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Zeolites as Catalysts in Industrial Processes

  • Chapter
Catalysis and Zeolites

Abstract

Zeolites find three main commercial applications: in detergents, because of their ion-exchange capacity, in separations and adsorption, because of their molecular sieve properties, and as catalysts, mainly because of their high acidity. In volume, the application in detergents is by far the largest [1]. However, with respect to financial market size, catalysts form the largest application of zeolites [2]. As an example, the market volume in US $/annum of zeolite catalysts (basis 1994 figures) constitutes about 60% of the total market, with fluid catalytic cracking (FCC) catalysts forming the greatest contribution, 48% of total market, followed by hydrocracking catalysts, 7% of total market. In catalysts currently mainly zeolite Y is used, with the biggest consumption being in catalytic cracking and hydrocracking, but ZSM-5, mordenite, and other zeolites have also found commercial application in catalysts. Continuously, new catalytic applications are being developed, or existing ones further fine-tuned, by making use of the many opportunities zeolites offer for tailoring a catalyst.

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Abbreviations

ASA:

amorphous silica-alumina

BP:

British Petroleum Co.

bpsd:

barrels per stream day

BTX:

benzene toluene xylene

CCR:

Conradson carbon residue

DHCD:

dehydrocyclodimerization

DIPD:

diisopropyldiphenyl

DME:

dimethyl ether

EB:

ethylbenzene

EBHP:

ethylbenzene hydroperoxide

FCC:

fluid catalytic cracking

FIMS:

Field Ion Mass Spectrometry

GHSV:

gas hourly space velocity

HDN:

hydrodenitrogenation

LABS:

linear alkylbenzene sulfonates

LCO:

light cycle oil

LPG:

liquified petroleum gases

LR:

long residue

MDDW:

Mobil Distillate Dewaxing

MEK:

methyl ethyl ketone

MHC:

Mild Hydrocracking

MOGD:

Mobil Olefins to Gasoline and Distillate

MON:

Motor octane number

MSTDP:

Mobil Selective Toluene Disproportionation Process

MTBE:

Methyl-tertiary-butyl ether

MTDP:

Mobil Toluene Disproportionation Process

MTG:

methanol to gasoline

MTO:

methanol to olefins

PCAH:

polycyclic aromatic hydrocarbons

PCP:

protonated cyclopropane

PSD:

pore size distribution or particle size distribution

RON:

reseach octane number

RVD:

Reid vapor pressure

SMDS:

Shell Middle Distillate Synthesis

SPA:

supported phosphoric acid

SPGK:

Shell Poly-Gasoline and -Kero process

TAME:

tert-amyl-methyl ether

TBHP:

tert-butyl hydroperoxide

TIGAS:

Topsøe Integrated Gasoline synthesis

TIP:

Total Isomerization Process

UCS:

unit cell size

UOP:

Universal Oil Products Inc.

URBK:

Union Rheinische Braunkohlen Kraftstoff AG

USY:

ultrastable Y-zeolite

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Blauwhoff, P.M.M., Gosselink, J.W., Kieffer, E.P., Sie, S.T., Stork, W.H.J. (1999). Zeolites as Catalysts in Industrial Processes. In: Weitkamp, J., Puppe, L. (eds) Catalysis and Zeolites. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03764-5_7

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