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Order-Disorder Phenomena in Metal Hydrides

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Metal Hydrides

Part of the book series: NATO Advanced Study Institutes Series ((NSSB,volume 76))

Abstract

In the last decade, considerable progress has been made in the study of order-disorder phenomena in metal hydrides. The purpose of this paper is to review the recent investigations on the order-disorder transitions in hydrides of the group V transition metals (V, Nb and Ta) and of Pd. The emphasis is put upon the features of structural changes in the equilibrium states on the basis of experimental data.

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References

  1. K. K. Kelley, Specific heat of Ta at low temperatures and the effect of small amounts of dissolved hydrogen, J. chem. Phys., 8: 316 (1940).

    Article  CAS  Google Scholar 

  2. T. R. Waite, W. E. Wallace and R. S. Craig, Structures and phase relationships in the Ta-H system between -145 and 70°C, J. chem. Phys., 24: 634 (1956).

    Article  CAS  Google Scholar 

  3. W. G. Saba, W. E. Wallace, H. Sandmo and R. S. Craig, Heat capacities and the residual entropy of Ta2H, J. chem. Phys., 35: 2148 (1961).

    Article  Google Scholar 

  4. W. E. Wallace, Neutron diffraction data for Ta2D and the probable arrangement of the deuteriums in two of its polymorphic varieties, J. chem. Phys., 35: 2156 (1961).

    Article  CAS  Google Scholar 

  5. K. Honda, Die Theorie der Stahlhärtung, Archir. Eisenhüttenwesen, Gruppe E, 8: 527 (1928).

    Google Scholar 

  6. C. Zener, Kinetics of the decomposition of austenite, Trans. AIME, 167: 550 (1946). Details are discussed in: Theory of strain interaction of solute atoms, Phys. Rev., 74: 639 (1948).

    Google Scholar 

  7. H. Sato, On the ordered arrangement of interstitial atoms in interstitial solid solution, J. Jpn. Inst. Met., 17: 601 (1954). (in Japanese).

    Google Scholar 

  8. M. Hirabayashi, S. Yamaguchi, H. Asano and K. Hiraga, Order-disorder transformations of interstitial solutes in transition metals of IV and V groups, in: “Order-Disorder Transitions in Alloys,” H. Warlimont, ed., Springer-Verlag, Berlin, 266 (1974).

    Google Scholar 

  9. V. A. Somenkov and S. S. Shil’stein, Structural behaviour of hydrogen in metals and intermetallic compounds, Z. Phys. Chem. (N.F.), 117: 125 (1979).

    Article  CAS  Google Scholar 

  10. V. A. Somenkov and S. S. Shil’stein, Phase transitions of hydrogen in metals, Prog. Mat. Sci., 24: 267 (1980).

    Google Scholar 

  11. G. Alefeld, Wasserstoff in Metallen als Beispiel für ein Gittergas mit Phasenumwandlungen, phys. stat. sol., 32: 67 (1969).

    CAS  Google Scholar 

  12. Y. Fukai and H. Sugimoto, Quantum-mechanical approach to the state of hydrogen in bcc metals, Proc. JIMIS-2, Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met., 21: 41 (1980).

    Google Scholar 

  13. A. G. Khachaturyan, Ordering in substitutional and interstitial solid solutions, Prog. Mat. Sci., 22: 1 (1978).

    CAS  Google Scholar 

  14. H. E. Cook and D. de Fontaine, On the elastic free energy of solid solutions, I. Microscopic theory, Acta Met., 17: 915 (1969).

    Article  CAS  Google Scholar 

  15. T. Moriya and H. Ino, Ordered structures of interstitial solutes in bcc lattice, J. Phys. Soc. Jpn., 46: 1776 (1979).

    Article  CAS  Google Scholar 

  16. J. Kanamori, Magnetization process in an Ising spin system, Prog. theor. Phys., 35: 16 (1966).

    CAS  Google Scholar 

  17. M. Kaburagi and J. Kanamori, A method of determining the ground state of the extended-range classical lattice gas model, Prog. theor. Phys., 54: 30 (1975).

    Google Scholar 

  18. T. Schober and H. Wenzl, The systems NbH(D), TaH(D), VH(D); structures, phase diagrams, morphologies, methods of preparation, in: “Hydrogen in Metals” II, G. Alefeld and J. Völkl, ed., Springer-Verlag, Berlin (1978).

