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Abstract

Chemical Solution Deposition (CSD) offers a relatively robust fabrication route in the formation of complex metal oxide thin films. This utility stems largely from the straightforward control of film stoichiometry via the concentration of metallic components in the precursor solutions. There are several techniques by which these precursor solutions can be applied to substrates, each with their own merits that enable specific applications. The purpose of this chapter will be to describe the aerosol deposition of precursor solutions and to compare this technique against other established coating methods. The key processes by which aerosol deposition takes place will be examined and various deposition techniques will be explained on the basis of these processes. Finally, the characteristics of aerosol deposited films will be discussed and the applications in which aerosol deposition has been employed will be presented.

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References

  1. Brubaker M, Mumbauer PD, Grant R (2001) Deposition and thermal processing of ferroelectric thin films with the Primaxx 2F platform. Integr Ferroelectr 36:305–312

    Article  Google Scholar 

  2. Solayappan N, Joshi V, DeVilbiss A, Bacon J, Cuchiaro J, McMillan L, Paz de Araujo C (1998) Chemical solution deposition (CSD) and characterization of ferroelectric and dielectric thin films. Integr Ferroelectr 22:1–11

    Article  Google Scholar 

  3. Kawasaki S, Motoyama SI, Tatsuta T, Tsuji O, Shiosaki T (2003) Fabrication of Pb(Zr,Ti)O3 thin films by liquid source misted chemical deposition method equipped with a mist-droplet size controller. Integr Ferroelectr 53:287–297

    Google Scholar 

  4. Grace JM, Marijnissen JCM (1994) Review of liquid atomization by electrical means. J Aerosol Sci 25:1005–1019

    Article  Google Scholar 

  5. Hinds WC (1999) Aerosol technology: properties, behavior, and measurement of airborne particles, 2nd edn. Wiley, New York

    Google Scholar 

  6. Reist PC (1984) Introduction to aerosol science. Macmillan/Collier Macmillan, New York/London

    Google Scholar 

  7. Fuchs NA (1964) In: Davies CN (ed transl) The mechanics of aerosols. Pergamon, Oxford, pp 378–394 (revised and enlarged edn)

    Google Scholar 

  8. Schlichting H, Oertel H (2000) Grenzschicht-Theorie. English: Boundary-layer theory, 8th rev. and enl. edn. Springer, Berlin

    Google Scholar 

  9. Primaxx Technical literature. Primaxx, Inc, Allentown, PA http://www.primaxxinc.com

  10. Siefert W (1984) Corona spray pyrolysis – a new coating technique with an extremely enhanced deposition efficiency. Thin Solid Films 120:267–274

    Article  Google Scholar 

  11. Mumbauer P, Chang K, Mahoney W, Lee DO, Shanmugasundaram PK, Roman P, Brubaker M, Grant R, Ruzyllo J (2004) Mist deposition in semiconductor device manufacturing. Semicond Int 27:75–80

    Google Scholar 

  12. Adamson AW, Gast AP (1997) Physical chemistry of surfaces, 6th edn. Wiley, New York

    Google Scholar 

  13. Blake TD, Clarke A, Stattersfield EH (2000) Investigation of electrostatic assist in dynamic wetting. Langmuir 16(6):2928–2935

    Article  Google Scholar 

  14. Langlet M, Vautey C, Mazeas N (1997) Some aspects of the aerosol-gel process. Thin Solid Films 299(1–2):25–32

    Article  Google Scholar 

  15. Ortega J, Kodas TT (1992) Control of particle morphology during multicomponent metal oxide powder generation by spray pyrolysis. J Aerosol Sci 23(SUPPL 1):253–256

    Article  Google Scholar 

  16. Khoroshun IV, Karyaev EV, Moshnyaga VT, Kiosse GA, Krachun MA, Zakosarenko VM, Davydov VY (1990) Characteristics of epitaxial Y-Ba-Cu-O thin-films grown by aerosol MOCVD technique. Supercond Sci Technol 3:493–496

    Article  Google Scholar 

  17. Grigoriev D, Choy KL (2004) Aerosol deposition of films in an electrical field: modelling and experiment. Scr Mater 51:857–861

    Article  Google Scholar 

  18. Kuang-Che H, Shih-Chieh L, Yi-Jia C (2007) Synthesis, characterization and photocatalytic property of nanostructured Al-doped ZnO powders prepared by spray pyrolysis. Mater Sci Eng A 447:71–76

    Article  Google Scholar 

  19. Losego MD, Trolier-McKinstry S (2003) Mist deposition of micron-thick lead zirconate titanate films. Materials Research Society, Boston, MA

