Abstract
More is known about the rates of ion-molecule reactions than about those of any other family of chemical reactions. This chapter will not, however, consist of a joyful celebration of that pleasant reality, but rather, the reverse—it will take a somewhat severe look at what we need to know, at what we sometimes think we know; and at what in fact we do know. The ultimate objective, complete and mutual overlap of all three domains, is very far from being realized: in reality, despite the proclamation of the first sentence, there is little overlap between the first and third categories at the present time.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
L.M. Branscomb, Is the literature worth reviewing?, Sci. Res. 3 (11), 49–56 (1968).
E. E. Ferguson, F. C. Fehsenfeld, and A. L. Schmeltekopf, in “Advances in Atomic and Molecular Physics” (D.R. Bates and I. Estermann, eds.), Vol. 5, pp. 1–56, Academic Press, New York (1969).
T.F. George and R.J. Suplinskas, Kinematic model for reaction. II. Ion-molecule reactions involving H2 and D2, J. Chem. Phys. 51, 3666–3670 (1969).
I. G. Csizmadia, J. C. Polanyi, A. C. Roach, and W. H. Wong, Distribution of reaction products (theory). VII. D+ + H2 → DH + H+ using an ab initio potential-energy surface, Can. J. Chem. 47, 4097–4099 (1969).
E.A. Gislason, B.H. Mahan, C.W. Tsao, and A.S. Werner, Evidence for long-lived collision complexes in ion-molecule reactions: DO2 + from O2 + and D2, J. Chem. Phys. 50, 5418–5419 (1969).
H. Pauly and J.P. Toennies, in “Advances in Atomic and Molecular Physics” (D.R. Bates and I. Estermann, eds.) Vol. 1, pp. 195–344, Academic Press, New York (1965).
V. Čermák and Z. Herman, Mass spectrometric study of the formation of N3 + and C2O+ ions, Collection Czech. Chem. Commun. 30, 1343–1357 (1965).
W.B. Maier II and R.F. Holland, Emission from metastable states in a nitrogen ion beam, J. Chem. Phys. 52, 2997–3001 (1970).
S. J. Wisniewski, R. P. Clow, and J. H. Futrell, On the competition between unimolecular dissociation and ion-molecule reaction of cis-2-butene molecular ions, J. Phys. Chem. 74, 2234–2235 (1970).
J.C. Light, J. Ross, and K.E. Schuler, in “Kinetic Processes in Gases and Plasmas” (A.R. Hochstim, ed.), pp. 281–320, Academic Press, New York (1969).
D.R. Herschbach, in “Advances in Chemical Physics” (J. Ross, ed.), Vol. 10, pp. 319–393, Interscience, New York (1966).
J. L.J. Rosenfeld and J. Ross, Calculation of chemical reaction probabilities from elastic scattering data, J. Chem. Phys. 44, 188–194 (1966).
R.J. Beuhler, Jr. and R.B. Bernstein, Crossed-beam study of the reactive asymmetry of oriented methyl iodide molecules with rubidium, J. Chem. Phys. 51, 5305–5315 (1969).
P.R. Brooks, Molecular beam reaction of K with oriented CF3I. Evidence for harpooning?, J. Chem. Phys. 50, 5031–5032 (1969).
E. F. Greene and A. Kuppermann, Chemical reaction cross sections and rate constants, J. Chem. Ed. 45, 361–369 (1968).
J.P. Toennies, Molecular beam investigations of bimolecular reactions, Ber. Bunsenges. Phys. Chem. 72, 927–949 (1968).
M. Menzinger and R. Wolfgang, The meaning and use of the Arrhenius activation energy, Angew. Chem. Internat. Edit. 8, 438–444 (1969).
J. I. Steinfeld and J. L. Kinsey, in “Progress in Reaction Kinetics” (G. Porter, ed), Vol. 5, pp. 1–28, Pergamon Press, Oxford (1970).
J. E. Jordan, E. A. Mason, and I. Amdur, in “Physical Methods in Chemistry” (A. Weissberger and B.W. Rossiter, eds.), Interscience, New York (in press).
L. A. Melton and R. G. Gordon, Extraction of reaction cross section from rate constant data: D + H2 → HD + H, J. Chem. Phys. 51, 5449–5457 (1969).
J.C. Light, Phase-space theory of chemical kinetics, J. Chem. Phys. 40, 3221–3229 (1964).
