Abstract
Advanced oxidation processes (AOPs) constitute a family of redox technologies that have been involved in various environmental applications, including, amongst others, the treatment of municipal and industrial wastewater contaminated by various organic and inorganic compounds.
This chapter focuses on the science and engineering of water and wastewater treatment in relation to AOPs applications. The chapter gives a short but necessary description of the key AOPs employed in water treatment and then discusses process fundamentals, advantages and drawbacks. This is done providing recent paradigms from the literature on process integration aiming to improve degradation rates or separate pollutants, catalysts and chemicals prior to or after advanced oxidation.
The chapter includes also information on solar-driven applications (homogeneous and heterogeneous photocatalysis) as an excellent example of sustainable treatment technologies. This part discusses technological advances (development of non-concentrating collectors and scaling-up of photocatalytic reactors) and summarizes most of the recent research related to the degradation of water contaminants. The approach is exemplified through a combined solar photocatalysis and bio-treatment unit capable of destroying very persistent toxic compounds.
Finally, in this chapter, the use of AOPs in drinking water treatment is discussed with respect to both disinfection by-products control and micro-pollutants removal and compared to the efficiency of conventional treatment technologies.
All authors have contributed equally to this chapter.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Adewuyi, Y. G. (2005). Sonochemistry in environmental remediation. 1. Combinative and hybrid sonophotochemical oxidation processes for the treatment of pollutants in water. Environmental Science and Technology, 39, 3409-3420.
Agüera, A., Perez Estrada, L. A., Ferrer, I., Thurman, E. M., Malato, S., & Fernandez-Alba, A. R. (2005). Application of time-of-flight mass spectrometry to the analysis of phototransformation products of diclofenac in water under natural sunlight. Journal of Mass Spectrometry, 40, 908-915.
Ajona, J. A., & Vidal, A. (2000). The use of CPC collectors for detoxification of contaminated water: Design, construction and preliminary results. Solar Energy, 68, 109-120.
Bahnemann, D. (2004). Photocatalytic water treatment: Solar energy applications. Solar Energy, 77, 445-459.
Balasubramanian, G., Dionysiou, D. D., Suidan, M. T., Baudin, I., & Laine, J. M. (2004). Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water. Applied Catalysis. B, Environmental, 47, 73-84.
Barth, J. A. C., Steidle, D., Kuntz, D., Gocht, T., Mouvet, C., von Tümpling, W., et al. (2007). Deposition, persistence and turnover of pollutants: first results from the EU project AquaTerra for selected river basins and aquifers. Science of the Total Environment, 376, 40-50.
Bautista, P., Mohedano, A. F., Casas, J. A., Zazo, J. A., & Rodriguez, J. J. (2008). An overview of the application of Fenton oxidation to industrial wastewaters treatment. Journal of Chemical Technology and Biotechnology, 83, 1323-1338.
Bekbölet, M., & Özkösemen, G. (1996). A preliminary investigation on the photocatalytic degradation of a model humic acid. Water Science and Technology, 33(6), 189-194.
Bekbolet, M., Uyguner, C. S., Selcuk, H., Rizzo, L., Nikolaou, A. D., Meric, S., et al. (2005). Application of oxidative removal of NOM to drinking water and formation of disinfection by-products. Desalination, 176, 155-166.
Belgiorno, V., Rizzo, L., Fatta, D., Della Rocca, C., Lofrano, G., Nikolaou, A., et al. (2007). Review of endocrine disrupting-emerging compounds in urban wastewater: Occurrence and removal by photocatalysis and ultrasonic irradiation for wastewater reuse. Desalination, 215, 166-176.
Beltran, F. J. (2003). Ozone reaction kinetics for water and wastewater systems. Boca Raton, FL: CRC Press.
Benner, J., Salhi, E., Ternes, T., & von Gunten, U. (2008). Ozonation of reverse osmosis concentrate: Kinetics and efficiency of betablocker oxidation. Water Research, 42, 3003-3012.
