Abstract
We have analysed the unusual light induced changes in the Raman spectra of C60 single crystals and thin films. This changes revealed a strong dependence on the exposure of the material to ambient conditions. The changes are suppressed for temperatures above 80° C and for temperatures moderately below room temperature. Excitation to a triplet state and interaction with oxygen are considered as the main sources for the unusual behavior of the spectra.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
D.S. Bethune, G. Meijer, W.C. Tang, H.J. Rosen, Chem. Phys. Lett. 174 (1990), 219.
S.J. Duclos, R.C. Haddon, S.H. Glarum, A.F. Hebard, K.B. Lyons, Solid State Commun. 80 (1991), 481.
M. Matus, H. Kuzmany, E. Sohmen, Phys. Rev. Lett. 68 (1992), 2822.
S. Leach, M. Vervloet, A. Desprès, E. Bréheret, J.P. Hare, T.J. Dennis, H.W. Kroto, R. Taylor, D.R.M. Walton, Chem. Phys. 160 (1992), 451.
P.H.M. van Loosdrecht, P.J.M. van Bentum, G. Meijer, Chem. Phys. Lett. 205 (1993), 191.
A.M. Rao, P. Zhou, K.-A. Wang, G.T. Hager, J.M. Holden, Y. Wang, W.-T. Lee, X.-X. Bi, P.C. Eklund, D.S. Cornett, M.A. Duncan, I.J. Amster, Science 259 (1993), 955.
P.C. Eklund, (1993), this volume.
M. Haluška, H. Kuzmany, M. Vybornov, P. Rogl und P. Fejdi, Appl. Phys. A 56 (1993), 161.
M. Matus, H. Kuzmany, Appl. Phys. A 56 (1993), 241.
R. Schlögl, (1993), this volume.
J.W. Arbogast, A.P. Darmanyan, C.S. Foote, Y. Rubin, F. N. Diederich, M.M. Alvarez, S.J. Anz, R.L. Whetten, J. Phys. Chem. 95 (1991), 11.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1993 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Matus, M., Winter, J., Kuzmany, H. (1993). Stability of Single-Crystal and Thin-Film Raman Spectra in C60 . In: Kuzmany, H., Fink, J., Mehring, M., Roth, S. (eds) Electronic Properties of Fullerenes. Springer Series in Solid-State Sciences, vol 117. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-85049-3_42
Download citation
DOI: https://doi.org/10.1007/978-3-642-85049-3_42
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-85051-6
Online ISBN: 978-3-642-85049-3
eBook Packages: Springer Book Archive