Abstract
This paper reviews the long-range transport of toxic metal pollutants through the atmosphere and their incorporation into the environment. Metals remain among the most pervasive contaminants, because they are transported far from their point-sources and are found even in remote regions. Metal pollution has a long history, with geologic archives documenting its onset ~5000 years ago. Peak metal pollution in Europe and North America occurred in the 1970s, but has subsequently declined in part following health concerns. However, it appears to be increasing downwind of Asia, which is experiencing rapid industrialisation. Data on metal pollution are scarce from many regions, including Africa and South America. Few studies have examined long-range metal pollution in urban environments, where local pollution often masks the long-range component; however, this is likely to be a significant pollution source in many urban settings. Metal pollution remains a significant health concern as toxicology studies now imply that any exposure to Pb and Hg is potentially harmful. In addition, recent studies show historical metal pollution, stored within the Earth’s surface sediments and water bodies, can be remobilized, again causing impacts.
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References
AMAP (1997) Assessment Programme Report: Arctic pollution issues: a state of the Arctic Environment Report. Heavy Metals. Arctic Monitoring and Assessment Programme, Oslo, Norway
Anon (2008) Coal information. Organisation of Economic Co-operation and Development (OECD)/International Energy Agency (IEA)
Arimoto R, Duce RA, Ray BJ et al (1987) Trace-elements in the atmosphere of American Samoa: concentrations and deposition to the tropical South-Pacific. J Geophys Res 92:8465–8479
Arimoto R, Ray BJ, Duce RA et al (1990) Concentrations, sources, and fluxes of trace-elements in the remote marine atmosphere of New Zealand. J Geophys Res 95:22389–22405
Arimoto R, Duce RA, Savoie DL et al (1992) Trace-elements in aerosol-particles from Bermuda and Barbados—concentrations, sources and relationships to aerosol sulfate. J Atmos Chem 14:439–457
Arimoto R, Duce RA, Savoie DL et al (1996) Relationships among aerosol constituents from Asia and the North Pacific during PEM-West A. J Geophys Res 10:2011–2023
Bacardit M, Camarero L (2009) Fluxes of Al, Fe, Ti, Mn, Pb, Cd, Zn, Ni, Cu, and As in monthly bulk deposition over the Pyrenees (SW Europe): the influence of meteorology on the atmospheric component of trace element cycles and its implications for high mountain lakes. J Geophys Res. doi:10.1029/2008jg000732
Barbante C, Boutron C, Morel C et al (2003) Seasonal variations of heavy metals in central Greenland snow deposited from 1991 to 1995. J Environ Monit 5:328–335
Bellis DJ, Satake K, Inagaki M et al (2005) Seasonal and long-term change in lead deposition in central Japan: evidence for atmospheric transport from continental Asia. Sci Total Environ 341:149–158
Bergamaschi L, Rizzio E, Valcuvia MGL et al (2002) Determination of trace elements and evaluation of their enrichment factors in Himalayan lichens. Environ Pollut 120:137–144
Bindlera R, Renberga I, Klamindera J et al (2004) Tree rings as Pb pollution archives? A comparison of 206Pb/207Pb isotope ratios in pine and other environmental media. Sci Total Environ 319:173–183
Bogdal C, Schmid P, Zennegg M et al (2009) Blast from the past: melting glaciers as a relevant source for persistent organic pollutants. Environ Sci Technol 43:8173–8177
Brännvall M, Binnderl R, Renberg I (1999) The medival metal industry was the cradle of modern large-scale atmospheric lead pollution in northern Europe. Environ Sci Technol 33:4391–4395
Chiaradia M, Gulson BL, James M et al (1997) Identification of secondary lead sources in the air of an urban environment. Atmos Environ 31:3511–3521
Chow TJ, Patterson CC (1961) The occurrence and significance of lead isotopes in pelagic sediments. Geochim Cosmochim Acta 26:263–308
Conrad CF, Chisholm-Brause CJ (2004) Spatial survey of trace metal contaminants in the sediments of the Elizabeth River, Virginia. Mar Pollut Bull 49:319–324
