Abstract
The method of piezoelectric microgravimetry (nanogravimetry) using an electrochemical quartz crystal microbalance (EQCM) or nanobalance (EQCN) can be considered as a novel and much more sensitive version of electrogravimetry. The EQCN technique has become a widely used technique in several areas of electrochemistry, electroanalytical chemistry, bioelectrochemistry, etc. [1–10]. Obviously, mass changes occurring during adsorption, sorption, electrosorption, electrodeposition, or spontaneous deposition can be followed, which is very helpful for the elucidation of reaction mechanism via identification of the species accumulated on the surface. These investigations include metal and alloy deposition, underpotential deposition, electroplating, synthesis of conducting polymers by electropolymerization, adsorption of biologically active materials, and analytical determination of small ions and biomolecules. Of course, the opposite processes, i.e., spontaneous dissolution, electrodissolution, corrosion, can also be studied. Electrochemical oscillations, in which the formation and oxidation of chemisorbed molecular fragments play a determining role, have been studied, too. The majority of the investigations have been devoted to ion and solvent transport associated with the redox transformations of electrochemically active polymers. Similar studies have been carried out regarding polynuclear surface layers such as metal hexacyanometalates as well as inorganic and organic microcrystals of different compositions.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Buttry DA (1991) Applications of the quartz crystal microbalance to electrochemistry. In: Bard AJ (ed) Electroanalytical chemistry, vol 17. Marcel Dekker, New York, pp 1–85
Buttry DA, Ward MD (1992) Chem Rev 92: 1355
Grate JW, Martin SJ, White RM (1993) Anal Chem 65: 940A; 987A
Hepel M (1999) In: Wieczkowski A (ed), Interfacial electrochemistry. Marcel Dekker, New York, pp 599–630
Hillman AR (2003) The electrochemical quartz crystal microbalance. In: Bard AJ, Stratmann M (eds) Encyclopedia of electrochemistry, vol 3. Unwin PR (ed), Wiley-VHC, Weinheim pp 230–289
Buck RP, Lindner E, Kutner W, Inzelt G (2004) Pure Appl Chem 76: 1139–1160
Tsionsky V, Daikhin L, Urbakh M, Gileadi E (2004) Looking at the metal/solution interface with electrochemical quartz-crystal microbalance: theory and experiment. In: Bard AJ, Rubinstein I (eds) Electroanalytical chemistry, vol 22. Marcel Dekker, New York, pp 2–94
Lu C, Czanderna AW (eds) (1984) Applications of piezoelectric quartz crystal microbalances. Elsevier, New York
O’Sullivan CK, Guilbault (1999) Biosens Bioelectron 14: 663
Calvo EJ, Etchenique RA (1999) Kinetic applications of the electrochemical quartz crystal microbalance (EQCM). In: Compton RG, Hancock G (eds) Comprehensive chemical kinetics, vol 37. Elsevier, Amsterdam, pp 461–487
Kern P, Landolt D (2000) J Electrochem Soc 147: 318
Kim JM, Chang SM, Muramatsu H (1999) J Electrochem Soc 146: 4544
Henderson MJ, Hillman AR, Vieil E (1998) J Electroanal Chem 454: 1
Inzelt G, Horányi G (1989) J Electrochem Soc 136: 1747
Friedt J-M, Choi KH, Frederix F, Campitelli A (2003) J Electrochem Soc 150: H229
Gollas B, Bartlett PN, Denuault (2000) Anal Chem 72: 349
Gabrielli C, Keddam M, Perrot H, Torresi R (1994) J Electroanal Chem 378: 85
Sauerbrey G (1959) Z Phys 155: 206
Bácskai J, Láng G, Inzelt G (1991) J Electroanal Chem 319: 55
Lee WW, White HS, Ward MD (1993) Anal Chem 65: 3232
Smalley JF, Guy L, Feldberg SW, Rogers LC, Leddy J (1993) J Electroanal Chem 356: 181
Róka A, Varga I, Inzelt G (2006) Electrochim Acta 51: 6243
Wasberg M, Bácskai J, Inzelt G, Horányi G (1996) J Electroanal Chem 418: 195
Inzelt G (2008) Conducting polymers. A new era in electrochemistry. In: Scholz F (ed) Monographs in electrochemistry. Springer, Berlin Heidelberg
Inzelt G, Németh K, Róka A (2007) Electrochim Acta 52: 4015
Inzelt G, Puskás Z, Németh K, Varga I (2005) J Solid State Electrochem 9: 823
Inzelt G, Kertész V (1993) Electrochim Acta 38: 2385
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2010 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Inzelt, G. (2010). Electrochemical Quartz Crystal Nanobalance. In: Scholz, F., et al. Electroanalytical Methods. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-02915-8_13
Download citation
DOI: https://doi.org/10.1007/978-3-642-02915-8_13
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-02914-1
Online ISBN: 978-3-642-02915-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)