Berberidou, C., Poulios, I., Xekoukoulotakis, N. P., & Mantzavinos, D. (2007). Sonolytic, photocatalytic and sonophotocatalytic degradation of malachite green in aqueous solutions. Applied Catalysis. B, Environmental, 74, 63-72.
Bhargava, S. K., Tardio, J., Prasad, J., Folger, K., Akolekar, D. B., & Grocott, S. C. (2006). Wet oxidation and catalytic wet oxidation. Industrial and Engineering Chemistry Research, 45, 1221-1258.
Blanco-Gálvez, J., & Malato-Rodríguez, S. (2003). Solar detoxification. France: UNESCO Publishing.
Boroski, M., Rodrigues, A. C., Garcia, J. C., Gerola, A. P., Nozaki, J., & Hioka, N. (2008). The effect of operational parameters on electrocoagulation-flotation process followed by photocatalysis applied to the decontamination of water effluents from cellulose and paper factories. Journal of Hazardous Material, 160, 135-141.
Bossmann, S. H., Oliveros, E., Göb, S., Siegwart, S., Dahlen, E. P., Payawan, L., Jr., et al. (1998). New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced Fenton reactions. Journal of Physical Chemistry, 102, 5542-5550.
Bousselmi, L., Geissen, S. U., & Schroeder, H. (2004). Textile wastewater tratment and reuse by solar photocatalysis: Results from a pilot plant in Tunisia. Water Science and Technology, 49, 331-337.
Calza, P., Pelizzetti, E., & Minero, C. (2005). The fate of organic nitrogen in photocatalysis: an overview. Journal of Applied Electrochemistry, 35, 665-673.
Chen, G. (2004). Electrochemical technologies in wastewater treatment. Separation and Purification Technology, 38, 11-41.
Chen, W. R., Wu, C., Elovitz, M. S., Linden, K. G., & Suffet, I. H. (Mel). (2008). Reactions of thiocarbamate, triazine and urea herbicides, RDX and benzenes on EPA Contaminant Candidate List with ozone and with hydroxyl radicals. Water Research, 42, 137-144.
Comninellis, C., Kapalka, A., Malato, S., Parsons, S., Poulios, I., & Mantzavinos, D. (2008). Advanced oxidation processes for water treatment: Advances and trends for R&D. Journal of Chemical Technology and Biotechnology, 83, 769-776.
Dalrymple, O. K., Yeh, D. H., & Trotz, M. A. (2007). Removing pharmaceuticals and endocrine disrupting compounds from wastewater by photocatalysis. Journal of Chemical Technology and Biotechnology, 82, 121-134.
Dillert, R., Cassano, A. E., Goslich, R., & Bahnemann, D. (1999). Large scale studies in solar catalytic wastewater treatment. Catalysis Today, 54, 267-282.
Erdei, L., Arecrachakul, N., & Vigneswaran, S. (2008). A combined photocatalytic slurry reactor-immersed membrane module system for advanced wastewater treatment. Separation and Purification Technology, 62, 382-388.
Esplugas, S., Bila, D., Krause, L. G., & Dezotti, M. (2007). Ozonation and advanced oxidation technologies to remove endocrine disrupting chemicals (EDCs) and pharmaceuticals and personal care products (PPCPs) in water effluents. Journal of Hazardous Material, 149, 631-642.
Garoma, T., Gurol, M. D., Osibodu, O., & Thotakura, L. (2008). Treatment of groundwater contaminated with gasoline components by an ozone/UV process. Chemosphere, 73, 825-831.
Geissen, S., Xi, W., Weidemeyer, A., Vogelpohl, A., Bousselmi, L., Ghrabi, A., et al. (2001). Comparison of suspended and fixed photocatalytic reactor systems. Water Science and Technology, 44, 245-249.
Gibs, J., Stackelberg, P. E., Furlong, E. T., Meyer, M., Zaugg, S. T., & Lippincott, R. L. (2007). Persistence of pharmaceuticals and other organic compounds in chlorinated drinking water as a function of time. Science of the Total Environment, 373, 240-249.
