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Transition Metals and Organometallics as Catalysts for Olefin Polymerization

  • Conference proceedings
  • © 1988

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Editors:
  1. Walter Kaminsky

    1. Institut für Technische und Makromolekulare Chemie, Universität Hamburg, Hamburg 13, Germany

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  2. Hansjörg Sinn

    1. Institut für Technische und Makromolekulare Chemie, Universität Hamburg, Hamburg 13, Germany

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    You can also search for this editor in PubMed   Google Scholar

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Table of contents (42 papers)

  1. Front Matter

    Pages I-XIX
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  2. Studies of Active Sites, and Kinetics and Mechanisms in Heterogeneous Catalyst

    1. Front Matter

      Pages 1-1
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    2. Kinetic Behavior During Initial Stage (less than 1 s) of Propene Polymerization with Supported Catalyst

      • Tominaga Keii, Minoru Terano, Kouhei Kimura, Kazuhiro Ishii
      Pages 3-12

    3. Activation and Stereospecific Control in Propylene Polymerization with MgCl2 Supported Ziegler-Natta Catalysts

      • A. Guyot, C. Bobichon, R. Spitz, L. Duranel, J. L. Lacombe
      Pages 13-20

    4. Isotactic Polymerization of Propene Using Living Catalysts Originally Found by Hercules Inc

      • Kazuo Soga, Hisayoshi Yanagihara
      Pages 21-32

    5. Olefin Polymerizations with a Highly Active MgCl2 Supported TiCl4 Catalyst System: Comparison on the Behaviors of Propylene, Butene-1 Ethylene and Styrene Polymerizations

      • N. Kashiwa, J. Yoshitake, T. Tsutsui
      Pages 33-43

    6. Determination of the Titanium Oxidation States in a MgCl2-Supported Ziegler-Natta Catalyst (CW-Catalyst) During Aging and Polymerization

      • S. Weber, J. C. W. Chien, Y. Hu
      Pages 45-53

    7. Behavior of the Complexes of TiCl4 with Various Carboxylic Acid Esters in MgCl2-supported High Yield Catalysts

      • M. Terano, T. Kataoka, M. Hosaka, T. Keii
      Pages 55-66

    8. Distinctive Features of Olefin Polymerization on the Surface of Supports

      • F. S. Dyachkovskii
      Pages 67-78

    9. Recent Developments in the Determination of Active Centers in Olefin Polymerization

      • J. Mejzlík, P. Vozka, J. Kratochvíla, M. Lesná
      Pages 79-90

    10. Active Centers of the Supported Organic and Hydride Transition Metal Catalysts for Ethylene Polymerization

      • V. A. Zakharov, G. A. Nesterov, S. A. Vasnetsov, K. H. Thiele
      Pages 91-100

    11. Copolymerization of Ethylene with α-Olefins by Highly Active Supported Catalysts of Various Composition

      • G. D. Bukatov, L. G. Yechevskaya, V. A. Zakharov
      Pages 101-108

    12. Stereoelective Polymerization of Racemic α-Olefins by Highly-Active Chirally Modified Ziegler-Natta Catalysts

      • F. Ciardelli, C. Carlini, F. Menconi, A. Altomare, J. C. W. Chien
      Pages 109-112

    13. Solution NMR and FT-IR studies on the reactions and the complexes of silyl ethers with triethylaluminium

      • Eero Iiskola, Pekka Sormunen, Thomas Garoff, Eila Vähäsarja, Tuula T. Pakkanen, Tapani A. Pakkanen
      Pages 113-122

    14. A Study of the Active Site Structure in MgCl2 Supported Ziegler-Natta Catalysts by a Stereochemical Investigation of the Initiation Step

      • M. C. Sacchi, I. Tritto, P. Locatelli
      Pages 123-127

    15. Ethylene Polymerization Process with a Highly Active ZieglerNatta Catalyst — Kinetic Studies

      • M. M. V. Marques, C. P. Nunes, P. J. T. Tait, A. R. Dias
      Pages 129-134

  3. New Aspects in the Heterogeneous Catalysts Polymerization of Olefins

    1. Front Matter

      Pages 135-135
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    2. Aluminium-Filled Polyethylene. Ziegler-Natta Polymerization on Filler Surface

      • S. Ewangelidis, A. Hanke, K. H. Reichert
      Pages 137-148

    3. Developments with High-Activity Titanium, Vanadium, and Chromium Catalysts in Ethylene Polymerization

      • Frederick J. Karol, Kevin J. Cann, Burkhard E. Wagner
      Pages 149-161

    4. Surface Compounds of Transition Metals, XXXIII (1) Phillips-Like Systems and their Reaction with Olefins

      • H. L. Krauss
      Pages 163-168
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Keywords

About this book

More than 30 years after the discovery of transition metals and organometal­ lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly­ merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

Editors and Affiliations

  • Institut für Technische und Makromolekulare Chemie, Universität Hamburg, Hamburg 13, Germany

    Walter Kaminsky, Hansjörg Sinn

Bibliographic Information

  • Book Title: Transition Metals and Organometallics as Catalysts for Olefin Polymerization

  • Editors: Walter Kaminsky, Hansjörg Sinn

  • DOI: https://doi.org/10.1007/978-3-642-83276-5

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1988

  • Softcover ISBN: 978-3-642-83278-9Published: 19 January 2012

  • eBook ISBN: 978-3-642-83276-5Published: 06 December 2012

  • Edition Number: 1

  • Number of Pages: XIX, 442

  • Topics: Physical Chemistry, Organic Chemistry, Polymer Sciences, Characterization and Evaluation of Materials

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