Crone H (2004) Paracelsus: the man who defied medicine: his real contribution to medicine. The Albarello Press, Melbourne
Diaz-Somoano M, Kylander ME, Lopez-Anton MA et al (2009) Stable lead isotope compositions in selected coals from around the world and implications for present day aerosol source tracing. Environ Sci Technol 43:1078–1085
Erel Y, Dayan U, Rabi R et al (2006) Trans boundary transport of pollutants by atmospheric mineral dust. Environ Sci Technol 40:2996–3005
Erel Y, Kalderon-Asael B, Dayan U et al (2007) European atmospheric pollution imported by cooler air masses to the Eastern Mediterranean during the summer. Environ Sci Technol 41:5198–5203
Espi E, Boutron CF, Hong S et al (1997) Changing concentrations of Cu, Zn, Cd and Pb in a high altitude peat bog from Bolivia during the past three centuries. Water Air Soil Pollut 100:289–296
Förstner U (1990) Inorganic sediment chemistry and elemental speciation. In: Baudo R, Giesy J, Muntau H (eds) Sediments: chemistry and toxicity of in-place pollutants. Lewis Publishers, INC, Chelsea
Fujiwara F, Dos Santos M, Marrero J et al (2006) Fractionation of eleven elements by chemical bonding from airborne particulate matter collected in an industrial city in Argentina. J Environ Monit 8:913–922
Grandjean P, Weihe P, Jørgensen PJ et al (1992) Impact of maternal seafood diet on fetal exposure to mercury, selenium, and lead. Arch Environ Health 47:185–195
Gulson BL, Davis JJ, Mizon KJ et al (1995a) Sources of lead in soil and dust and the use of dust fallout as a sampling medium. Sci Total Environ 166:245–262
Gulson BL, Mahaffey KR, Mizon KJ et al (1995b) Contribution of tissue lead to blood lead in adult female subjects based on stable lead isotope methods. J Lab Clin Med 125:703–712
Hageman KJ, Simonich SL, Campbell DH et al (2006) Atmospheric deposition of current-use and historic-use pesticides in snow at national parks in the western United States. Environ Sci Technol 40:3174–3180
Halstead MJR, Cunninghame G, Hunter KA (2000) Wet deposition of trace metals to a remote site in Fiordland, New Zealand. Atmos Environ 34:665–676
Harmens H, Norris DA, Koerber GR et al (2007) Temporal trends in the concentration of arsenic, chromium, copper, iron, nickel, vanadium and zinc in mosses across Europe. Atmos Environ 41:6673–6687
Henry F, Amara R, Courcot L et al (2004) Heavy metals in four fish species from the French coast of the eastern English Channel and Southern Bight of the North Sea. Environ Int 30:675–683
Hong S, Candelone JP, Patterson CC et al (1996) History of ancient copper smelting pollution during Roman and medieval times recorded in Greenland ice. Science 272:246–249
Hong SM, Barbante C, Boutron C et al (2004) Atmospheric heavy metals in tropical South America during the past 22000 years recorded in a high altitude ice core from Sajama, Bolivia. J Environ Monit 6:322–326
Jaffe D, Strode S (2008) Sources, fate and transport of atmospheric mercury from Asia. Environ Chem 5:121–126
Jaffe D, Anderson T, Kotchenruther R et al (1999) Transport of Asian air pollution to North America. Geophysi Res Lett 26:711–714
Jaffe D, McKendry I, Anderson T et al (2003) Six ‘new’ episodes of trans-Pacific transport of air pollutants. Atmos Environ 37:391–404
Jaffe D, Prestbo E, Swartzendruber P et al (2005) Export of atmospheric mercury from Asia. Atmos Environ 39:3029–3038
Kabata-Pendias A (2001) Trace elements in soils and plants. CRC Press LLC, Boca Raton
Kamber BS, Greig A, Collerson KD (2005) A new estimate for the composition of weathered young upper continental crust from alluvial sediments, Queensland, Australia. Geochim Cosmochim Acta 69:1041–1058
Kim KH, Ma CJ, Okuda T (2009) An analysis of long-term changes in airborne toxic metals in South Korea’s two largest cities from 1991 to 2004. Environ Sci Pollut Res 16:565–572
Kirby J, Maher W, Krikowa F (2001) Selenium, cadmium, copper and zinc concentrations in sediments and Mullet (Mugil cephaluts) from the southern basin of Lake Macquarie, NSW, Australia. Arch Environ Contam Toxicol 40:246–256
