Skip to main content

Progress in Thermodynamic Database Development for ICME of Mg Alloys

  • Chapter
Magnesium Technology 2015

Abstract

Integrated thermodynamic software packages are a powerful tool to analyze phase formation in multicomponent Mg alloys, providing key data for focused alloy and process development. The thermodynamic database of the alloy system is the indispensable basis for this direct application, but also needed for any further step towards Integrated Computational Materials Engineering. The database quality, which may vary widely, is crucial for the reliability of such applications. Progress in development and extension of the large thermodynamic database for magnesium alloys is reported, with emphasis on consistency, coherency and quality assurance. One aspect is the coherent description of large solid solution ranges of intermetallic phases in multicomponent Mg alloys with rare earths. Further addition of Zn may produce complex icosahedral, long-period stacking order (LPSO) or other hexagonal phases. All these may form highly efficient secondary phase precipitates in the (Mg) matrix. Examples are given for Mg-Ce-La, Mg-Ce-Y, and Mg-Gd-Nd-Y-Zn-Zr alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. L. Kaufman, H. Bernstein, “Computer Calculations of Phase Diagrams”, Academic Press: New York, NY, 1970.

    Google Scholar 

  2. H. L. Lukas, S. G. Fries, B. Sundman, “Computational thermodynamics: The Calphad Method”, Cambridge University Press, 2007.

    Book  Google Scholar 

  3. W. Cao, S. Chen, F. Zhang, K. Wu, Y. Yang, Y.A. Chang, R. Schmid-Fetzer, W.A. Oates, “PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation”, Calphad 33 (2009) 328–342.

    Article  Google Scholar 

  4. J.O. Andersson, T. Helander, L. Höglund, P. Shi, B. Sundman, “Thermo-Calc & DICTRA, computational tools for materials science”, Calphad, 26 (2002) 273–312.

    Article  Google Scholar 

  5. C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, I.-H. Jung, Y.-B. Kang, J. Melançon, A.D. Pelton, C. Robelin, S. Petersen, “FactSage thermochemical software and databases — recent developments”, Calphad, 33 (2009) 295–311

    Article  Google Scholar 

  6. A.A. Luo, P. Fu, L. Peng, X. Kang, X., Z. Li, T. Zhu, “Solidification micro structure and mechanical properties of cast magnesium-aluminum-tin alloys”, Met. Mater. Trans., 43A (2012) 360–368.

    Article  Google Scholar 

  7. A.A. Luo, B.R. Powell, A.K. Sachdev, “Computational phase equilibria and experimental investigation of magnesium-aluminum-calcium alloys”, Intermetallics, 24 (2012) 22–29.

    Article  Google Scholar 

  8. A.C. Hänzi, F.H. Dalla Torre, L. Zhao, P. Gunde, R. Schmid-Fetzer, M. Kuehlein, J.F. Loftier, P.J. Uggowitzer, “Design strategy for microalloyed ultra-ductile magnesium alloys”, Phil. Mag. Lett., 89 (2009) 377–390.

    Article  Google Scholar 

  9. A. Pisch, R. Schmid-Fetzer, “Development of a thermodynamic Mg-alloy database by experiments and modeling”, in “Magnesium Alloys and their Applications”, B.L. Mordike, K.U. Kainer (eds.), Int. Conf., Wolfsburg, April 28–30, 1998, Werkstoff-Informationsgesellschaft mbH, Frankfurt, (1998) 139–144.

    Google Scholar 

  10. R. Schmid-Fetzer, J. Gröbner, “Focused Development of Magnesium Alloys using the Calphad Approach”, Advanced Engineering Materials, 3 (2001) 947–961.

    Article  Google Scholar 

  11. R. Schmid-Fetzer, A. Janz, J. Gröbner, M. Ohno, “Aspects of quality assurance in a thermodynamic Mg alloy database”, Advanced Engineering Materials, 7 (2005) 1142–1149.

    Article  Google Scholar 

  12. R. Schmid-Fetzer, J. Groebner, D. Mirkovic, A. Janz, A. Kozlov, “Constitution of Magnesium Alloys”, in “Magnesium Technology 2007” R. Beals, M. Pekguleryuz, N. Neelameggham (eds.), TMS (The Minerals, Metals & Materials Society), (2007) 339–344.

    Google Scholar 

  13. J. Gröbner, A. Janz, A. Kozlov, D. Mirkovic, R. Schmid-Fetzer, “Phase diagrams of advanced magnesium alloys containing Al, Ca, Sn, Sr and Mn”, J. Metals, No. 12 (December), (2008) 32–38.

    Google Scholar 

  14. R. Schmid-Fetzer, J. Gröbner, “Thermodynamic database for Mg alloys — progress in multicomponent modeling”, Metals, 2, (2012) 377–398 (Special Issue “Magnesium Technology”), Open Access, www.mdpi.com/2075–4701/2/3/377, DOI: 10.3390/met2030377

    Article  Google Scholar 

  15. J. Gröbner, R. Schmid-Fetzer, “Key issues in a thermodynamic Mg alloy database” Metall. Mater. Trans. A, A44, (2013) 2918–2934.

    Article  Google Scholar 

  16. O. Klag, J. Gröbner, G. Wagner, R. Schmid-Fetzer, D. Eitler, “Mcrostructural and Thermodynamic Investigations on Friction Stir Welded Mg/Al-Joints”, Int. J. Materials Research (Z. Metallkunde), 105 (2014) 145–155.

    Article  Google Scholar 

  17. R. Schmid-Fetzer, D. Andersson, P. Y. Chevalier, L. Eleno, O. Fabrichnaya, U.R. Kattner, B. Sundman, C. Wang, A. Watson, L. Zabdyr, M. Zinkevich, “Assessment techniques, database design and software facilities for thermodynamics and diffusion”. Calphad, 31 (2007) 38–52.

    Article  Google Scholar 

  18. J. Gröbner, M. Hampl, R. Schmid-Fetzer, MA. Easton, S.M. Zhu, MA. Gibson, J.F. Nie, “Phase Analysis of Mg-La-Nd and Mg-La-Ce Alloys”, Intermetallics, 28 (2012) 92–101.

    Article  Google Scholar 

  19. J. Gröbner, R. Schmid-Fetzer, “Thermodynamic modeling of the Mg-Ce-Gd-Y system”, Scripta Materialia, 63 (2010) 674–679.

    Article  Google Scholar 

  20. Xingguo Zhang, Linggang Meng, Canfeng Fang, Peng Peng, Fei Ja, Hai Hao, “Effect of Nd on the micro structure and mechanical properties of Mg-8Gd-5Y-2Zn-0.5Zr alloy”. Materials Science and Engineering: A, 586 (2013) 19–24.

    Article  Google Scholar 

  21. E. Scheil, “Bemerkungen zur Schichtkristallbildung”, Z. Metallkd., 34 (1942) 70–72.

    Google Scholar 

  22. R. Schmid-Fetzer, “Phase diagrams — the Beginning of Wisdom”, J. Phase Equil. Diffusion, (2014) online-first, Open Access DOI: 10.1007/s11669–014-0343–5.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Schmid-Fetzer, R. (2015). Progress in Thermodynamic Database Development for ICME of Mg Alloys. In: Manuel, M.V., Singh, A., Alderman, M., Neelameggham, N.R. (eds) Magnesium Technology 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48185-2_53

Download citation

Publish with us

Policies and ethics