J.C. Light, Conversion of phenomenological to microscopic cross sections for ion-molecule reactions, J. Chem. Phys. 41, 586–587 (1964).
G. Gioumousis, Cross Sections and Rate Constants for Ion-Molecule Reactions, Lockheed Research Laboratory, Palo Alto, California, Report No. 2–12–66–4 (October 1966).
V. L. Talrose and E. L. Frankevich, Pulse method of determining the rate constants of ion-molecule reactions, Russian J. Phys. Chem. 34, 1275–1279 (1960).
C.W. Pyun, Nonequilibrium effects in free-radical recombination and ion-molecule reaction kinetics, J. Chem. Phys. 48, 1306–1311 (1968).
C. W. Pyun, Nonequilibrium effects in gas reactions, J. Chem. Phys. 50, 2782–2783 (1969).
I. Szabo, Consecutive ion-molecule reactions in ethylene investigated by means of positive ion-impact, Arkiv Fysik 33, 57–71 (1967).
P. Warneck, Studies of ion-neutral reactions by a photoionization mass-spectrometer technique. I, J. Chem. Phys. 46, 502–512 (1967).
L. W. Sieck, S.K. Searles, and P. Ausloos, High-pressure photoionization mass spectrometry. I. Unimolecular and bimolecular reactions of C4H8 + from cyclobutane, J. Am. Chem. Soc. 91, 7627–7634 (1969).
E.W. McDaniel, in “Methods of Experimental Physics” (B. Bederson and W. L. Fite, eds.), Vol. 7A, pp. 361–390, Academic Press, New York (1968).
C.F. Barnett and H.B. Gilbody, in “Methods of Experimental Physics” (B. Bederson and W.L. Fite, eds.), Vol. 7A, pp. 390–476, Academic Press, New York (1968).
E.W. McDaniel, V. Čermák, A. Dalgarno, E.E. Ferguson, and L. Friedman, “Ion-Molecule Reactions,” Wiley-Interscience, New York (1970).
C. F. Giese and W. B. Maier II, Energy dependence of cross sections for ion-molecule reactions. Transfer of hydrogen atoms and hydrogen ions, J. Chem. Phys. 39, 739–748 (1963).
M.J. Henchman, H. Otwinowska, and F.H. Field, in “Advances in Mass Spectrometry” (W.L. Mead, ed.), Vol. 3, pp. 359–375, Institute of Petroleum, London (1966).
L. Matus, I. Opauszky, D. Hyatt, A.J. Masson, K. Birkinshaw, and M. J. Henchman, Kinematic investigations of ion-neutral collision mechanisms at ~ 1 eV, Disc. Faraday Soc. 44, 146–156 (1967).
E.W. McDaniel, Possible sources of large error in determinations of ion-molecule reaction rates with drift tube-mass spectrometers, J. Chem. Phys. 52, 3931–3935 (1970).
D.W. Vance, Relative population of N+ and N2 + in a “mass-14” ion beam, J. Chem. Phys. 48, 1873–1874 (1968).
A.J. Masson, Ph.D. Thesis, Brandeis University (1971); A.J. Masson and M.J. Henchman, unpublished work.
K. R. Ryan and J. H. Futrell, Effect of translational energy on ion-molecule reaction rates. I, J. Chem. Phys. 42, 824–829 (1965).
J.H. Futrell, in “Advances in Mass Spectrometry” (W.L. Mead, ed.), Vol. 3, p. 432, Institute of Petroleum, London (1966).
H. Pauly and J. P. Toennies, in “Methods of Experimental Physics” (B. Bederson and W.L. Fite, ed.), Vol. 7A, pp. 227–341, Academic Press, New York (1968).
A.G. Harrison and J.J. Myher, Ion-molecule reactions in mixtures with D2 or CH4, J. Chem. Phys. 46, 3276–3277 (1967).
M.G. Holliday, J.T. Muckerman, and L. Friedman, Isotopic studies of the proton-hydrogen molecule reaction, J. Chem. Phys. 54, 1058–1072 (1971).
T.M. Miller, Ph.D. Thesis, Georgia Institute of Technology (1968).
J. Heimerl, R. Johnsen, and M. Biondi, Ion-molecule reactions, He+ + O2 and He+ + N2, at thermal energies and above, J. Chem. Phys. 51, 5041–5048 (1969).