Le Roux G, Weiss D, Grattan J et al (2004) Identifying the sources and timing of ancient and medieval atmospheric lead pollution in England using a peat profile from Lindow bog, Manchester. J Environ Monit 6:502–510
Lee CSL, Qi SH, Zhang G et al (2008) Seven thousand years of records on the mining and utilization of metals from lake sediments in central China. Environ Sci Technol 42:4732–4738
Lin CY, Liu SC, Chou CCK et al (2005) Long-range transport of aerosols and their impact on the air quality of Taiwan. Atmos Environ 39:6066–6076
Martinez-Cortizas A, Pontevedra-Pombal X, Garcia-Rodeja E et al (1999) Mercury in a Spanish peat bog: archive of climate change and atmospheric metal deposition. Science 284:939–942
Marx SK, Kamber BS, McGowan HA (2005) Provenance of long travelled dust determined with ultra-trace-element composition: a pilot study with samples from New Zealand glaciers. Earth Surf Process and Landf 30:699–716
Marx SK, Kamber BS, McGowan HA (2008) Scavenging of trace metal pollutants by mineral dust: inter-regional transport of trace metal pollution to New Zealand. Atmos Environ 42:2460–2478
Marx SK, Kamber BS, McGowan HA et al (2010) Atmospheric pollutants in alpine peat bogs record a detailed chronology of industrial and agricultural development on the Australian continent. Environ Pollut. doi:10.1016/j.envpol.2009.12.009
McConnell JR, Edwards R (2008) Coal burning leaves toxic heavy metal legacy in the Artic. PNAS 105:12140–12144
McLennan SM (2001) Relationships between the trace element composition of sedimentary rocks and upper continental crust. Geochem Geophys Geosyst. doi:10.1029/2000GC000109
Miller JR, Lechler PJ, Hudson-Edwards KA et al (2002) Lead isotopic fingerprinting of heavy metal contamination, Rio Pilcomayo basin, Bolivia. Geochem Explor Environ Anal 2:225–233
Mubiana VK, Qadah D, Meys J et al (2005) Temporal and spatial trends in heavy metal concentrations in the marine mussel Mytilus edulis from the Western Scheldt estuary (The Netherlands). Hydrobiologia 540:169–180
Nriagu JO (1983) Lead and lead poisoning in antiquity. Wiley, New York
Nriagu JO (1990) The rise and fall of leaded gasoline. Sci Total Environ 92:13–28
Nriagu JO (1994) Mercury pollution from the past mining of gold and silver in the Americas. Sci Total Environ 149:167–181
Nriagu JO, Pacyna JM (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace metals. Nature 333:134–139
Okuda T, Tenmoku M, Kato J et al (2006) Long-term observation of trace metal concentration in aerosols at a remote island, Rishiri, Japan by using inductively coupled plasma mass spectrometry equipped with laser ablation. Water Air Soil Pollut 174:3–17
Osterberg E, Mayewski P, Kreutz K et al (2008) Ice core record of rising lead pollution in the North Pacific atmosphere. Geophys Res Lett. doi:10.1029/2007gl032680
Outridge PM, Stern GA, Hamilton PB et al (2005) Trace metal profiles in the varved sediment of an Arctic lake. Geochim Cosmochim Acta 69:4881–4894
Owen BD, Flegal AR (1998) Blood lead concentrations in marine mammals validate estimates of 102- to 103-fold increase in human blood lead concentrations. Environ Res 78:134–139
Pacyna JM, Pacyna EG (2001) An assessment of global and regional emissions of trace metals to the atmosphere from anthropogenic sources worldwide. Environ Rev 9:269–298
Parrish DD, Hahn CJ, Williams EJ et al (1992) Indications of photochemical histories of Pacific air masses from measurements of atmospheric trace species at Point Arena, California. J Geophys Res 97:15883–15901
Patterson CC (1965) Contaminated and natural lead environments of man. Arch Environ H 11:344–360
Prospero JM (1999) Long-term measurements of the transport of African mineral dust to the southeastern United States: implications for regional air quality. J Geophys Res 104:15917–15927
Prospero JM, Glaccum RA, Nees RT (1981) Atmospheric transport of soil dust from Africa to South America. Nature 289:570–572
Reimann C, DeCaritat P, Halleraker JH et al (1997) Regional atmospheric deposition patterns of Ag, As, Bi, Cd, Hg, Mo, Sb and Tl in a 188,000 km2 area in the European arctic as displayed by terrestrial moss samples—long-range atmospheric transport vs local impact. Atmos Environ 31:3887–3901
