Abstract
One of the environmental challenges the mining and minerals industry is facing today is the increased levels of metals in the environment due to mining, milling, and refining activities. Liquid effluents, mine waters, tailings, waste rocks, and dusts may contribute to the generation of potentially deleterious waste and contaminated groundwater and soil deposits in, around, and outside mine environments. Tailings which are unwanted silicate, oxide and sulfide minerals discarded during ore processing operations, are usually discharged into impoundments as a slurry with particle sizes that are predominantly in the silt to fine sand size range (1 µm-1 mm). Waste rock is essentially wall rock material removed to access and mine ore. Waste rock material, composed of particles ranging in size from silt to boulder size fragments, are often disposed of in large piles.
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References
Acker JG, Bricker OP (1992) The influence of pH on biotite dissolution and alteration kinetics at low temperature. Geochim Cosmochim Acta 56:3073–3092
Anbeek C, Van Breemen N, Meijer EL, Van der Plas L (1994) The dissolution of naturally weathered feldspar and quartz. Geochim Cosmochim Acta 58:4601–4613
Berner RA (1995) Chemical weathering and its effect on atmospheric CO2 and climate. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31: 565–583
Blum AE, Stillings, LL (1995) Feldspar dissolution kinetics. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31:291–351
Brantley SL, Chen Y (1995) Chemical weathering rates of pyroxenes and amphiboles. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31:119–172
Busenberg E, Plummer LN (1982) The kinetics of dissolution of dolomite in CO2-H2O systems at 1.5 to 65°C and 0 to 1 atm PCO2. American J Sci 282: 45–78
Coastec Research (1991) Acid rock drainage prediction manual. Energy Mines and Resources, Canada, CANMET,MEND report 1.16.1(b)
Drewer, JI, Clow DW (1995) Weathering rates in catchments. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Soc of America, Rev in Mineralogy 31:463–483
Eriksson N, Destouni G (1997) Combined effects of dissolution kinetics, secondary mineral precipitation, and preferential flow on copper leaching from mining waste rock. Water Resour Res 33:471–483
Feasby DG, Tremblay GA (1995) New technologies to reduce environmental liability from acid generating mine wastes. In: Hyne TP, Blanchette MC (eds), Proc of Sudbury’95 — Mining and the Environ. 28 May-1 June 1995, Sudbury, Ontario, Canada, Vol 2, pp 643–647
Heaton JS, Engstrom RC (1994) In situ atomic force microscopy study of the differential dissolution of fayalite and magnetite. Environ Sci Techn 28:1747–1754
Hering JG, Stumm W (1990) Oxidative and reductive dissolution of minerals. In: Hochella MF Jr, White AF (eds) Mineral-water interface geochemistry. Mineralogical Soc of America, Rev in Mineralogy 23:427–465
Hochella MF Jr, Banfield JF (1995) Chemical weathering of silicates in nature: a microscopic perspective with theoretical considerations. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31:353–406
Kwong YTJ (1995) Influence of galvanic sulfide oxidation on mine water chemistry. In: Hyne TP, Blanchette MC (eds), Proc of Sudbury’95 — Mining and the Environment. May 28-June 1, 1995, Sudbury, Ontario, Canada, 2, 477–483
Lapakko K (1988) Prediction of acid mine drainage from Duluth Complex mining wastes in northeastern Minnesota. 1988 Mine Drainage and Surface Mine Reclamation conference. Bureau of Mines Information Circular 1988, 10-9183; pp 180–190
Lasaga AC (1984) Chemical kinetics of water-rock interactions. Journal of Geophysical Research, 89-B6: 4009–4025
Lasaga AC, Soler, JM, Ganor J, Burch TE, Nagy KL (1994) Chemical weathering rate laws and global geochemical cycles. Geochim Cosmochim Acta 58:2361–2386
Lawrence RW, Wang Y (1997) Determination of neutralization potential for acid rock drainage prediction. Natural Resources Canada, CANMET, MEND report 1.16.3
Levenspiel O (1972) Chemical reaction engineering. John Wiley and Sons, p 578
Martello DV, Vecchio KS, Diehl JR, Graham RA, Tamilia JP, Pollack SS (1994) Do dislocations and stacking faults increase the oxidation rate of pyrites? Geochim Cosmochim Acta 58:4657–4665
Morin KA, Hutt NM, McArthur R (1995) Statistical assessment of past water chemistry to predict future chemistry at Noranda Minerals’ Bell Mine. In: Hynes T, Blanchette MC (eds) Proceedings of Sudbury’95 — Mining and the Environment. May 28-June 1, 1995, Sudbury, Ontario, Canada, Vol 3, pp 925–935
Morse JW (1983) The kinetics of calcium carbonate dissolution and precipitation. In: Reeder RJ (ed) Carbonates: mineralogy and chemistry. Mineralogical Society of America, Rev in Mineralogy 11: 227–264
Nagy KL (1995) Dissolution and precipitation kinetics of sheet silicates. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31:173–225
Nicholson RV (1994) Iron-sulfide oxidation mechanisms: laboratory studies. In: Blowes DW, Jambor JL (eds) The environmental geochemistry of sulfide mine-wastes. Mineralogical Association of Canada, Short Course Handbook Vol 22, pp 163–183
Nicholson RV, Gillham, RW, Reardon EJ (1990) Pyrite oxidation in carbonate-buffered solution: rate control by oxide coatings. Geochim Cosmochim Acta 54:395–402
Nicholson RV, Scharer JM, Kwong, ECM, Janzen MP (1997) Laboratory and modeling studies of pyrrhotite oxidation. Final Report, CANMET Contract No. 23440-4-1198/01-SQ, p 292
Norecol, Dames and Moore (1996) Guide for predicting water chemistry from waste rock piles. Natural Resources Canada, CANMET, MEND report 1.27.1a.