P. J. Chantry, Doppler broadening in beam experiments, Bull. Am. Phys. Soc. 16, 212–213 (1971).
W.B. Maier II, Atom transfer in endothermic ion-molecule reactions, J. Chem. Phys. 46, 4991–4992 (1967).
D.G. Truhlar, Statistical phase-space theory of the reaction C+ + D2 including threshold behavior, J. Chem. Phys. 51, 4617–4623 (1969).
P. J. Chantry, Doppler broadening in beam experiments J. Chem. Phys. 55, 2746–2759 (1971).
E. Lindholm, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P.J. Ausloos, ed.), pp. 1–19, American Chemical Society, Washington, D.C.(1966).
R. L. Champion and L. D. Doverspike, Charge transfer and dissociative charge transfer between rare-gas ions and molecular nitrogen, J. Chem. Phys. 49, 4321–4329 (1968).
A. J. Masson, K. Birkinshaw, and M. J. Henchman, Collision mechanism of a dissociative charge-transfer reaction at low energy, J. Chem. Phys. 50, 4112–4114 (1969).
R. S. Lehrle, J. C. Robb, and D. W. Thomas, A modified time-of-flight mass spectrometer for studying ion-molecule or neutral particle-molecule interactions, J. Sci. Instr. 39, 458–463 (1962).
J.B. Homer, R.S. Lehrle, J.C. Robb, and D.W. Thomas, Gas-phase ion-molecule interactions involving atom transfer; limitations of the orbiting theory in accounting for the variation of cross-section with energy, Nature 202, 795–797 (1964).
D. Hyatt and K. Lacmann, Chemical reaction kinematics. VIII. Cross sections of some D-atom transfer reactions in the energy range 1–100 eV, Z. Naturforsch. 23a, 2080–2083 (1968).
E. R. Wiener, G. R. Hertel, and W. S. Koski, Gas phase reactions between carbon tetrachloride and mass analyzed ions of nitrogen between 3 and 200 eV, J. Am. Chem. Soc., 86, 788–793 (1964).
G. R. Hertel and W. S. Koski, Ion-molecule reactions between rare gas ions and methane, J. Am. Chem. Soc. 87, 1686–1691 (1965).
M. A. Berta, B. Y. Ellis, and W. S. Koski, Reaction of HD+ with rare gases, J. Chem. Phys. 44, 4612–4615 (1966).
Z. Herman, J. Kerstetter, T. Rose, and R. Wolfgang, Crossed-beam studies of ion-molecule reaction mechanisms, Disc. Faraday Soc. 44, 123–136 (1967).
V. Čermák and Z. Herman, Molecular dissociation in charge-transfer reactions, Nucleonics 19(9), 106–114 (1961).
A. J. Masson, P. F. Fennelly, and M. J. Henchman, in “Advances in Mass Spectrometry,” Vol. 5, pp. 207–212, Institute of Petroleum, London (1971).
R. L. Wolfgang, private communication.
L. Friedman, in “Annual Review of Physical Chemistry” (H.L. Eyring, ed.), Vol. 19, pp. 273–300, Annual Reviews, Palo Alto, Calif. (1968).
W. R. Gentry, E. A. Gislason, B. H. Mahan, and C. W. Tsao, Dynamics of the reaction of N2 + with H2, D2, and HD, J. Chem. Phys. 49, 3058–3070 (1968);
E. A. Gislason, B.H. Mahan, C. W. Tsao, and A.S. Werner, Dynamics of the reactions of N2 + with CH4 and CD4, J. Chem. Phys. 50, 142–150 (1969).
J. F. Paulson, F. Dale, and S. A. Studniarz, Study of ion-neutral reactions with a time-of-flight mass spectrometer, Int. J. Mass Spectrom. Ion Phys. 5, 113–126 (1970).
E. Teloy and D. Gerlich, private communication; D. Gerlich, Diplomarbeit Thesis, University of Freiburg (1971).
W. Paul and H. Steinwedel, Ein neues Massenspektrometer ohne Magnetfeld, Z. Naturforsch. 8a, 448–450 (1953).
C.F. Giese and W.B. Maier II, Dissociative ionization of CO by ion impact, J. Chem. Phys. 39, 197–200 (1963).
