Abstract
Zeolites find three main commercial applications: in detergents, because of their ion-exchange capacity, in separations and adsorption, because of their molecular sieve properties, and as catalysts, mainly because of their high acidity. In volume, the application in detergents is by far the largest [1]. However, with respect to financial market size, catalysts form the largest application of zeolites [2]. As an example, the market volume in US $/annum of zeolite catalysts (basis 1994 figures) constitutes about 60% of the total market, with fluid catalytic cracking (FCC) catalysts forming the greatest contribution, 48% of total market, followed by hydrocracking catalysts, 7% of total market. In catalysts currently mainly zeolite Y is used, with the biggest consumption being in catalytic cracking and hydrocracking, but ZSM-5, mordenite, and other zeolites have also found commercial application in catalysts. Continuously, new catalytic applications are being developed, or existing ones further fine-tuned, by making use of the many opportunities zeolites offer for tailoring a catalyst.
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Abbreviations
- ASA:
-
amorphous silica-alumina
- BP:
-
British Petroleum Co.
- bpsd:
-
barrels per stream day
- BTX:
-
benzene toluene xylene
- CCR:
-
Conradson carbon residue
- DHCD:
-
dehydrocyclodimerization
- DIPD:
-
diisopropyldiphenyl
- DME:
-
dimethyl ether
- EB:
-
ethylbenzene
- EBHP:
-
ethylbenzene hydroperoxide
- FCC:
-
fluid catalytic cracking
- FIMS:
-
Field Ion Mass Spectrometry
- GHSV:
-
gas hourly space velocity
- HDN:
-
hydrodenitrogenation
- LABS:
-
linear alkylbenzene sulfonates
- LCO:
-
light cycle oil
- LPG:
-
liquified petroleum gases
- LR:
-
long residue
- MDDW:
-
Mobil Distillate Dewaxing
- MEK:
-
methyl ethyl ketone
- MHC:
-
Mild Hydrocracking
- MOGD:
-
Mobil Olefins to Gasoline and Distillate
- MON:
-
Motor octane number
- MSTDP:
-
Mobil Selective Toluene Disproportionation Process
- MTBE:
-
Methyl-tertiary-butyl ether
- MTDP:
-
Mobil Toluene Disproportionation Process
- MTG:
-
methanol to gasoline
- MTO:
-
methanol to olefins
- PCAH:
-
polycyclic aromatic hydrocarbons
- PCP:
-
protonated cyclopropane
- PSD:
-
pore size distribution or particle size distribution
- RON:
-
reseach octane number
- RVD:
-
Reid vapor pressure
- SMDS:
-
Shell Middle Distillate Synthesis
- SPA:
-
supported phosphoric acid
- SPGK:
-
Shell Poly-Gasoline and -Kero process
- TAME:
-
tert-amyl-methyl ether
- TBHP:
-
tert-butyl hydroperoxide
- TIGAS:
-
Topsøe Integrated Gasoline synthesis
- TIP:
-
Total Isomerization Process
- UCS:
-
unit cell size
- UOP:
-
Universal Oil Products Inc.
- URBK:
-
Union Rheinische Braunkohlen Kraftstoff AG
- USY:
-
ultrastable Y-zeolite
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Blauwhoff, P.M.M., Gosselink, J.W., Kieffer, E.P., Sie, S.T., Stork, W.H.J. (1999). Zeolites as Catalysts in Industrial Processes. In: Weitkamp, J., Puppe, L. (eds) Catalysis and Zeolites. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03764-5_7
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