    Google Scholar 

  19. H. Asano and M. Hirabayashi, Hydrogen ordering in Va transition metal hydrides, Z. Phys. Chem. (N.F.), 114: 1 (1979).

    Article  CAS  Google Scholar 

  20. I. Okada, H. Asano and M. Hirabayashi, Refinement of the structure of ß-V2D by single crystal neutron diffraction, Proc. JIMIS-2, Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met., 21: 89 (1980).

    Google Scholar 

  21. H. Asano and M. Hirabayashi, Neutron diffraction studies of metal hydrides, This proceedings.

    Google Scholar 

  22. M. Hirabayashi, Structural phase transition of metal hydrides; V-H and V-D, Proc. JIMIS-2, Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met., 21: 49 (1980).

    Google Scholar 

  23. H. S. U. Jo and S. C. Moss, Deuterium-induced vanadium short-range modulation above Tc in single crystal V2D, Modulated Structures-1979. Proc. AIP Conf. No. 53: 400 New York (1979).

    Google Scholar 

  24. H. Asano and M. Hirabayashi, Hydrogen (deuterium) location and tetragonal distortion in 8-VHX and 8-V2D, Proc. 2nd Int. Cong. Hydrogen in Met., Paris, 1D6, (1977).

    Google Scholar 

  25. H. Metzger, H. Jo, S. C. Moss and D. G. Westlake, Single crystal X-ray study of the superstructure modulation and long-range order in V2D, phys. stat. sol., (a) 47: 631 (1978).

    CAS  Google Scholar 

  26. H. Asano, Y. Abe and M. Hirabayashi, A calorimetric study of the phase transformation of vanadium hydrides VH0.06-VH0.77, Acta Met., 24: 95 (1976).

    Article  CAS  Google Scholar 

  27. I. Okada, Master Thesis, Tohoku University, (1980).

    Google Scholar 

  28. G. Bambakidis, M. W. Pershing and R. C. Bowman, Jr., Electrical resistivity studies of order-disorder phenomena in V2H and V2D, Scripta Met., 13: 441 (1979).

    Article  CAS  Google Scholar 

  29. D. G. Westlake, M. H. Mueller and H. W. Knott, Structural transitions at low temperatures in vanadium deuterides, J. appl. Cryst., 6: 206 (1973).

    Article  CAS  Google Scholar 

  30. H. Asano and M. Hirabayashi, Interstitial superstructures of V-D, phys. stat. sol. (a) 15: 267 (1973).

    Article  CAS  Google Scholar 

  31. T. Schober and W. Pesch, The systems V-H and V-D, Z. Phys. Chem. (N.F.), 114: 21 (1979).

    Article  CAS  Google Scholar 

  32. Y. Fukai and S. Kazama, On the constitution of 8-VHX, Scripta Met., 9: 1073 (1975).

    Article  CAS  Google Scholar 

  33. D. G. Westlake, A resistometric contribution to the V-H phase diagram, Scripta Met., 11: 887 (1977).

    Article  CAS  Google Scholar 

  34. S. Takano, H. Kojima, R. Akaba and T. Suzuki, On the martensitic transformation a-8 of a V2H single crystal, Proc. JIMIS-2, Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met., 21: 85 (1980).

    Google Scholar 

  35. Y. Fukai and S. Kazama, NMR studies of anomalous diffusion of hydrogen and phase transition in V-H alloys, Acta Met., 25: 59 (1977).

    Article  CAS  Google Scholar 

  36. T. Kajitani, private communication.

    Google Scholar 

  37. V. A. Somenkov, A. V. Gurskaya, M. G. Zemlyanov, M. E. Kost, N. A. Chernoplekov and A. A. Chertkov, Neutron scattering study of structure and phase transitions in niobium hydrides and deuterides, Sov. Phys.-Solid State, 10: 1076 (1968).

    Google Scholar 

  38. G. Mair, K. Bichmann and H. Wenzl, Structural transformation correlated with order-disorder transformations of H in NbH crystals, Z. Phys. Chem., (N.F.), 114: 29 (1979).