B. R. Turner, M. A. Fineman, and R. F. Stebbings, Crossed-beam investigation of N2D+ production in N2 +-D2 collisions, J. Chem. Phys. 42, 4088–4096 (1965).
J. Colwell and M.A. Fineman, Calculation of the total cross section from angular measurements in crossed-beam experiments, J. Chem. Phys. 42, 4097–4100 (1965).
R.H. Neynaber, in “Advances in Atomic and Molecular Physics” (D. R. Bates and I. Estermann, eds.), Vol. 5, pp. 57–108, Academic Press, New York (1969).
V. A. Belyaev, B. G. Brezhnev, and E. M. Erastov, Resonance charge exchange of protons and deuterons at low energies, Soviet Physics—JETP 25, 777–782 (1967).
V.A. Belyaev, B.G. Brezhnev, and E. M. Erastov, Resonant-charge transfer of low-energy carbon and nitrogen ions, Soviet Physics—JETP 27, 924–926 (1968).
R. H. Neynaber, S. M. Trujillo, and E. W. Rothe, Symmetric resonance charge transfer in Ar from 0.1–20 eV using merging beams, Phys. Rev. 157, 101–102 (1967).
R.H. Neynaber and S.M. Trujillo, Study of H2 + + H2 → H3 + + H using merging beams, Phys. Rev. 167, 63–66 (1968) [Erratum: Phys. Rev. 171, 282 (1968)].
P. K. Rol, Low-Energy Interaction Studies by a Merging Beams Technique, Space Science Laboratory, General Dynamics/Convair, Report AFCRL-69–0324 (GDC-DBE69–006) (1970).
P. K. Rol and E. A. Entemann, Low-Energy Interaction Studies by a Merging Beams Technique, Space Science Laboratory, General Dynamics/Convair, Report AFCRL-69--0022 (GDC-DBE69–002) (January 1969).
P.K. Rol and E.A. Entemann, NaO+ production from Na and O2 + in merged beams, J. Chem. Phys. 49, 1430–1431 (1968).
T. W. Shannon, F. Meyer, and A. G. Harrison, A pulsed ion source for the study of uni-molecular and bimolecular reactions of gas-phase ions, Can. J. Chem. 43, 159–174 (1965).
S. K. Gupta, E. G. Jones, A. G. Harrison, and J. J. Myher, Reactions of thermal energy ions. VI. Hydrogen-transfer ion-molecule reactions involving polar molecules, Can. J. Chem. 45, 3107–3117 (1967).
K. Birkinshaw, A.J. Masson, D. Hyatt, L. Matus, I. Opauszky, and M.J. Henchman, in “Advances in Mass Spectrometry” (E. Kendrick, ed.), Vol. 4, pp. 379–390, Institute of Petroleum, London (1968).
M.S.B. Munson, J.L. Franklin, and F.H. Field, A mass spectrometric study of homo-nuclear and heteronuclear rare gas molecule ions, J. Phys. Chem. 67, 1542–1548 (1963).
L.M. Draper, Ph.D. Thesis, University of New South Wales (1964).
V.L. Talrose and A.K. Lyubimova, Secondary processes in a mass spectrometer ion source, Dokl. Akad. Nauk. SSSR 86, 909–912 (1952).
F.H. Field and J.L. Franklin, Reactions of gaseous ions. X. Ionic reactions in xenon-methane mixtures, J. Am. Chem. Soc. 83, 4509–4515 (1961).
M.J. Henchman, Ion-molecule reactions and reactions in crossed molecular beams, Ann. Rep. Chem. Soc. 62, 39–62 (1965).
D. P. Stevenson, in “Mass Spectrometry” (C. A. McDowell, ed.), pp. 589–615, McGraw-Hill, New York (1963).
W.A. Chupka and M.E. Russell, Photoionization study of ion-molecule reactions in mixtures of hydrogen and rare gases, J. Chem. Phys. 49, 5426–5437 (1968).
J. C. Light and J. Lin, Phase-space theory of chemical kinetics.II. Ion-molecule reactions, J. Chem. Phys. 43, 3209–3219 (1965).
K. R. Ryan and J. H. Futrell, Effect of translational energy on ion-molecule reaction rates. II, J. Chem. Phys. 43, 3009–3014 (1965).
K. R. Ryan, J. H. Futrell, and C. D. Miller, Method for studying low energy ion-molecule reactions using monoenergetic ions, Rev. Sci. Instr. 37, 107–110 (1966).
