plenum, New York, pp 437–504
Zook LA, Leddy J (1996) Density and solubility of Nafion: recast, annealed, and commercial films. Anal Chem 68:3793–3796
Chen T-Y, Leddy J (2000) Ion exchange capacity of Nafion and Nafion composites. Langmuir 16:2866–2871
Oberbroeckling KJ, Dunwoody DC, Minteer SD et al (2002) Density of Nafion exchanged with transition metal complexes and tetramethyl ammonium, ferrous, and hydrogen ions: commercial and recast films. Anal Chem 74:4794–4799
Pereira FC, Fogg AG, Ugo P et al (2005) Determination of iodide and idoxuridine at a glutaraldehyde-cross-linked poly-L-lysine modified glassy carbon electrode. Electroanalysis 17:1309–1316
Anson FC, Saveant JM, Shigehara K (1983) New model for the interior of polyelectrolyte coatings on electrode surfaces. Mechanisms of charge transport through protonated poly(L-lysine) films containing FeIII(edta)− and FeII(edta)2− as counter ions. J Am Chem Soc 105:1096–1106
Walcarius A (2008) Electroanalytical applications of microporous zeolites and mesoporous (organo)silicas: recent trends. Electroanalysis 20:711–738
Walcarius A (2001) Electroanalysis with pure, chemically modified and sol–gel-derived silica-based materials. Electroanalysis 13:701–718
Buttry DA, Anson FC (1981) Electron hopping vs. molecular diffusion as charge transfer mechanism in redox polymer films. J Electroanal Chem 130:333–338
Ugo P, Moretto LM, Mazzocchin GA (1993) Voltammetric determination of trace mercury in chloride media at glassy carbon electrodes modified with polycationic ionomers. Anal Chim Acta 273:229–236
Dunsch L, Kavan L, Weber J (1990) Perfluoro anion-exchange polymeric films on glassy carbon electrodes. J Electroanal Chem 280:313–325
Kaufman FB, Schroeder AH, Engler EM et al (1980) Ion and electron transport in stable, electroactive tetrathiafulvalene polymer coated electrodes. J Am Chem Soc 102:483–488
Schroeder AH, Kaufman FB (1980) The influence of polymer morphology on polymer film electrochemistry. J Electroanal Chem 113:209–224
Gennett T, Purdy WC (1990) Voltammetric determination of the ion-exchange behaviour of AQ polymers [poly(ester sulfonic acid) anionomers] in acetonitrile. Anal Chem 62:2155–2158
Brunetti B, Ugo P (1999) Factors influencing the ion-exchange preconcentration and voltammetric behaviour of redox cations at polyestersulfonated ionomer coated electrodes in acetonitrile solutions. J Electroanal Chem 460:38–45
Weber J, Janda P, Kavan L et al (1986) Study of Nafion film on electrodes prepared from dimethylacetamide solution. J Electroanal Chem 200:379–381
Moore RB III, Martin CR (1988) Chemical and morphological properties of solution-cast perfluorosulfonate ionomers. Macromolecules 21:1334–1339
Goebel G, Aldebert P, Pineri M (1987) Structure and related properties of solution-cast perfluorosulfonated ionomer films. Macromolecules 20:1425–1428
Hoyer B, Jensen N (1994) Signal stability of Nafion-coated thin mercury film electrodes for stripping voltammetry. Talanta 41:449–453
Stribel KA, Scherer GG, Haas O (1991) Effect of curing-humidity on recast-Nafion films. J Electroanal Chem 304:289–296
Shi M, Anson FC (1996) Effects of hydration on the resistances and electrochemical responses of nafion coatings on electrodes. J Electroanal Chem 415:41–46
Shimazu K, Kita H, Kuwana T (1989) RF-plasma treatment of Nafion film electrodes. J Electroanal Chem 258:49–59
Nishide H, Deguchi J, Tsuchida E (1977) Adsorption of metal ions on cross-linked poly(4-vinylpyridine) resins prepared with a metal ion as template. J Polym Sci 15:3023–3029
Lindholm B, Sharp M (1986) Simple preparation and characteristics of stabilized, protonated poly-4-vinylpyridine films containing electroactive anions on glassy carbon electrode surfaces. J Electroanal Chem 198:37–52