Renzoni A, Zino F, Franchi E (1998) Mercury levels along the food chain and risk for exposed populations. Environ Res 77:68–72
Reynolds PH (1971) A U-Th-Pb lead isotope study of rocks and ores from Broken-Hill, Australia. Earth Planet Sci Lett 12:215–223
Rotstayn LD, Cai WJ, Dix MR et al (2007) Have Australian rainfall and cloudiness increased due to the remote effects of Asian anthropogenic aerosols? J Geophys Res. doi:10.1029/2006JD007712
Rühling Å, Tyler G (2004) Changes in the atmospheric deposition of minor and rare elements between 1975 and 2000 in south Sweden, as measured by moss analysis. Environ Pollut 131:417–423
Schwartz J (1994) Low-level lead exposure and children’s IQ: a meta-analysis and search for a threshold. Environ Res 65:42–55
Settle DM, Patterson CC (1982) Magnitudes and sources of precipitation and dry deposition fluxes of industrial and natural lead to the North Pacific at Enewetak. J Geophys Res 87:8857–8885
Shevchenko V, Lisitzin A, Vinogradova A, Stein R (2003) Heavy metals in aerosols over the seas of the Russian Arctic. Sci Total Environ 306:11–25
Shotyk W (2002) The chronology of anthropogenic, atmospheric Pb deposition recorded by peat cores in three minerogenic peat deposits from Switzerland. Sci Total Environ 292:19–31
Shotyk W, Weiss D, Appleby PG et al (1998) History of atmospheric lead deposition since 12, 370 14C yr BP from a peat bog, Jura Mountains, Switzerland. Science 281:1635–1640
Shotyk W, Weiss D, Kramers JD et al (2001) Geochemistry of the peat bog at Etang de la Gruere, Jura Mountains, Switzerland, and its record of atmospheric Pb and lithogenic trace metals (Sc, Ti, Y, Zr, and REE) since 12, 370 C-14 yr BP. Geochim Cosmochim Acta 65:2337–2360
Shotyk W, Krachler M, Martinez-Cortizas A et al (2002) A peat bog record of natural, pre-anthropogenic enrichments of trace elements in atmospheric aerosols since 12, 370 C-14 yr BP, and their variation with Holocene climate change. Earth Planet Sci Lett 199:21–37
Smith DR, Flegal AR (1992) The public health implications of humans’ natural levels of lead. Am J Public Health 82:1565–1566
Spencer KL, Cundy AB, Croudace IW (2003) Heavy metal distribution and early-diagenesis in salt marsh sediments from the Medway Estuary, Kent, UK. Estuar Coast Shelf Sci 57:43–54
Spokes LJ, Jickells TD (2002) Speciation of metals in the atmospehre. In: Ure AM, Davidson CM (eds) Chemical speciation in the environment. Blackwell Science Ltd, Oxford
Szczepaniak K, Biziuk M (2003) Aspects of the biomonitoring studies using mosses and lichens as indicators of metal pollution. Environ Res 93(3):221–230
Townsend AT, Snape I (2002) The use of Pb isotope ratios determined by magnetic sector ICP-MS for tracing Pb pollution in marine sediments near Casey Station, East Antarctica. J Anal At Spectrom 17:922–928
Tylecote RF (1976) A history of metallurgy. The metals society, London, 177 pp
Vallelonga P, Van de Velde K, Candelone JP et al (2002) The lead pollution history of Law Dome, Antarctica, from isotopic measurements on ice cores: 1500 AD to 1989 AD. Earth Planet Sci Lett 204(1–2):291–306
Wheatley B, Barbeau A, Clarkson TW, Lapham LW (1979) Methylmercury poisoning in Canadian Indians—elusive diagnosis. Can J Neurol Sci 6(4):417–422
WHO (2007) Joint WHO Task force on the health aspects of air pollution, health risks of heavy metals from long-range transboundary air pollution. World Health Organization, Copenhagen
Wolff WW, Suttie ED, Peel DA (1999) Antarctic snow record of cadmium, copper and zinc content during the twentieth century. Atmos Environ 33:1535–1541
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Marx, S.K., McGowan, H.A. (2010). Long-Distance Transport of Urban and Industrial Metals and Their Incorporation into the Environment: Sources, Transport Pathways and Historical Trends. In: Zereini, F., Wiseman, C. (eds) Urban Airborne Particulate Matter. Environmental Science and Engineering(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-12278-1_6
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