J.H. Futrell and T.O. Tiernan, in “Fundamental Processes in Radiation Chemistry,” (P.J. Ausloos, ed.), pp. 171–280, Interscience, New York (1968).
D.J. Hyatt, E.A. Dodman, and M.J. Henchman, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P.J. Ausloos, ed.), pp. 131–149, American Chemical Society, Washington, D. C. (1966).
R. A. Challinor and R. A. Duncan, The effects of thermal energy and ion-removal time on the “pulsed source” method for mass spectrometer investigations of ion-molecule reactions, Austr. J. Phys. 20, 633–642 (1967).
K. R. Ryan, Ionic collision processes in gaseous nitrogen, J. Chem. Phys. 51, 570–576 (1969).
J.S. Dahler, J.L. Franklin, M.S.B. Munson, and F.H. Field, Rare-gas molecule-ion formation by mass spectrometry. Kinetics of Ar2 +, Ne2 +, and He2 + formation by second- and third-order processes, J. Chem. Phys. 36, 3332–3344 (1962).
F.W. Lampe, J.L. Franklin, and F.H. Field, in “Progress in Reactions Kinetics” (G. Porter, ed.), Vol. 1. pp. 67–103, Pergamon Press, New York (1961).
G.G. Meisels and H.F. Tibbals, Higher order ion-molecule reactions, Part I. Theoretical basis, J. Phys. Chem. 72, 3746–3753 (1968).
I. Szabo, Theoretical analysis of consecutive ion-molecule reactions. I. The mechanisms in a tandem mass spectrometer of perpendicular type. II. The mechanisms in a tandem mass spectrometer of longitudinal type, Int. J. Mass Spectrom. Ion Phys. 3, 103–129, 169–188 (1969).
P. Warneck, Studies of ion-neutral reactions by a photoionization mass-spectrometer technique. II. Charge-transfer reactions of argon ions at near-thermal energies, J. Chem. Phys. 46, 513–519 (1967).
C.J. Ogle, Ph.D. Thesis, University of Leeds, 1968; M.J. Henchman and C.J. Ogle, unpublished work.
J. F. Paulson, Low energy charge exchange and ion-molecule reactions, Ann. Geophys. 20,75–87 (1964).
A. G. Harrison, J. J. Myher, and J. C. J. Thynne, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P. J. Ausloos, ed.), pp. 150–166, American Chemical Society, Washington, D.C. (1966).
A.A. Herod, A.G. Harrison, R.M. O’Malley, A.T. Ferrer-Correia, and K. R. Jennings, A comparison of the zero-field pulsing technique and the ICR technique for studying ion-molecule reactions, J. Phys. Chem. 74, 2720–2722 (1970).
J. Bracher, H. Ehrhardt, R. Fuchs, O. Osberghaus, and R. Taubert, in “Advances in Mass Spectrometry” (R.M. Elliott, ed.), Vol. 2, pp. 285–295, Pergamon Press, Oxford (1963).
T.H. McGee and M.J. Henchman, unpublished work.
G.V. Karachevtsev, M.I. Markin, and V.L. Talrose, Mass-spectrometric impulse method of investigating elementary processes of charge exchange of thermal ions in molecules, Kinetics Catalysis 5, 331–339 (1964).
B.G. Reuben, A. Lifshitz, and C. Lifshitz, Calculations of rate constants for ion-molecule reactions in a pulsed-source mass spectrometer, Int. J. Mass Spectrom. Ion Phys. 2, 385–390 (1969).
D. A. Durden, P. Kebarle, and A. Good, Thermal ion-molecule reaction rate constants at pressures up to 10 Torr with a pulsed mass spectrometer. Reactions in methane, krypton, and oxygen, J. Chem. Phys. 50, 805–813 (1969).
T. H. McGee, P. F. Fennelly, and M.J. Henchman, in “Abstracts of Papers, Sixth International Conference on the Physics of Electronic and Atomic Collisions” (I. Amdur, ed.), pp. 321–324, M.I.T. Press, Cambridge (1969).
R. Johnsen, H.L. Brown, and M.A. Biondi, Ion-molecule reactions involving N2 +, N+, O2 +, and O+ ions from 300°K to ~ 1 eV, J. Chem. Phys. 52, 5080–5084 (1970).
