Abstract
In this paper we present new results, obtained from a variety of experiments, which probe the structure and lattice dynamics of donor- and acceptor-type graphite intercalation compounds (GIC’s). Specifically, we wish to discuss conclusions deduced from x-ray diffraction, Mössbauer, inelastic neutron scattering and Raman scattering investigations of well-staged GIC’s. The paper is organized as follows: in section II we discuss the experimental details, in section III we collect results pertaining to the chemistry, layer structure and c-axis dispersion of low-frequency phonon branches in SbCℓ5:graphite; in section IV and V we present the results of Raman scattering studies; section IV — the stage-dependence of two-phonon scattering from high-frequency graphitic modes in SbCℓ5:graphite (acceptor system) and Rb:graphite (donor system); section V- the observation and study of the temperature dependence of low frequency shear modes (ω ≃ 15, 20 cm-1) in stage 2 Rb:graphite.
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Eklund, P.C., Giergiel, J., Boolchand, P. (1981). Experimental Studies of Phonon Dispersion and C-Axis Structure in Graphite Intercalation Compounds. In: Pietronero, L., Tosatti, E. (eds) Physics of Intercalation Compounds. Springer Series in Solid-State Sciences, vol 38. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81774-8_23
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DOI: https://doi.org/10.1007/978-3-642-81774-8_23
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