Oyama N, Shimomura T, Shigehara K et al (1980) Electrochemical responses of multiply-charged transition metal complexes bound electrostatically to graphite electrode surfaces coated with polyelectrolytes. J Electroanal Chem 112:271–280
De Castro ES, Huber EW, Villaroel D et al (1987) Electrodes with polymer network films formed by g-irradiation cross-linking. Anal Chem 59:134–139
Denisevich P, Abruna HD, Leidner CR et al (1982) Electropolymerization of vinylpyridine and vinylbipyridine complexes of iron and ruthenium: homopolymers, copolymers, reactive polymers. Inorg Chem 21:2153–2161
Kaner RB (1990) Preparations and properties of electrochemically synthesized polymers. In: Linford RG (ed) Electrochemical science and technology of polymers, vol 2. Elsevier, London, pp 97–148
Ugo P, Sperni L, Moretto LM (1997) Ion-exchange voltammetry of trace mercury(II) at glassy carbon electrodes coated with a cationic polypyrrole derivative. Application to pore-waters analysis. Electroanalysis 9:1153–1158
Mao H, Pickup PG (1989) Electronically conductive anion exchange polymers based on polypyrrole. Preparation, characterization, electrostatic binding of ferrocyanide and electrocatalysis of ascorbic acid oxidation. J Electroanal Chem 265:127–142
Pickup PG (1987) Poly-(3-methylpyrrole-4-carboxylic acid): an electronically conducting ion-exchange polymer. J Electroanal Chem 225:273–280
Basak S, Rajeshwar K, Kaneko M (1990) Ion binding by poly{pyrrole-co-[3-(pyrrol-1-yl)propanesulfonate]} thin films. Anal Chem 62:1407–1413
Cosnier S, Deronzier A, Moutet J-C et al (1989) Alkylammonium and pyridinium group-containing polypyrroles, a new class of electronically conducting anion-exchange polymers. J Electroanal Chem 271:69–81
Guadalupe AR, Abruna HD (1985) Electroanalysis with chemically modified electrodes. Anal Chem 57:142–149
Degani Y, Heller A (1989) Electrical communication between redox centres of glucose oxidase and electrodes via electrostatically and covalently bound redox polymers. J Am Chem Soc 111:2357–2358
Heller A, Feldman B (2008) Electrochemical glucose sensors and their applications in diabetes management. Chem Rev 108:2482–2505
Hoyer B, Jensen N, Busch LP (2001) Effect of the pretreatment of recast Nafion membranes on their rejection of the albumin interference in anodic stripping voltammetry. Electroanalysis 13:843–848
Wilner I, Katz E (2000) Integration of layered redox proteins and conductive supports for bioelectronic applications. Angew Chem Int Ed 39:1180–1218
Mano N, Kuhn A (2002) Affinity assembled multilayers for new dehydrogenase biosensors. Bioelectrochemistry 56:123–126
Mano N, Kuhn A (2001) Electrodes modified with nitrofluorenone derivatives as a basis for new biosensors. Biosens Bioelectron 16:653–660
Anicet N, Bourdillon C, Moiroux J et al (1998) Simple electrochemical procedure for measuring the rates of electron transfer across liquid/liquid interfaces formed by coating graphite electrodes with thin layers of nitrobenzene. J Phys Chem B 102:9845–9854
Hodak J, Etchenique R, Calvo EJ et al (1997) Layer-by-layer self-assembly of glucose oxidase with a poly(allylamine)ferrocene redox mediator. Langmuir 13:2708–2716
Ma H, Hu N, Rusling J (2000) Electroactive myoglobin films grown layer-by-layer with poly(styrenesulfonate) on pyrolytic graphite electrodes. Langmuir 16:4969–4975
Lojou E, Bianco P (2003) Quartz crystal microbalance and voltammetry monitoring for layer-by-layer assembly of cytochrome c 3 and poly(ester sulfonic acid) films on gold and silver electrodes. J Electroanal Chem 557:37–47
Lojou E, Bianco P (2004) Buildup of polyelectrolyte–protein multilayer assemblies on gold electrodes. Role of the hydrophobic effect. Langmuir 20:748–755
Galeska I, Chattopadhyay D, Moussy F et al (2000) Calcification-resistant Nafion/Fe3+ assemblies for implantable biosensors. Biomacromolecules 1:202–207
