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Supramolecular Nanostructures of Phthalocyanines and Porphyrins at Surfaces Based on the “Bottom-Up Assembly”

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Functional Phthalocyanine Molecular Materials

Part of the book series: Structure and Bonding ((STRUCTURE,volume 135))

Abstract

The “bottom-up” strategy is an attractive and promising approach for the construction of nanoarchitectures. Supramolecular assemblies based on noncovalent interactions have been explored in an attempt to control the surface properties. In this chapter, we focus on advances made in the past 5 years in the field of scanning tunneling microscopy (STM) on supramolecularly nanostructured phthalocyanines and porphyrins on single-crystal surfaces. The design of supramolecular nanoarchitectures consisting of phthalocyanines and porphyrins, supramolecular traps of C60 and coannulene, direct metallation on phthalocyanines and porphyrins adlayers, direct synthesis of porphyrin oligomers at surfaces, axial coordination of phthalocyanines and porphyrins, and nanoapplications induced by tip manipulation at surfaces were clearly visualized by STM.

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Acknowledgements

This work was supported in part by the JST program “Special Coordination Funds for Promoting Science and Technology” (S.Y.) and by a Grant-in-Aid for Scientific Research on Innovative Areas (No. 20108007, “π-Space”) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.

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  1. Priority Organization for Innovation and Excellence, Kumamoto University, 2–39–1 Kurokami, Kumamoto, 860–8555, Japan

    Soichiro Yoshimoto

  2. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980–8578, Japan

    Nagao Kobayashi

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  1. Soichiro Yoshimoto
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  2. Nagao Kobayashi
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Correspondence to Soichiro Yoshimoto .

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  1. Dept. Chemistry, Shandong University, Jinan, 250100, China, People's Republic

    Jianzhuang Jiang

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Yoshimoto, S., Kobayashi, N. (2010). Supramolecular Nanostructures of Phthalocyanines and Porphyrins at Surfaces Based on the “Bottom-Up Assembly”. In: Jiang, J. (eds) Functional Phthalocyanine Molecular Materials. Structure and Bonding, vol 135. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-04752-7_5

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