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Polyacrylonitrile-Based Materials: Properties, Methods and Applications

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Advanced Materials

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 175))

Abstract

Polyacrylonitrile (PAN ) is extremely popular and attracts much attention due to its unique structure and ability to change the structure under heating. PAN and modifying additives (Cu(II), Ag(I), Co(II), Cr(III)) were dissolved in DMF and coated on polycor substrates and then the thin films  were fabricated by pyrolysis method under the influence of incoherent IR-radiation under low vacuum conditions. Surface structure and morphology of the fabricated samples were investigated by X-ray photoelectronic spectroscopy (XPS ), X-ray diffraction analysis (XPD ), transmission electron microscopy (TEM ), scanning electron microscopy (SEM ), atomic force microscopy (AFM ). The electrical resistance of the metal-containing PAN films was measured in the range from 102 to 1012 Ω. The fabricated films demonstrate gas-sensing properties to NO2, Cl2, NH3 and gasoline vapors at room temperature.

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Acknowledgments

This work was performed with the financial support of the Federal Targeted Program “Investigation and High Priority Branches of Development of Scientific Technological Complexes of Russia for the period of 2014–2020” of the Ministry of Education and Science of the Russian Federation (the unique project number RFMEFI57514X0103). The equipment of the Centre of Collective Use of Equipment “Nanotechnologies” and Multi-Access Center of Microsystem Engineering and Integral Sensor Technology of the Southern Federal University as well as the Kabardino-Balkarsky State University and the Helmholtz-Zentrum Berlin für Materialien und Energie was used for this study. The author is also grateful to M.M. Brzhezinskaya, Helmholtz-Zentrum Berlin für Materialien und Energie, Berlin, Germany; to Z. Kh. Kalazhokov and Kh.Kh. Kalazhokov, Kabardino-Balkarsky State University, Nalchik, Kabardino-Balkar Republic, Russia; to O.A. Ageev, Engineering-Technological Academy, Southern Federal University, Taganrog, Russia.

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Authors and Affiliations

  1. Engineering-Technological Academy, Southern Federal University, Taganrog, Russia

    T. V. Semenistaya

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  1. T. V. Semenistaya
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Correspondence to T. V. Semenistaya .

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Editors and Affiliations

  1. Southern Federal University, Rostov-on-Don, Russia

    Ivan A. Parinov

  2. Department of Microelectronics, National Kaohsiung Marine University, Kaohsiung City, Taiwan

    Shun-Hsyung Chang

  3. Rostov on Don, Russia

    Vitaly Yu. Topolov

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Semenistaya, T.V. (2016). Polyacrylonitrile-Based Materials: Properties, Methods and Applications. In: Parinov, I., Chang, SH., Topolov, V. (eds) Advanced Materials. Springer Proceedings in Physics, vol 175. Springer, Cham. https://doi.org/10.1007/978-3-319-26324-3_5

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