Gogate, P. R., & Pandit, A. B. (2004). A review of imperative technologies for wastewater treatment I: Oxidation technologies at ambient conditions. Advances in Environmental Research, 8, 501-551.
Gomes de Moraes, S., Sanches Freire, R., & Duran, N. (2000). Degradation and toxicity reduction of textile effluent by combined photocatalytic and ozonation processes. Chemosphere, 40, 369-373.
Goslan, E. H., Gurses, F., Banks, J., & Parson, S. A. (2006). An investigation into reservoir NOM reduction by UV photolysis and advanced oxidation processes. Chemosphere, 65, 1113-1119.
Goswami, D. Y. (1997). A review of engineering developments of aqueous phase solar photocatalytic detoxification and disinfection processes. Journal of Solar Energy Engineering, 119, 101-107.
Gottschalk, C., Libra, J. A., & Saupe, A. (2000). Ozonation of water and wastewater. Weinheim, Germany: Wiley-VCH.
Guzzella, L., Feretti, D., & Monarca, S. (2002). Advanced oxidation and adsorption technologies for organic micropollutant removal from lake water used as drinking-water supply. Water Research, 36, 4307-4318.
Guzzella, L., Pozzoni, F., & Giuliano, G. (2006). Herbicide contamination of surficial groundwater in Northern Italy. Environmental Pollution, 142, 344-353.
Haber, F., & Weiss, J. (1934). The catalytic decomposition of hydrogen peroxide by iron salts. Proceedings of the Royal Society A, 134, 332-351.
Hidaka, H. (1996). Standardization protocol of process efficiencies and activation parameters in heterogeneous photocatalysis: Relative photonic efficiencies. Journal of Photochemistry and Photobiology A: Chemistry, 94, 191-203.
Hildebrandt, A., Guillamón, M., Lacorte, S., Tauler, R., & Barceló, D. (2008). Impact of pesticides used in agriculture and vineyards to surface and groundwater quality (North Spain). Water Research, 42, 3315-3326.
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995). Environmental applications of semiconductor photocatalysis. Chemical Reviews, 95, 69-96.
Hua, W., Bennett, E. R., & Letcher, R. J. (2006). Ozone treatment and the depletion of detectable pharmaceuticals and atrazine herbicide in drinking water sourced from the upper Detroit River, Ontario, Canada. Water Research, 40, 2259-2266.
Huber, M. M., Canonica, S., Park, G., & von Gunten, U. (2003). Oxidation of pharmaceuticals during ozonation and advanced oxidation processes. Environmental Science and Technology, 37, 1016-1024.
Iordache, I., Wilson, S., Lundanes, E., & Neculai, A. (2007). Comparison of Fenton and sono-Fenton bisphenol A degradation. Journal of Hazardous Materials, 142, 559-563.
Kagaya, S., Shimizu, K., Arai, R., & Hasegawa, K. (1999). Separation of titanium dioxide photocatalyst in its aqueous suspensions by coagulation with basic aluminium chloride. Water Research, 33, 1753-1755.
Kaneko, M., & Okura, I. (eds). (2002). Photocatalysis: Science and technology. Berlin, Germany: Springer.
Kitis, M., & Kaplan, S. S. (2007). Advanced oxidation of natural organic matter using hydrogen peroxide and iron-coated pumice particles. Chemosphere, 68, 1846-1853.
Klavarioti, M., Mantzavinos, D., & Kassinos, D. (2009). Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. Environment International, 35, 402-417.
Kolpin, D. W., Furlong, E. T., Meyer, M. T., Thurman, E. M., Zaugg, S. D., Barber, L. B., et al. (2002). Pharmaceuticals, hormones, and other organic wastewater contaminants in US streams, 1999-2000: A national reconnaissance. Environmental Science and Technology, 36, 1202-1211.