J.T. Moseley, R.M. Snuggs, D.W. Martin, and E.W. McDaniel, Mobilities, diffusion coefficients, and reaction rates of mass-identified nitrogen ions in nitrogen, Phys. Rev. 178, 240–248 (1969).
M.T. Bowers, D. D. Elleman, and J. L. Beauchamp, Ion cyclotron resonance of olefins. I. A study of the ion-molecule reactions in electron-impacted ethylene, J. Phys. Chem. 72, 3599–3612 (1968).
S. E. Buttrill, Jr., Measurement of ion-molecule reaction rate constants using ion cyclotron resonance, J. Chem. Phys. 50, 4125–4132 (1969).
R. P. Clow and J. H. Futrell, Ion-cyclotron resonance study of the kinetic energy dependence of ion-molecule reaction rates. I. Methane, hydrogen, and rare gas-hydrogen systems, Int. J. Mass Spectrom. Ion Phys. 4, 165–179 (1970).
J. L. Beauchamp and S. E. Buttrill Jr., Proton affinities of H2S and H2O, J. Chem. Phys. 48, 1783–1789 (1968).
L. R. Anders, Study of the energetics of ion-molecule reactions by pulsed ion cyclotron double resonance, J. Phys. Chem. 73, 469–470 (1969).
R. C. Dunbar, Energy dependence of methanol proton transfer reaction rate, J. Chem. Phys. 52, 2780–2781 (1970).
D. Wobschall, R. A. Fluegge, and J. R. Graham, Jr., Collision cross sections of hydrogen and other ions as determined by ion cyclotron resonance, J. Chem. Phys. 47, 4091–4094 (1967).
J. L. Beauchamp, Theory of collision-broadened ion cyclotron resonance spectra, J. Chem. Phys. 46, 1231–1243 (1967).
J.L. Beauchamp and J.T. Armstrong, An ion ejection technique for the study of ion-molecule reactions with ion cyclotron resonance spectroscopy, Rev. Sci. Instr. 40, 123–128 (1969).
J.H. Futrell, private communication.
M.T. Bowers and D.D. Elleman, Kinetic analysis of the concurrent ion-molecule reactions in mixtures of argon and nitrogen with H2, D2, and HD utilizing ion-ejection-ion-cyclotron-resonance techniques, J. Chem. Phys. 51, 4606–4617 (1969).
J. King Jr., and D. D. Elleman, Charge-exchange reactions in xenon-methane mixtures, J. Chem. Phys. 48, 4803–4804 (1968).
R. P. Clow and J. H. Futrell, Observation of charge exchange in xenon-methane mixtures by ion-cyclotron double resonance, J. Chem. Phys. 50, 5041–5042 (1969).
A. G. Marshall and S. E. Buttrill Jr., Calculation of ion-molecule reaction rate constants from ion cyclotron resonance spectra: methyl fluoride, J. Chem. Phys. 52, 2752–2759 (1970).
M.T. Bowers, D.D. Elleman, and J. King Jr., Kinetic analysis of the ion-molecule reactions in nitrogen-hydrogen mixtures using ion cyclotron resonance, J. Chem. Phys. 50, 1840–1845 (1969).
W.L. Fite, in “Methods of Experimental Physics” (B. Bederson and W.L. Fite, eds.), Vol. 7B, pp. 124–139, Academic Press, New York (1968).
W.L. Fite, Positive ion reactions, Can. J. Chem. 47, 1797–1807 (1969).
W. C. Lineberger and L. J. Puckett, Positive ions in nitric oxide afterglows, Phys. Rev. 186, 116–127 (1969).
W.C. Lineberger and L.J. Puckett, Hydrated positive ions in nitric-oxide-water afterglows, Phys. Rev. 187, 286–291 (1969).
L.J. Puckett and W.C. Lineberger, Negative-ion reactions in NO-H2O mixtures, Phys. Rev. A 1, 1635–1641 (1970).
N.G. Adams, D. K. Bohme, D. B. Dunkin, and F.C. Fehsenfeld, Temperature dependences of the rate coefficients for the reactions of Ar+ with O2, H2, and D2, J. Chem. Phys. 52, 1951–1955 (1970).
F.C. Fehsenfeld, A.L. Schmeltekopf, D.B. Dunkin, and E.E. Ferguson, Compilation of Reaction Rate Constants Measured in the ESSA Flowing Afterglow System to August 1969, ESSA Technical Report ERL 135-AL 3 (September 1969).
