Abstract
During the decade, 1960–1970, boron filament progressed from its position of a $5000 per pound laboratory curiosity to its present status of a production level reinforcement fiber exhibiting superior properties for advanced composite applications. Boron filament is currently manufactured in quantities of about 30,000 lbs/year for primary use in military aircraft structures. Boron composites are being used extensively on the U.S. military aircraft, F-14 and F-15, and are being studied as a potential reinforcement material for commercial aircraft such as the DC-10, Boeing 737, and European A300 Airbus. From 1974 on, several thousand pounds of boron composites will be used on the Space Shuttle Orbiter structure, and, finally, boron composites are finding increasing application in stiffening golf shafts, tennis rackets, and bicycle frames.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
BASCHE, M., FANTI, R., GALASSO, F.: Preparation and properties of silicon carbide-coated boron filaments. Fiber Sci. Technol. 1, 19–21 (1968)
BASCHE, M., FANTI, R., GALASSO, F., KUNTZ, U., SCHILLE, R.: Method for producing boron-carbon fibers. U.S. Pat. 3, 679, 475 (1972)
BASCHE, M., JACOB, B.: Development of a Process for Producing Ribbon shaped Boron Filaments, C.R-132356. Printed by United Airways Corp. East Hartford, Conn. 1973
BASCHE, M., KUNTZ, U.E.: U.S. Pat. 3, 622, 369 (1971)
BERNEBERG, P.L., KRUKONIS, V.J.: Unpubl. Indt. Res Developm (IRAD-Z001), (1969)
BLACKMAN, L.C.F., UBBELOHDE, A.R.: Stress recrystallization of graphite. Proc. Roy. Soc. 266, 20–35 (1962)
BROWN, G.G.: Personal communication of work being carried out at Northrup Research Lab. (1974)
CAMAHORT, J.L.: Protective coating by surface nitridation of boron filament. Jour. Comp. Mater. 2, 104–111 (1968)
CAMAHORT, J.L., KRUKONIS, V.J.: Unpubl, Ind. Res. Develop. (IRAD-Y243), (1972)
CHRETIEN, A., HELCORSKY, J.: Sur les borones de molybdone et de tungstene MoB4 et WB4, Composes Nouveaux. C.R. Acad. Sci. (Paris) 252, 742–744 (1961)
DEBOLT, H.E.: Unpubl. Ind. Res. Develop. (IRAD-ZOOl), (1969)
DEBOLT, H.E.: Unpubl. Ind. Res. Develop. (IRAD-Z610), (1970)
DEBOLT, H.E.: Unpubl. Ind. Res. Develop. (IRAD-Y246), (1972)
DEBOLT, H.E., DIEFENDORF, R. J., GRUBER, P.E., JOO, L.A., KRUKONIS, V.J., MCKEE, J.A., MEHALSO, R.M.: Lower cost high strength boron filament, AFML-TR-70–287. Printed by AVCO Corporation, Lowell, Mass. (1971)
DEBOLT, H.E., KRUKONIS, V.J.: Development of a process for producing ribbon shaped filaments, NASA CR-132319. Printed by AVCO Corporation, Mass. (1973)
DEBOLT, H.E., KRUKONIS, V.J., MC KEE, J.A., PRESCOTT, R., WAWNER, F.E.; Development and demonstration of a low cost boron filament formation process, AFML-TR-72–271. Printed by AVCO Corporation, Lowell, Mass.(1972)
DIEFENDORF, R.J., MEHALSO, R.M.: Carbon monofilament as a substrate for CVD filament. Adv. Mat. Composites and Carbon, Amer. Cer. Soc, 51–58 (1971)
DIEFENDORF, R.J., MEHALSO, R.M.: Chemical vapor deposition of boron on a carbon monofilament substrate. Proc. 3rd Int. Conf. Chem. Vapor Deposition, Salt Lake City, 552–560 (1972)
FOYE, R.L.: An evaluation of various engineering estimates of the transverse properties of unidirection composites. SAMPE J. 10, G31-G42 (1966)