Kosjek, T., & Heath, E. (2008). Applications of mass spectrometry to identifying pharmaceutical transformation products in water treatment. Trends in Analytical Chemistry, 27, 807-820.
Kulik, N., Trapido, M., Goi, A., Veressinina, Y., & Munter, R. (2008). Combined chemical treatment of pharmaceutical effluents from medical ointment production. Chemosphere, 70, 1525-1531.
Legrini, O., Oliveros, E., & Braun, A. M. (1993). Photochemical processes for water treatment. Chemical Reviews, 93, 671-698.
Levec, J., & Pintar, A. (2007). Catalytic wet-air oxidation processes: A review. Catalysis Today, 124, 172-184.
Li, J., Mi, C., Li, J., Xu, Y., Jia, Z., & Li, M. (2008). The removal of MO molecules from aqueous solution by the combination of ultrasound/adsorption/photocatalysis. Ultrasonics Sonochemistry, 15, 949-954.
Ma, J., & Graham, N. J. D. (1999). Degradation of atrazine by manganese-catalysed ozonation: Influence of humic substances. Water Research, 33, 785-793.
Ma, X. J., & Xia, H. L. (2009). Treatment of water-based printing ink wastewater by Fenton process combined with coagulation. Journal of Hazardous Materials, 162, 386-390.
Malato, S., Blanco, J., Alarcón, D. C., Maldonado, M. I., Fernández-Ibáñez, P., & Gernjak, W. (2007a). Photocatalytic decontamination and disinfection of water with solar collectors. Catalysis Today, 122, 137-149.
Malato, S., Blanco, J., Alarcón, D. C., Maldonado, M. I., Fernández-Ibáñez, P., & Gernjak, W. (2007b). Photocatalytic detoxification of water with solar energy. In Y. Goswami (Ed.), Advanced in solar energy, an annual review of research and development (pp. 130-168). Boulder, CO: American Solar Energy Society.
Malato, S., Blanco, J., Vidal, A., Fernández, P., Cáceres, J., Trincado, P., et al. (2002). New large solar photocatalytic plant: Set-up and preliminary results. Chemosphere, 47, 235-240.
Mantzavinos, D., & Psillakis, E. (2004). Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment. Journal of Chemical Technology and Biotechnology, 79, 431-454.
Martinez-Huitle, C. A., & Ferro, S. (2006). Electrochemical oxidation of organic pollutants for the wastewater treatment: Direct and indirect processes. Chemical Society Reviews, 35, 1324-1340.
Mascolo, G., Ciannarella, R., Balest, L., & Lopez, A. (2008). Effectiveness of UV-based advanced oxidation processes for the remediation of hydrocarbon pollution in the groundwater: A laboratory investigation. Journal of Hazardous Materials, 152, 1138-1145.
Mason, T. J., & Lorimer, J. P. (2002). Applied sonochemistry. Weinheim, Germany: Wiley-VCH.
Menapace, H. M., Diaz, N., & Weiss, S. (2008). Electrochemical treatment of pharmaceutical wastewater by combining anodic oxidation with ozonation. Journal of Environmental Science and Health Part A, 43, 961-968.
Mills, A., & Le Hunte, S. (1997). An overview of semiconductor photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 108, 1-35.
Murray, C. A., & Parsons, S. A. (2004). Comparison of AOPs for the removal of natural organic matter: performance and economic assessment. Water Science and Technology, 49(4), 267-272.
Neyens, E., & Baeyens, J. (2003). A review of classic Fenton’s peroxidation as an advanced oxidation technique. Journal of Hazardous Materials, B98, 33-50.
Nikolaou, A., Rizzo, L., & Selcuk, H. (eds). (2007). Control of disinfection by-products in drinking water systems. Hauppauge, NY: Nova Science Publishers, Inc.
Parsons, S. (2004). Advanced oxidation processes for water and wastewater treatment. Cornwall, UK: IWA Publishing.
Petrović, M., Gonzalez, S., & Barceló, D. (2003). Analysis and removal of emerging contaminants in wastewater and drinking water. Trends in Analytical Chemistry, 22, 685-696.