H. I. Schiff, A. E. Roche, F. C. Fehsenfeld, and D. K. Bohme, in “Abstracts of Papers, Seventh International Conference on the Physics of Electronic and Atomic Collisions” (L. Branscomb, ed.), pp. 984–986, North-Holland, Amsterdam (1971).
D. K. Bohme and L. B. Young, Gas-phase reactions of oxide radical ion and hydroxide ion with simple olefins and of carbanions with oxygen, J. Am. Chem. Soc. 92, 3301–3309 (1970).
R. C. Bolden, R. S. Hemsworth, M. J. Shaw, and N. D. Twiddy, Measurement of thermal-energy ion-neutral reaction rate coefficients for rare-gas ions, J. Phys. B. 3, 45–60 (1970).
A.L. Farragher, Ion-molecule reaction rate studies in a flowing afterglow system, Trans. Faraday Soc. 66, 1411–1422 (1970).
R.C. Bolden, R.S. Hemsworth, M.J. Shaw, and N.D. Twiddy, The measurement of penning ionization cross sections for helium 2 3S metastables using a steady-state flowing afterglow method, J. Phys. B. 3, 61–71 (1970).
W.A. Chupka, M.E. Russell, and K. Refaey, Ion-molecule and chemi-ionization reactions in H2 by photoionization, J. Chem. Phys. 48, 1518–1527 (1968).
N. Sbar and J. Dubrin, Study of the rotational kinetic energy dependence of the reaction cross section: Ar+ + H2 → ArH+ + H, J. Chem. Phys. 53, 842–843 (1970).
F.C. Fehsenfeld, D.L. Albritton, J.A. Burt and H.I. Schiff, Associative-detachment reactions of CT and O2 - by O2(1Δ g ), Can. J. Chem. 47, 1793–1795 (1969).
M. J. Henchman, D. Hyatt, and L. Matus, in “Proceedings of the XIV Colloquium Spec-troscopicum Internationale,” pp. 1535–1539, Adam Hilger, London (1967).
L. Matus, D.J. Hyatt, and M.J. Henchman, Collision mechanisms of ion-molecule reactions at energies of 1 eV, J. Chem. Phys. 46, 2439–2440 (1967).
C.W. Hand and H. von Weyssenhoff, Ion-molecule reactions studied by time-of-flight mass spectrometry. II. Reactions in CO-D2 and CH4-D2 mixtures, Can. J. Chem. 42, 2385–2392 (1964).
J.L. Franklin, Y. Wada, P. Natalis, and P.M. Hierl, Ion-molecule reactions in acetonitrile and propionitrile, J. Phys. Chem. 70, 2353–2361 (1966).
K. Birkinshaw, Ph.D. Thesis, University of Leeds (1968); K. Birkinshaw and M.J. Henchman, unpublished results.
R.A. Fluegge, Ion-molecule reactions in alpha-particle-irradiated methane and water vapor, J. Chem. Phys. 50, 4373–4380 (1969).
C. Lifshitz and B.G. Reuben, Ion-molecule reactions in aromatic systems. I. Secondary ions and reaction rates in benzene, J. Chem. Phys. 50, 951–960 (1969).
M. Inoue and S. Wexler, Isotopic exchange in CH4-D2 and CD4-H2 mixtures studied by ion cyclotron resonance spectroscopy. The mechanism of self-induced labeling of methane by tritium, J. Am. Chem. Soc. 91, 5730–5740 (1969).
D. Holtz, J. L. Beauchamp, and J. R. Eyler, Acidity, basicity and ion-molecule reactions of phosphine in the gas phase by ion cyclotron resonance spectroscopy, J. Am. Chem. Soc. 92, 7045–7055 (1970).
K. R. Ryan, Ionic collision processes in water vapor, J. Chem. Phys. 52, 6009–6016 (1970).
F. H. Field, J. L. Franklin, and F. W. Lampe, Reactions of gaseous ions. I. Methane and ethylene, J. Am. Chem. Soc. 79, 2419–2429 (1957).
T. W. Martin and C. E. Melton, Hydrogen atom abstraction reactions by cyanide ion-radicals, J. Chem. Phys. 32, 700–704 (1960).
A. Giardini-Guidoni and L. Friedman, Energy transfer in ion-molecule reactions in the methane system, J. Chem. Phys. 45, 937–943 (1966).