Harris JJ, Stair JL, Bruening ML (2000) Layered polyelectrolyte films as selective, ultrathin barriers for anion transport. Chem Mater 12:1941–1946
Calvo EJ, Wolosiuk A (2002) Donnan permselectivity in layer-by-layer self-assembled redox polyelectrolyte thin films. J Am Chem Soc 124:8490–8497
De Longchamp DM, Hammond PT (2003) Fast ion conduction in layer-by-layer polymer films. Chem Mater 15:1165–1173
Bertoncello P, Ram MK, Notargiacomo A et al (2002) Fabrication and physico-chemical properties of Nafion Langmuir-Schaefer films. Phys Chem Chem Phys 4:4036–4043
Bertoncello P, Ugo P (2003) Preparation and voltammetric characterization of electrodes coated with Langmuir-Schaefer ultrathin films of Nafion®. J Braz Chem Soc 14:517–522
Moretto LM, Kohls T, Chauvin A et al (2008) Epifluorescence imaging of electrochemically switchable Langmuir–Blodgett films of Nafion. Langmuir 24:6367–6374
Moretto LM, Kohls T, Badocco D et al (2010) Electrochemiluminescence of Ru(bpy) 3+2 loaded in Nafion Langmuir–Blodgett films: role of the interfacial ultrathin film. J Electroanal Chem 640:35–41
Bertoncello P, Dennany L (2007) Nafion–tris(2-2′-bipyridyl)ruthenium(II) ultrathin Langmuir–Schaefer films: redox catalysis and electrochemiluminescent properties. Anal Chem 79:7549–7553
Wring SA, Hart JP (1992) Chemically modified, carbon-based electrodes and their application as electrochemical sensors for the analysis of biologically important compounds. A review. Analyst 117:1215–1229
Ugo P, Moretto LM, Bertoncello P et al (1998) Determination of trace mercury in saltwaters at screen-printed electrodes modified with Sumichelate Q10R. Electroanalysis 10:1017–1021
Zumbrunnen HR, Anson FC (1983) Electrostatic binding of anions and cations to graphite electrodes coated with a polyelectrolyte containing both positive and negative fixed charges. J Electroanal Chem 152:111–124
Espenscheid MW, Martin CR (1985) Electroactive ion exchange polymers. J Electroanal Chem 188:73–84
Buyukserin F, Kohli P, Wirtz MC et al (2007) Electroactive nanotube membranes and redox-gating. Small 3:266–270
Fan FF, Bard AJ (1986) Polymer films on electrodes. J Electrochem Soc 133:301–304
Penner RM, Martin CR (1986) Electronically conductive composite polymer membranes. J Electrochem Soc 133:310–315
Nagasubramanian G, Di Stefano S, Moacanin J (1986) Electrochemical incorporation of poly(pyrrole) into Nafion and comparison of the electrochemical properties of Nafion-poly(pyrrole) and poly(pyrrole) films. J Phys Chem 90:4447–4451
Orata D, Buttry DA (1988) Virtues of composite structures in electrode modification. Preparation and properties of poly(anyline)/Nafion composite films. J Electroanal Chem 257:71–82
Hirai T, Kuwabata S, Yonegani H (1988) Electrochemical behaviours of polypyrrole, poly-3-methylthiophene, and polyaniline deposited on Nafion-coated electrodes. J Electrochem Soc 135:1132–1137
Shimidzu T, Ohtani A, Iyoda T et al (1987) Charge-controllable polypyrrole/polyelectrolyte composite membranes. Part II. Effect of incorporated anion size on the electrochemical oxidation-reduction process. J Electroanal Chem 224:123–135
Shimidzu T, Ohtani A, Iyoda T et al (1988) Charge-controllable polypyrrole/polyelectrolyte composite membranes. Part III. Electrochemical deionization system constructed by anion-exchangeable and cation-exchangeable polypyrrole electrodes. J Electroanal Chem 251:323–337
Zhou QX, Miller LL, Valentine JR (1989) Electrochemically controlled binding and release of protonated dimethyldopamine and other cations from poly(N-methyl-pyrrole)/polyanion composite redox polymers. J Electroanal Chem 261:147–164
Elliot CM, Kopelove AB, Albery WJ et al (1991) Nonaqueous electrochemistry of polypyrrole/polystyrenesulfonate composite films: voltammetric, coulometric, EPR, and a.c. impedance studies. J Phys Chem 95:1743–1747