    Article  CAS  Google Scholar 

  39. W. Pesch, T. Schober and H. Wenzl, TEM investigation of anisotropie lattice distortions in ordered NbH and NbD alloys, Scripta Met., 12: 815 (1978).

    Article  CAS  Google Scholar 

  40. B. J. Makenas, Precipitation and ordering in the Nb-H system, Ph. D. Thesis, University of Illinois, (1978).

    Google Scholar 

  41. T. O. Brun, T. Kajitani, M. H. Mueller, D. G. Westlake, B. J. Makenas and H. K. Birnbaum, The structure of the X-phases of Nb-D, Modulated Structures-1979. Proc. AIP Conf. No. 53: 397, New York (1979).

    Google Scholar 

  42. T. Kajitani, T. O. Brun, M. H. Mueller, H. K. Birnbaum and B. J. Makenas, Modulated ordering Nb-H alloys, Modulated Structures-1979, Proc. AIP Conf., No. 53: 394, New York (1979).

    Google Scholar 

  43. M. A. Pick, Strukturelle Phasenübergänge in NbH System, Tech. Rpt. Jül-951-FF, KFA Jülich (1973).

    Google Scholar 

  44. J. Hauck, Ordering of hydrogen in niobium hydride phases, Acta Cryst., A33: 208 (1977).

    Google Scholar 

  45. H. Asano, Y. Ishino, R. Yamada and M. Hirabayashi, Interstitial superstructures in the Ta-D system, J. Solid State Chem., 15: 45 (1975).

    Article  CAS  Google Scholar 

  46. W. A. Oates, J. A. Lambert and P. T. Gallagher, Monte Carlo calculations of configurational entropies in interstitial solid solutions, Trans. AIME, 245: 47 (1969).

    CAS  Google Scholar 

  47. H. Asano, R. Yamada and M. Hirabayashi, A calorimetric study of the phase transformation in tantalum hydrides, Trans. Jpn. Inst. Met., 18: 155 (1977).

    CAS  Google Scholar 

  48. F. Ducastelle, R. Caudron and P. Costa, Etude de systeme Ta-H; diagramme d’equilibre et structure electronique, J. Phys. Chem. Solids, 31: 1247 (1970).

    Article  CAS  Google Scholar 

  49. T. G. Berlincourt and P. W. Bickel, Electrical properties of Ta2H, Phys. Rev., B2: 4838 (1970).

    Article  Google Scholar 

  50. Unpublished work.

    Google Scholar 

  51. T. Schober and A. Carl, A revision of the Ta-H phase diagram, Scripta Met., 11: 397 (1977).

    Article  CAS  Google Scholar 

  52. U. Köbler and T. Schober, Susceptibility and phase diagram of the Ta-H system, J. Less-Comm. Met., 60: 101 (1978).

    Article  Google Scholar 

  53. E. Wicke and H. Brodowsky, Hydrogen in palladium and palladium alloys, in: Hydrogen in Metals II, G. Alfeld and J. Völkl ed., Springer-Verlag, Berlin (1978).

    Google Scholar 

  54. J. Völkl, This proceedings.

    Google Scholar 

  55. T. Springer, Investigation of vibrations in metal hydrides by neutron spectroscopy, in: Hydrogen in Metals I, G. Alefeld and J. Völkl ed., Springer-Verlag, Berlin (1978).

    Google Scholar 

  56. E. N. Economou, This proceedings.

    Google Scholar 

  57. D. M. Nace and J. G. Aston, Palladium hydride II, The entropy of Pd2H at 0°K, J. Am. Chem. Soc., 79: 3623 (1957).

    Article  CAS  Google Scholar 

  58. J. K. Jacobs and F. D. Manchester, Thermal and motional aspects of the 50 K transition in PdH and PdD, J. Less-Comm. Met., 49: 67 (1976).

    Article  CAS  Google Scholar 

  59. I. S. Anderson, C. J. Carlile and D. K. Ross, The 50 K transition in 13-phase Pd deuteride observed by neutron scattering, J. Phys. C 11: L 381 (1978).

    Google Scholar 

  60. I. S. Anderson, D. K. Ross and C. J. Carlile, The structure of the y phase of Pd deuteride, Phys. Letters 68A: 249 (1978).