    Google Scholar 

  20. Schuler T, Krajewski T, Grobelsek I, Aegerter M (2004) A microstructural zone model for the morphology of sol-gel coatings. J Sol-Gel Sci Technol 31:235–239

    Article  Google Scholar 

  21. Takahashi Y, Okada S, Tahar RBH, Nakano K, Ban T, Ohya Y (1997) Dip-coating of ITO films. J Non-Cryst Solids 218:129–134

    Article  Google Scholar 

  22. Moshnyaga V, Khoroshun I, Sidorenko A, Petrenko P, Weidinger A, Zeitler M, Rauschenbach B, Tidecks R, Samwer K (1999) Preparation of rare-earth manganite-oxide thin films by metalorganic aerosol deposition technique. Appl Phys Lett 74:2842–2844

    Article  Google Scholar 

  23. Mooney JB, Radding SB (1982) Spray pyrolysis processing. Annu Rev Mater Sci 12:81–101

    Article  Google Scholar 

  24. Aukkaravittayapun S, Wongtida N, Kasecwatin T, Charojrochkul S, Unnanon K, Chindaudom P (2006) Large scale F-doped SnO2 coating on glass by spray pyrolysis. Thin Solid Films 496:117–120

    Article  Google Scholar 

  25. Solayappan N, McMillan LD, Paz de Araujo CA, Grant B (1997) Second generation liquid source misted chemical deposition (LSMCD) technology for ferroelectric thin films. Integr Ferroelectr 18:127–136

    Article  Google Scholar 

  26. Chung HJ, Choi JH, Lee JY, Woo SI (2001) Preparation and electrical properties of (Ba,Sr)TiO3 thin films deposited by liquid source misted chemical deposition. Thin Solid Films 382:106–112

    Article  Google Scholar 

  27. Lee DO, Roman P, Wu CT, Mumbauer P, Brubaker M, Grant R, Ruzyllo J (2002) Mist deposited high-k dielectrics for next generation MOS gates. Solid-State Electron 46(11):1671–1677

    Article  Google Scholar 

  28. Mahoney WJ III, Roman P, Mumbauer P, Ruzyllo J (2004) Mist deposition of thin photoresist films. In: Sturtevant JL (ed) Advances in resist technology and processing XXI, vol 5376. Proceedings of SPIE, Bellingham, WA, pp 861–866. doi:10.1117/12.534149

  29. Shanmugasundaram K, Price S, Chang K, Lee D, Ruzyllo J (2006) Mist deposition for TFT technology. ECS Trans 3:255–259

    Article  Google Scholar 

  30. Shanmugasundaram K, Brubaker M, Chang K, Mumbauer P, Roman P, Ruzyllo J (2007) Studies of solution processed metal oxides on silicon. Microelectron Eng 84:2294–2297

    Article  Google Scholar 

  31. Takakuwa A, Ishida M, Shimoda T (2005) Micropatterning of SrBi2Ta2O9 ferroelectric thin films using a selective deposition technique combined with patterned self-assembled monolayers and liquid-source misted chemical deposition. Jap J Appl Phys, Part 1 44:1897–1900

    Article  Google Scholar 

  32. Takakuwa A, Mitani T, Shimoda T (2007) Micropatterning of indium tin oxide thin films by selective deposition and improvement in selectivity by combination with substrate vibration. Jap J Appl Phys, Part 1 46:3016–3019

    Article  Google Scholar 

  33. Kawasaki S, Catalan G, Fan HJ, Saad MM, Gregg JM, Correa-Duarte MA, Rybczynski J, Morrison FD, Tatsuta T, Tsuji O, Scott JF (2008) Conformal oxide coating of carbon nanotubes. Appl Phys Lett 92:053109

    Article  Google Scholar 

  34. Morrison FD, Ramsay L, Scott JF (2003) High aspect ratio piezoelectric strontium-bismuth-tantalate nanotubes. J Phys Condens Matter 15:527–532

    Article  Google Scholar 

  35. Zhu T, Shanmugasundaram K, Price SC, Ruzyllo J, Zhang F, Xu J, Mohney SE, Zhang Q, Wang AY (2008) Mist fabrication of light emitting diodes with colloidal nanocrystal quantum dots. Appl Phys Lett 92:023111

    Article  Google Scholar 

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Correspondence to Matt D. Brubaker .

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Brubaker, M.D. (2013). Aerosol Deposition. In: Schneller, T., Waser, R., Kosec, M., Payne, D. (eds) Chemical Solution Deposition of Functional Oxide Thin Films. Springer, Vienna. https://doi.org/10.1007/978-3-211-99311-8_12

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