Wang J, Sun Z, Lu Z (1991) Electrochemical behaviour of polypyrrole/Kodak AQ composite polymeric films. J Electroanal Chem 310:269–279
Gbatu TP, Ceylan O, Sutton KL et al (1999) Electrochemical control of solid phase micro-extraction using unique conducting polymer coated fibers. Anal Commun 36:203–205
Wu J, Yu X, Lord H et al (2000) Solid phase microextraction of inorganic anions based on polypyrrole film. Analyst 125:391–394
Wu J, Pawliszyn J (2001) Preparation and applications of polypyrrole films in solid-phase microextraction. J Chromatogr A 909:37–52
Liljegren G, Petterson J, Markides KE et al (2002) Electrochemical solid-phase microextraction of anions and cations using polypyrrole coatings and an integrated three-electrode device. Analyst 127:591–597
Deinhammer RS, Porter MD, Shimazu K (1995) Retention characteristics of polypyrrole as a stationary phase for the electrochemically modulated liquid chromatographic (EMLC) separations of dansyl amino acids. J Electroanal Chem 387:35–46
Scopece P, Moretto LM, Polizzi S et al (2006) Composite films of poly-(ester-sulphonated) and poly-(3-methylthiophene) for ion-exchange voltammetry in acetonitrile solutions. Electrochim Acta 51:2153–2160
Hanzlik J, Ugo P, Daniele S et al (1996) Ion-exchange voltammetry of tris(2,2′-bipyridyl) ruthenium(II), iron(II), osmium(II) and tris(2,2′-bipyrazyl) ruthenium(II) in acetonitrile solutions at poly(ester-sulphonate) coated electrodes. J Electroanal Chem 404:89–97
Wang J, Tuzhi P (1986) Selectivity and sensitivity improvements at perfluorinated ionomer/cellulose acetate bilayer electrodes. Anal Chem 58:3257–3261
Wang J, Tuzhi P, Golden T (1987) Amperometric detection of cationic neurotransmitters at Nafion-coated glassy carbon electrodes in flow streams. Anal Chim Acta 194:129–138
Brazell MP, Kasser RJ, Renner KJ et al (1987) Electrocoating carbon fiber microelectrodes with Nafion improves selectivity for electroactive neurotransmitters. J Neurosci Methods 22:167–172
Kristensen EW, Kuhr WG, Wightman RM (1987) Temporal characterization of perfluorinated ion exchange coated microvoltammetric electrodes for in vivo use. Anal Chem 59:1752–1757
Crespi F, Martin KF, Marsden CA (1988) Measurement of extracellular basal levels of serotonin in vivo using Nafion-coated carbon fibre electrodes combined with differential pulse voltammetry. Neuroscience 27:885–896
Ugo P, Ballarin B, Daniele S et al (1991) Determination of trace amounts of Eu3+ and Yb3+ ions at Nafion-coated thin mercury film electrodes. Anal Chim Acta 244:29–38
Ugo P, Ballarin B, Daniele S et al (1990) Electrochemistry of Yb3+ and Eu3+ at Nafion modified electrodes. J Electroanal Chem 291:187–199
Zhou J, Wang E (1991) Ion exchange of cationic drugs at a Nafion-coated electrode in flow-through analysis. Anal Chim Acta 249:489–494
Gorski W, Cox JA (1992) Stripping voltammetry with preconcentration through chemical reactions coupled to charge transfer in an ionomer-coated electrode: application to the determination of a nitrosoamine. Anal Chem 64:2706–2710
Boyd D, Barreira Rodriguez JR, Miranda Ordieres AJ et al (1994) Voltammetric study of salbutamol, fenoterol and metaproterenol at unmodified and Nafion-modified carbon paste electrodes. Analyst 119:1979–1984
Zen J-M, Ting Y-S (1996) Square-wave voltammetric stripping analysis of lead(II) at a Nafion®/copper-mercury film electrode. Anal Chim Acta 332:59–65
Hu Z, Seliskar CJ, Heineman WR (1998) PAN-incorporated Nafion-modified spectroscopic graphite electrodes for voltammetric stripping determination of lead. Anal Chim Acta 369:93–101
Brett CMA, Fungaro DA, Morgado JM et al (1999) Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis. J Electroanal Chem 468:26–33
