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Kinetic Studies on Propene Polymerization using Magnesium Dichloride Supported Ziegler — Natta Catalysts

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Ziegler Catalysts

Abstract

This paper summarises the results of kinetic, active centre and morphological studies obtained using a number of magnesium dichloride-based catalysts when used for the polymerization of propene. In particular studies on polymerization systems using high activity catalysts such as:

MgCl2 (ball milled) / EB / TiCl4 — TEA

MgCl2 (ball milled) / EB / TiCl4 — TEA/MPT

MgCl2 (spherical) / DIBP / TiCl4 — TEA

MgCl2 (spherical) / DIBP / TiCl4 — TEA/DPDMS

MgCl2 (ethoxide type) / DNBP / TiCl4 — TEA

MgCl2 (ethoxide type) / DNBP / TiCl4 — TEA/DPDMS

are reported and the kinetic behavior of the systems analysed.

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Author information

Authors and Affiliations

  1. Department of Chemistry, UMIST, Sackville Street, P.O. Box 88, M60 1QD, Manchester, UK

    P. J. T. Tait, G. H. Zohuri & A. M. Kells

  2. ICI Plc, Chemicals and Polymers, P.O. Box 90, Wilton, Middlesborough, Cleveland, UK

    I. D. McKenzie

Authors
  1. P. J. T. Tait
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  2. G. H. Zohuri
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  3. A. M. Kells
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  4. I. D. McKenzie
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Editor information

Editors and Affiliations

  1. Max-Planck-Institut für Kohlenforschung, D-45470, Kaiser-Wilhelm-Platz 1, Mülheim, Germany

    Gerhard Fink

  2. Institut für Makromolekulare Chemie, Albert-Ludwigs-Universität Freiburg, Hermann-Staudinger-Haus, D-79104, Stefan-Meier-Straße 31, Freiburg, Germany

    Rolf Mülhaupt

  3. Universität Konstanz, D-78434, Konstanz, Germany

    Hans H. Brintzinger

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© 1995 Springer-Verlag Berlin Heidelberg

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Tait, P.J.T., Zohuri, G.H., Kells, A.M., McKenzie, I.D. (1995). Kinetic Studies on Propene Polymerization using Magnesium Dichloride Supported Ziegler — Natta Catalysts. In: Fink, G., Mülhaupt, R., Brintzinger, H.H. (eds) Ziegler Catalysts. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-79136-9_19

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  • DOI: https://doi.org/10.1007/978-3-642-79136-9_19

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-79138-3

  • Online ISBN: 978-3-642-79136-9

  • eBook Packages: Springer Book Archive

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