Pignatello, J. J. (1992). Dark and photoassisted Fe3+-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide. Environmental Science and Technology, 26, 944-951.
Pignatello, J. J., Liu, D., & Huston, P. (1999). Evidence for an additional oxidant in the Photoassisted Fenton reaction. Environmental Science and Technology, 33, 1832-1839.
Pignatello, J. J., Oliveros, E., & MacKay, A. (2006). Advanced oxidation processes for organic contaminant destruction based on the fenton reaction and related chemistry. Critical Reviews in Environmental Science and Technology, 36, 1-84.
Rizzo, L., Della Rocca, C., Belgiorno, V., & Bekbolet, M. (2008). Application of photocatalysis as a post treatment method of a heterotrophic-autotrophic denitrification reactor effluent. Chemosphere, 72, 1706-1711.
Rosal, R., Rodriguez, A., Perdigon-Melon, J. A., Mezcua, M., Hernando, M. D., Leton, P., et al. (2008). Removal of pharmaceuticals and kinetics of mineralization by O3/H2O2 in a biotreated municipal wastewater. Water Research, 42, 3719-3728.
Sacher, F., Lange, F. T., Brauch, H.-J., & Blankenhorn, I. (2001). Pharmaceuticals in groundwaters: Analytical methods and results of a monitoring program in Baden-Wurttenberg, Germany. Journal of Chromatography A, 938, 199-210.
Safarzadeh-Amiri, A., Bolton, J. R., & Carter, S. R. (1996). The use of iron in advanced oxidation processes. Journal of Advanced Oxidation Technologies, 1, 18-26.
Serpone, N., Sauvé, G., Koch, R., Tahiri, H., Pichat, P., Piccini, P., et al. (1996). Standardization protocol of process efficiencies and activation parameters in heterogeneous photocatalysis: Relative photonic efficiencies ζr. Journal of Photochemistry and Photobiology A: Chemistry, 94(191), 203.
Song, W., Ravindran, V., & Pirbazari, M. (2008). Process optimization using a kinetic model for the ultraviolet radiation-hydrogen peroxide decomposition of natural and synthetic organic compounds in groundwater. Chemical Engineering Science, 63, 3249-3270.
Sopajaree, K., Qasim, S. A., Basak, S., & Rajeshwar, K. (1999). An integrated flow reactor-membrane filtration system for heterogeneous photocatalysis. Part II: Experiments on the ultrafiltration unit and combined operation. Journal of Applied Electrochemistry, 29, 1111-1118.
Speitel, G. E., Symons, J. M., Mialaret, J. M., & Wanielista, M. E. (2000). AOP/biofilm processes for DOX precursors. Journal of American Water Works Association, 92, 59-73.
Stackelberg, P. E., Gibs, J., Furlong, E. T., Meyer, M. T., Zaugg, S. D., & Lippincott, R. L. (2007). Efficiency of conventional drinking-water-treatment processes in removal of pharmaceuticals and other organic compounds. Science of the Total Environment, 377, 255-272.
Suty, H., De Traversay, C., & Cost, M. (2004). Applications of advanced oxidation processes: Present and future. Water Science and Technology, 49, 227-233.
Tarr, M. A. (ed). (2003). Chemical degradation methods for wastes and pollutants: Environmental and industrial applications. NY, USA: Marcel Dekker.
Tekin, H., Bilkay, O., Ataberk, S., Balta, T., Ceribasi, H., Sanin, D., et al. (2006). Use of Fenton oxidation to improve the biodegradability of a pharmaceutical wastewater. Journal of Hazardous Materials, N136, 258-265.
Thiruvenkatachari, R., Kwon, T. O., & Moon, I. S. (2005). Application of slurry type photocatalytic oxidation-submerged hollow fiber microfiltration hybrid system for the degradation of bisphenol A (BPA). Separation Science and Technology, 40, 2871-2888.