Lu T-H, Yang H-Y, Sun I-W (1999) Square-wave anodic stripping voltammetric determination of thallium(I) at a Nafion/mercury film modified electrode. Talanta 49:59–68
Zen J-M, Jou J-J, Kumar AS (1999) A sensitive voltammetric method for the determination of parathion insecticide. Anal Chim Acta 396:39–44
Yang H-Y, Sun I-W (2000) Cathodic stripping voltammetric determination of selenium(IV) at a Nafion coated mercury film electrode modified with 3,3′-diaminobenzidine. Electroanalysis 12:1476–1480
Brett CMA, Fungaro DA (2000) Poly(ester sulphonic acid) coated mercury thin film electrodes: characterization and application in batch injection analysis stripping voltammetry of heavy metal ions. Talanta 50:1223–1231
Cheng HL, Sun IW (2001) Square-wave voltammetric detection of apomorphine on a Nafion film modified glassy carbon electrode. Electroanalysis 13:1544–1546
Yi H, Wu K, Hu S et al (2001) Adsorption stripping voltammetry of phenol at Nafion-modified glassy carbon electrode in the presence of surfactants. Talanta 55:1205–1210
Collyer SD, Bradbury SE, Hatfiled JV et al (2001) A study of factors affecting the enhanced voltammetric stripping analysis of N-nitrosamines at sulfopolyester modified electrodes. Electroanalysis 13:332–337
Ugo P, Zangrando V, Moretto LM et al (2002) Ion-exchange voltammetry and electrocatalytic sensing capabilities of cytochrome c at polyestersulfonated ionomer coated glassy carbon electrodes. Biosens Bioelectron 17:479–487
Wang HY, Xu GB, Dong SJ (2003) Electrochemiluminescence sensor using tris(2,2′-bipyridyl)ruthenium(II) immobilized in Eastman-AQ55D–silica composite thin-films. Anal Chim Acta 480:285–290
Xu Q, Xu C, Wang Q et al (2003) Application of a single electrode, modified with polydiphenylamine and dodecyl sulfate, for the simultaneous amperometric determination of electro-inactive anions and cations in ion chromatography. J Chromatogr A 997:65–71
Rodríguez Gutiérrez JA, Petit Domínguez MD, Pinilla Macías JM (2004) Development of ionoselective electrochemical sensors by using the sol–gel process. Anal Chim Acta 524:339–346
Monterroso SCC, Carapuça HM, Duarte AC (2005) Ion-exchange and permselectivity properties of poly(sodium 4-styrenesulfonate) coatings on glassy carbon: application in the modification of mercury film electrodes for the direct voltammetric analysis of trace metals in estuarine waters. Talanta 65:644–653
Moretto LM, Bertoncello P, Vezzà P et al (2005) Electrochemistry of cytochrome c incorporated in Langmuir–Blodgett films of Nafion and Eastman AQ 55. Bioelectrochemistry 66:29–34
Buriez O, Moretto LM, Ugo P (2006) Ion-exchange volatmmetry of tris-(2,2′-bipyridine) nickel(II), cobalt(II), and Co(salen)at polyestersulfonated ionomer coated electrodes in acetonitrile: reactivity of the electrogenerated low-valent complexes. Electrochim Acta 52:958–964
Monterroso SCC, Carapuça HM, Duarte AC (2006) Mixed polyelectrolyte coatings on glassy carbon electrodes: ion-exchange, permselectivity properties and analytical application of poly-l-lysine–poly(sodium 4-styrenesulfonate)-coated mercury film electrodes for the detection of trace metals. Talanta 68:1655–1662
Riccardi CD, Yamanaka H, Josowicz M et al (2006) Label-free DNA detection based on modified conducting polypyrrole films at microelectrodes. Anal Chem 78:1139–1145
Lin YH, Cui XL (2006) Electrosynthesis, characterization, and application of novel hybrid materials based on carbon nanotube–polyaniline–nickel hexacyanoferrate nanocomposites. J Mater Chem 16:585–592
Bertoncello P, Dennany L, Forster RJ et al (2007) Nafion–Tris(2-2′-bipyridyl)ruthenium(II) Ultrathin Langmuir–Schaefer films: redox catalysis and electrochemiluminescent properties. Anal Chem 79:7549–7553
Huang M, Jiang H, Zhai J et al (2007) A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential. Talanta 74:132–139