Otwinowski M (1995) Scaling analysis of acid rock drainage. Natural Resources Canada, CANMET, MEND report 1.19.2.
Otwinowski M (1997) Physical mechanisms in acid mine drainage waste rock piles: phase I. Physical and geostatistical aspects of acid rock drainage. Natural Resources Canada, CANMET, MEND report 1.28.1.
Perkins EH, Nesbitt HW, Gunter WD, StArnaud LC, Mycroft JR (1995) Critical review of geochemical processes and geochemical models adaptable for prediction of acidic drainage from waste rock. Natural Resources Canada, CANMET, MEND report 1.42.1.
Plummer LN, Wigley TML, Parkhurst DL (1978) The kinetics of calcite dissolution in CO2-water systems at 5 to 60°C and 0.0 to 1.0 atm CO2. American J Sci 278:179–216
Ritchie AIM (1994a) The waste-rock environment. In: Blowes DW, Jambor JL (eds) The environmental geochemistry of sulfide mine-wastes. Mineralogical Association of Canada, Short Course Handbook, Vol 22:133–161
Ritchie AIM (1994b) Sulfide oxidation mechanisms: controls and rates of oxygen transport. In: Blowes DW, Jambor JL (eds) The environmental geochemistry of sulfide mine-wastes. Mineralogical Association of Canada, Short Course Handbook, Vol 22: 201–245
Smith L, Lopez DL, Beckie R, Morin K, Dawson R, Price W (1995) Hydrogeology of waste rock dumps. Natural Resources Canada, CANMET, MEND Associate Project, July 1995.
Stillings LL, Brantley SL (1995) Feldspar dissolution at 25 °C and pH 3: reaction stoichiometry and the effect of cations. Geochim Cosmochim Acta 59:1483–1496
Sverdrup H, Warfvinge P (1995) Estimating field weathering rates using laboratory kinetics. In: White AF, Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31: 485–541
Sverjensky DA (1992) Linear free energy relations for predicting dissolution rates of solids. Nature 358: 310–313
Weatherell CJ, Feasby DG, Tremblay G (1997) The mine environment neutral drainage (MEND) program — a model of cooperative research for technology development. In: Proc of PMI 97, 28th Annual Seminars and Symp, 26 Sep-2 Oct 1997, Chicago.
White AF (1995) Chemical weathering rates of silicate minerals in soils. In: White AF, Brantley (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31: 407–461
White AF, Brantley SL (1995) Chemical weathering rates of silicate minerals. In: White AF and Brantley SL (eds) Chemical weathering rates of silicate minerals. Mineralogical Society of America, Rev in Mineralogy 31:1–22
White AF, Peterson, ML (1990) Role of reactive-surface area characterization in geochemical kinetic models. In: Melchior DC, Bassett RL (eds) Chemical modeling of aqueous systems II. American Chemical Soc Symp Series 416: 461–475
White AF, Blum AE, Schulz MS, Bullen TD, Harden JW, Peterson ML (1996) Chemical weathering rates of a soil chronosequence on granitic alluvium: I. Quantification of mineralogical and surface area changes and calculation of primary silicate reaction rates. Geochim Cosmochim Acta 60:2533–2550
White WW, Jeffers TH (1994) Chemical predictive modeling of acid mine drainage from metallic sulfide-bearing waste rock. In: Proc of American Chemical Society Symp Series 550:608–630
Williamson MA, Rimstidt JD (1994) The kinetics and electrochemical rate-determining step of aqueous pyrite oxidation. Geochim Cosmochim Acta 58:5443–5454
Wogelius RA, Walther JV (1991) Olivine dissolution at 25°C: effects of pH,CO2 and organic acids. Geochim Cosmochim Acta 55:943–954
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Paktunc, A.D. (1999). Characterization of Mine Wastes for Prediction of Acid Mine Drainage. In: Azcue, J.M. (eds) Environmental Impacts of Mining Activities. Environmental Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-59891-3_3
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DOI: https://doi.org/10.1007/978-3-642-59891-3_3
Publisher Name: Springer, Berlin, Heidelberg
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