GALASSO, F.S.: High Modulus Fibers and Composites. New York-London-Paris; Gordon and Breach (1969)
GALASSO, F.S., PATON, A.: The tungsten borides in boron fibers. Trans. AIME 236, 1751–1752 (1966)
GRUBER, P.E.: On the kinetics of chemical vapor deposition, 2nd Int. Conf, Chem. Vapor Deposition, Los Angeles (May 1970)
HOUGH, R.L.: U.S. Pat. 3, 437, 511 (1969)
HOUGH, R.L.: High strength, continuous large diameter composite fibers, 2nd ASTM Conf. Composite Materials, Anaheim (1971)
JANAF: Thermochemical Tables, PB-168370, U.S. Dep. Commerce (1965)
KEBLER, R.W., TUCKER, R.C.: Master alloy B/A1 tape for low pressure consolidation, IR-363 (III). Printed by Union Carbide Corporation, Indianapolis, Ind. (1972)
KREIDER, K.G., DARDI, L., PREWO, K.: Metal matrix composite technology, AFML-TR-71–204. Printed by United Aircraft Corporation, East Hartford, Conn. (1971)
KRUKONIS, V.J.: Unpubl. Ind. Res. Develop. (IRAD-ZOOl), (1969)
KRUKONIS, V.J.: Unpubl. Ind. Res. Develop. (IRAD-Y246), (1972)
KRUKONIS, V.J.: Unpubl. Tensile strength of B4C-coated boron filament produced by Soc. Nat. Poudres et Explosifs (1973)
KRUKONIS, V.J., HAUZE, A.W., WAWNER, F.E.: Exploratory development and evaluation of low cost boron aluminum composites, AVSD-0242–74-CR, AVCO Corporation, Lowell, Mass. (1974)
LINE, L.E., JR., HENDERSON, U.V.: Boron filament and other reinforcements produced by chemical vapor plating. In: Handbook of Fiberglass and Advanced Plastics Composites pp 201–236. (G. Lubin, ed.), New York-London (1969)
SCHRIEVER, B.A.: A Look at the Future. 26th Conf. Aviation Writers’ Assoc. Bal Harbour (May 1964)
STARKS, D.F., HOUGH, R.L., GOLF, L.C.: Surface finishes for boron filaments. AIAA Journ. 4, 1818–1821 (1966)
TALLEY, C.P.: Mechanical properties of glassy boron. J. Appl. Phys. 30, 1114–1115 (1959)
TOTH, I.: Original SEM photograph supplied by TRW (1974)
VELTRI, R., GALASSO, F.: Tensile strength of boron filament coated with silicon carbide and of uncoated boron filament at elevated temperatures. Nature 220, 781–782 (1968)
WAGNER, R.S., ELLIS, W.C.: The vapor-liquid-solid mechanism of crystal growth — Its applications to silicon. Trans AIME 233, 1053–1064 (1965)
WAWNER, F.E., JR.: Boron filaments. In: Modern Composite Materials pp 244–269. (L. Broutman and R. Krock, eds) Reading: Addison Wesley (1967)
WAWNER, F.E., SATTERFIELD, D.B.: Observations on the tensile strength of amorphous boron. Appl. Phys. Letters 11, 192–194 (1967a)
WAWNER, F.E., SATTERFIELD, D.B.: Strength, uniformity and fracture characteristics in boron filaments. In: Boron Filament Process Development, AFML-TR-67–120, Vol. IA, Appendix C, pp C1-C43. Printed by Texaco Experiment Incorporated, Richmond, Va. (1967b)
WEINTRAUB, E.: On the properties and preparation of the element boron. J. Ind. Eng. Chem. 3, 299–301 (1911)
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1977 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Krukonis, V. (1977). Chemical Vapor Deposition of Boron Filament. In: Matkovich, V.I. (eds) Boron and Refractory Borides. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66620-9_27
Download citation
DOI: https://doi.org/10.1007/978-3-642-66620-9_27
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-66622-3
Online ISBN: 978-3-642-66620-9
eBook Packages: Springer Book Archive