Zhang LB, Li J, Xu YH et al (2009) Solid-state electrochemiluminescence sensor based on the Nafion/poly(sodium 4-styrene sulfonate) composite film. Talanta 79:454–459
Silva CP, Carapuça HM, Rocha LS et al (2009) Evaluation of poly(sodium 4-styrenesulfonate) film coating in thin mercury film electrodes for lead determination. J Electroanal Chem 626:192–196
Çelebi MS, Özyörük H, Yıldız A et al (2009) Determination of Hg2+ on poly(vinylferrocenium) (PVF+)-modified platinum electrode. Talanta 78:405–409
Yuan Y, Yuan X, Chai Y et al (2010) A novel label-free electrochemical aptasensor for thrombin based on the {nano-Au/thionine} n multilayer films as redox probes. Anal Chim Acta 668:171–176
Xub H, Chenc J, Shia G, Jina L (2010) Nafion stabilized silver nanoparticles modified electrode and its application to Cr(VI) detection. J Electroanal Chem 652:60–65
Zhou C, Liu Z, Dai J et al (2010) Electrospun Ru(bpy) 2+3 -doped Nafion nanofibers for electrochemiluminescence sensing. Analyst 135:1004–1009
Taffa DH, Kathiresan M, Walder L et al (2010) Pore size and surface charge control in mesoporous TiO2 using post-grafted SAMs. Phys Chem Chem Phys 12:1473–1482
Azad UP, Ganesan V (2010) Efficient sensing of nitrite by Fe(bpy) 2+3 immobilized Nafion modified electrodes. Chem Commun 46:6156–6158
Cox JA, Kulesza PJ (1983) Stripping voltammetry of chromium(VI) at a poly(4-vinvlpyridine)-coated platium electrode. Anal Chim Acta 154:71–78
Cassidy JF, Tokuda K (1990) Preconcentration and voltammetric determination of copper ions in aqueous chloride solutions at a cross-linked poly(4-vinylpyridine)-coated electrode. J Electroanal Chem 285:287–294
Ugo P, Moretto LM, Mazzocchin GA (1995) Voltammetric determination of trace mercury in chloride media at glassy carbon electrodes modified with polycationic ionomers. Anal Chim Acta 305:74–82
Zen J-M, Chung M-J (1996) Square-wave voltammetric stripping analysis of bismuth(III) at a poly(4-vinylpyridine)/mercury film electrode. Anal Chim Acta 320:43–51
Moretto LM, Mazzocchin GA, Ugo P (1997) Electrochemical study on the ion-exchange voltammetric behaviour of Hg(II) at Tosflex®-coated glassy carbon electrode. J Electroanal Chem 427:113–121
Lu T-H, Sun I-W (1998) Anodic stripping voltammetric determination of thallium(III) using a Tosflex/mercury film electrode. Electroanalysis 10:1052–1056
Zen J-M, Chung H-G, Ilagovan G (1999) Selective voltammetric determination of lead(II) on partially quaternized poly(4-vinylpyridine)/mercury film electrodes. Electroanalysis 11:108–113
Yang H-Y, Chen W-Y, Sun I-W (1999) Anodic stripping voltammetric determination of bismuth(III) using a Tosflex-coated mercury film electrode. Talanta 50:977–984
Maizels M, Heineman WR, Seliskar CJ (2000) Graphite electrodes coated with poly(dimethyldiallylammonium)chloride network films cross-linked by gamma-irradiation. Electroanalysis 12:241–247
Lu T-H, Huang J-F, Sun I-W (2001) Perfluorinated anion-exchange polymer mercury film electrode for anodic stripping voltammetric determination of zinc(II): effect of model organic compounds. Anal Chim Acta 454:93–100
Cheng H-L, Kuei C-H, Sun I-W (2002) Electrochemical detection of O, O-diethyldithiophosphoric acid at a Tosflex film modified glassy carbon electrode. Electroanalysis 14:767–772
Prasad BB, Arora B (2003) Application of polymer-modified hanging mercury drop electrode in the indirect determination of certain β-lactam antibiotics by differential pulse, ion-exchange voltammetry. Electroanalysis 15:1212–1218
Rodríguez Gutiérrez JA, Petit Domínguez MD, Pinilla Macías JM (2004) Development of ionoselective electrochemical sensors by using the sol–gel process. Anal Chim Acta 524:339–346
Tsai DM, Kumar AS, Zen JM (2006) A highly stable and sensitive chemically modified screen-printed electrode for sulfide analysis. Anal Chim Acta 556:145–150