    Article  Google Scholar 

  61. O. Blaschko, R. Klemencic, P. Weinzierl and O. J. Eder, Investigation of the 50 K transition in PdHo 73 by y-ray and neutron diffraction, Solid State Comm., 27: 1149 (1978).

    Article  CAS  Google Scholar 

  62. A. G. Khachaturyan, The problem of symmetry in statistical thermodynamics of substitutional and interstitial ordered solid solutions, phys. stat. sol. (b) 60: 9 (1973).

    Article  CAS  Google Scholar 

  63. H. A. Goldberg, Model possibilities for the 50 K transition in Pd-Hx, Transition Metals-1977, Proc. AIP Conf.,No. 39: 504, New York (1977).

    Google Scholar 

  64. T. E. Ellis, C. B. Satterthwaite, M. H. Mueller and T. O. Brun, Evidence for H(D) ordering in PdHX(PdDX), Phys. Rev. Letters, 42: 457 (1979).

    Article  Google Scholar 

  65. O. Blaschko, R. Klemencic, P. Weinzierl and O. J. Eder, (1 1/2 0) superlattice reflection in ß-PdDX, J. Phys. F. 9: L 113 (1979).

    Google Scholar 

  66. I. S. Anderson, C. J. Carlile, D. K. Ross and D. L. T. Wilson, Interstitial interactions in the Pd-H(D) system, Z. Phys. Chem. (N.F.), 115: 165 (1979).

    Article  CAS  Google Scholar 

  67. M. H. Mueller, T. O. Brun, R. L. Hitterman, H. W. Knott, C. B. Satterthwaite and T. E. Ellis, Deuteron density modulation of D atoms in PdD1_X, Modulated Structures-1979. Proc. AIP Conf. No. 53: 391, New York (1979).

    Google Scholar 

  68. T. Kajitani, private communication.

    Google Scholar 

  69. H. Kanzaki, Point defects in face-centered cubic lattice, J. Phys. Chem. Solids, 2: 24 (1957).

    Article  Google Scholar 

  70. H. Goldberg and F. D. Manchester, Low temperature ordering in PdHX(DX) alloys, Phys. Letters, 68A: 360 (1978).

    Article  Google Scholar 

  71. D. de Fontaine, k-space symmetry rules for order-disorder reactions, Acta Met., 23: 553 (1975).

    Article  Google Scholar 

  72. P. C. Clapp and S. C. Moss, Correlation functions of disordered binary alloys, I, Phys. Rev., 142: 418 (1966). II, III, ibid, 171: (1978) 754, 764.

    Google Scholar 

  73. C. B. Satterthwaite, T. E. Ellis and R. J. Miller, On the nature of the 50 K anomaly in Pd-H, Transition Metals-1977, Proc. AIP Conf., No. 39: 501, New York (1977).

    Google Scholar 

  74. R. J. Miller and C. B. Satterthwaite, Electronic model for the reverse isotope effect in superconducting Pd-H(D), Phys. Rev. Letters, 34: 144 (1975).

    Article  CAS  Google Scholar 

  75. A. Fujimori, M. Ishii and N. Tsuda, Infrared and Raman spectra of non-stoichiometric cerium hydrides, phys. stat. sol. (b), 99: 673 (1980).

    Article  CAS  Google Scholar 

  76. D. G. de Groot, R. G. Barnes, B. J. Beaudry and D. R. Torgeson, Nuclear magnetic resonance evidence for the occurrence of an ordered structure in the La-H system near LaH2.65 at 250 K, Z. Phys. Chem. (N.F.), 114: 83 (1979).

    Article  Google Scholar 

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Authors and Affiliations

  1. The Research Institute for Iron, Steel and Other Metals, Tohoku University, Sendai 980, Japan

    Makoto Hirabayashi

  2. Institute of Materials Science, University of Tsukuba, Ibaraki 305, Japan

    Hajime Asano

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  1. Makoto Hirabayashi
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  2. Hajime Asano
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  1. Wright State University, Dayton, Ohio, USA

    Gust Bambakidis

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Hirabayashi, M., Asano, H. (1981). Order-Disorder Phenomena in Metal Hydrides. In: Bambakidis, G. (eds) Metal Hydrides. NATO Advanced Study Institutes Series, vol 76. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5814-6_3

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  • DOI: https://doi.org/10.1007/978-1-4757-5814-6_3

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