Toor, R., & Mohseni, M. (2007). UV-H2O2 based AOP and its integration with biological activated carbon treatment for DBP reduction in drinking water. Chemosphere, 66, 2087-2095.
USEPA. (2003). Occurrence Estimation Methodology and Occurrence Findings Report for the Six-Year Review of Existing National Primary Drinking Water Regulations, EPA-815-R-03-006. Office of Water, Washington, DC.
Uyguner, C. S., Bekbolet, M., & Swietlik, J. (2007). Natural organic matter: Definitions and characterization. In A. Nikolaou, L. Rizzo & H. Selcuk (Eds.), Control of disinfection by-products in drinking water systems (pp. 253-277). Hauppauge, NY: Nova Science Publishers, Inc.
Van der Kooij, D., Hijnen, W. A. M., & Kruithof, J. C. (1989). The effects of ozonation, biological filtration and distributionon the concentration of easily assimilable organic carbon (AOC) in drinking water. Ozone: Science and Engineering, 11, 297-311.
Vieno, N. M., Harkki, H., Tuhkanen, T., & Kronberg, L. (2007). Occurrence of pharmaceuticals in river water and their elimination in a pilot-scale drinking water treatment plant. Environmental Science and Technology, 41, 5077-5084.
Walling, C. (1975). Fenton’s reagent revisited. Accounts of Chemical Research, 8, 125-131.
Wang, X. J., Song, Y., & Mai, J. S. (2008). Combined Fenton oxidation and aerobic biological processes for treating a surfactant wastewater containing abundant sulfate. Journal of Hazardous Materials, 160, 34-348.
Wang, X., Zeng, G., & Zhu, J. (2008). Treatment of jean wash wastewater by combined coagulation, hydrolysis/acidification and Fenton oxidation. Journal of Hazardous Materials, 153, 810-816.
Westerhoff, P., Yoon, Y., Snyder, S., & Wert, E. (2005). Fate of endocrine-disruptor, pharmaceutical, and personal care product chemicals during simulated drinking water treatment processes. Environmental Science and Technology, 39, 6649-6663.
Xi, W., & Geissen, S. (2001). Separation of titanium dioxide from photocatalytically treated water by cross-flow microfiltration. Water Research, 35, 1256-1262.
Yoshihara, S., & Murugananthan, M. (2009). Decomposition of various endocrine-disrupting chemicals at boron-doped diamond electrode. Electrochimica Acta, 54, 2031-2038.
Zepp, R. G., Faust, B. C., & Hoigné, J. (1992). Hydroxyl radical formation in aqueous reactions (pH 3-8) of iron (II) with hydrogen peroxide: The photo-Fenton reaction. Environmental Science and Technology, 26, 313-319.
Acknowledgements
D. Fatta-Kassinos would like to acknowledge the financial assistance obtained by the Cyprus Research Promotion Foundation under the ‘PHAREM’ (ΑΕΙFΟ/0506/16), ‘SOLTEC’ (AEIFO 0308/BIE/01), ‘ESTROGENS’ (PROEM/0308/06) and ‘IX-Aqua’ (UPGRADING/DURABLE/0308/07) projects.
S. Malato wishes to thank the European Union for its financial assistance under the ‘INNOVAMED’ Project (INCO-CT-2006-517728).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2010 Springer Science+Business Media B.V.
About this chapter
Cite this chapter
Fatta-Kassinos, D., Hapeshi, E., Malato, S., Mantzavinos, D., Rizzo, L., Xekoukoulotakis, N.P. (2010). Removal of Xenobiotic Compounds from Water and Wastewater by Advanced Oxidation Processes. In: Fatta-Kassinos, D., Bester, K., Kümmerer, K. (eds) Xenobiotics in the Urban Water Cycle. Environmental Pollution, vol 16. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3509-7_21
Download citation
DOI: https://doi.org/10.1007/978-90-481-3509-7_21
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-3508-0
Online ISBN: 978-90-481-3509-7
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)