Silva CP, Carapuça HM (2006) Glassy carbon electrodes coated with poly(allylamine hydrochloride), PAH: characterization studies and application to ion-exchange voltammetry of trace lead(II) at combined PAH/mercury film electrodes. Electrochim Acta 52:1182–1190
Tsai M-C, Chen P-Y (2007) Electrochemical detection of 2-naphthol at a glassy carbon electrode modified with Tosflex film. Electroanalysis 19:1315–1321
Vago M, Tagliazucchi M, Williams FJ et al (2008) Electrodeposition of a palladium nanocatalyst by ion confinement in polyelectrolyte multilayers. Chem Commun 5746–5748
Hui T-W, Baker MD (2001) Ion exchange and electron transport at methyl viologen Y modified electrodes. J Phys Chem B 105:3204–3210
Li Y-J, Liu C-Y (2001) Silver-exchanged zeolite Y-modified electrodes: size selectivity for anions. J Electroanal Chem 517:117–120
Hui T-W, Baker MD (2002) Redox processes of methyl viologen cation radicals at zeolite Y-modified electrodes. J Phys Chem B 106:827–832
Zen JM, Wang HF, Kumar AS et al (2002) Preconcentration and electroanalysis of copper(II) in ammoniacal medium on nontronite/cellulose acetate modified electrodes. Electroanalysis 14:99–105
Zhang Y, Chen F, Shan W et al (2003) Fabrication of ultrathin nanozeolite film modified electrodes and their electrochemical behavior. Micropor Mesopor Mat 65:277–285
Tonle IK, Ngameni E, Walcarius A (2004) From clay – to organoclay-film modified electrodes: tuning charge selectivity in ion exchange voltammetry. Electrochim Acta 49:3435–3443
Yuan S, Chen W, Hu S (2004) Simultaneous determination of cadmium (II) and lead (II) with clay nanoparticles and anthraquinone complexly modified glassy carbon electrode. Talanta 64:922–928
Guo Z, Shen Y, Zhao F et al (2004) Electrochemical and electrogenerated chemiluminescence of clay nanoparticles/Ru(bpy) 2+3 multilayer films on ITO electrodes. Analyst 129:657–663
Lin C-L, Tien P, Chau L-K (2004) Electrochemical behavior of an anion-exchanger modified electrode prepared by sol–gel processing of an organofunctional silicon alkoxide. Electrochim Acta 49:573–580
Walcarius A, Etienne M, Delacote C (2004) Uptake of inorganic HgII by organically modified silicates: influence of pH and chloride concentration on the binding pathways and electrochemical monitoring of the processes. Anal Chim Acta 508:87–98
Walcarius A, Ganesan V (2006) Ion-exchange properties and electrochemical characterization of quaternary ammonium-functionalized silica microspheres obtained by the surfactant template route. Langmuir 22:469–477
Letaief S, Tonle IK, Diaco T et al (2008) Nanohybrid materials from interlayer functionalization of kaolinite. Application to the electrochemical preconcentration of cyanide. Appl Clay Sci 42:95–101
Ganesan V, Walcarius A (2008) Ion exchange and ion exchange voltammetry with functionalized mesoporous silica materials. Mat Sci Eng B 149:123–132
Gan T, Hu C, Chen Z et al (2010) Direct electrochemical determination of methyl jasmonate in wheat spikelet at a nano-montmorillonite film modified electrode by derivative square wave voltammetry. J Agric Food Chem 58:8942–8947
Tcheumi HL, Tonle IK, Ngameni E et al (2010) Electrochemical analysis of methylparathion pesticide by a gemini surfactant-intercalated clay-modified electrode. Talanta 81:972–979
Acknowledgments
We wish to thank all collaborators of the Laboratory for Electrochemical Sensors of the University Ca’ Foscari of Venice (their names can be found as coauthors of many papers). Partial financial support by MIUR (Rome, Project PRIN 2008MWHCP2_001) is acknowledged.
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Ugo, P., Moretto, L.M. (2012). Ion Exchange Voltammetry. In: Dr., I., Luqman, M. (eds) Ion Exchange Technology I. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1700-8_11
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