W. Poschenrieder and P. Warneck, Gas analysis by photo-ionization mass spectrometry, J. Appl. Phys. 37, 2812–2820 (1966).
J. H. Futrell, T. O. Tiernan, F. P. Abramson, and C. D. Miller, Modification of a time-of-flight mass spectrometer for investigation of ion-molecule reactions at elevated pressures, Rev. Sci. Instr. 39, 340–345 (1968).
S. Wexler and N. Jesse, Consecutive ion-molecule reactions in methane, J. Am. Chem. Soc. 84, 3425–3432 (1962).
F.H. Field, J.L. Franklin, and M.S.B. Munson, Reactions of gaseous ions. XII. High pressure mass spectrometric study of methane, J. Am. Chem. Soc. 85, 3575–3583 (1963).
G.A.W. Derwish, A. Galli, A. Giardini-Guidoni, and G.G. Volpi, Ion-molecule reactions in methane and in ethane, J. Chem. Phys. 40, 5–12 (1964).
S. Wexler, A. Lifshitz, and A. Quattrochi, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P.J. Ausloos, ed.), pp. 193–209, American Chemical Society, Washington, D.C. (1966).
S.O. Colgate and T.W. Schmidt, Energy-dependence measurement of the CH4 + + CH4 = CH3 + CH5 + reaction cross section, J. Chem. Phys. 45, 367–369 (1966).
F. P. Abramson and J. H. Futrell, On the reaction of CH4 + with CD4, J. Chem. Phys. 46, 3264–3266 (1967).
C.E. Melton and W.H. Hamill, Appearance potentials by the retarding potential-difference method for secondary ions produced by excited-neutral, excited ion-neutral, and ion-neutral reactions, J. Chem. Phys. 41, 1469–1474 (1964).
W. A. Chupka and J. Berkowitz, Photoionization of methane: ionization potential and proton affinity of CH4, J. Chem. Phys. 54, 4256–4259 (1971).
H. Gutbier, Massenspecktrometrische Untersuchung der reaktion X+ + H2 → HX+ + H, Z. Naturforsch. 12a, 499–507 (1957).
G. Gioumousis and D.P. Stevenson, Reactions of gaseous molecule ions with gaseous molecules. V. Theory, J. Chem. Phys. 29, 294–299 (1958).
Z. Herman and V. Čermák, Mass spectrometric investigation of the reactions of ions and excited neutral particles in mixtures containing mercury vapour, Collection Czech. Chem. Commun. 28, 799–807 (1963).
J. H. Green and D. M. Pinkerton, Hydride ion transfer and radiolysis reactions in pentane and isopentane, J. Phys. Chem. 68, 1107–1111 (1964).
V. Aquilanti, A. Galli, A. Giardini-Guidoni, and G.G. Volpi, Ion-molecule reactions in hydrogen-rare-gas mixtures, J. Chem. Phys. 43, 1969–1973 (1965).
J. Sayers and D. Smith, Ion and charge exchange reactions involving atmospheric gases, Disc. Faraday Soc. 37, 167–175 (1964).
D.B. Dunkin, F.C. Fehsenfeld, A.L. Schmeltekopf, and E.E. Ferguson, Ion-molecule reaction studies from 300° to 600°K in a temperature-controlled flowing afterglow system, J. Chem. Phys. 49, 1365–1371 (1968).
W.B. Maier II, Reactions of He+ with N2 and O2 in the upper atmosphere, Planetary Space Sci. 16, 477–493 (1968).
B. Ziegler, Der Wirkungsquerschnitt sehr langsamer ionen, Z. Physik 136, 108–118 (1953).
W. H. Cramer, Elastic and ineleastic scattering of low-velocity ions: Ne+ in A, A+ in Ne, and A+ in A, J. Chem. Phys. 30, 641–642 (1959).
B. J. Nichols and F. C. Witteborn, Measurements of Resonant Charge Exchange Cross Sections in Nitrogen and Argon between 0.5 and 17 eV, NASA Technical Note NASA TN D-3265 (February 1966).
P. Mahadevan and G. D. Magnuson, Low-energy (1- to 100-eV) charge-transfer cross-section measurements for noble-gas-ion collisions with gases, Phys. Rev. 171, 103–109 (1968)
I. Popescu Iovitsu and N. Ionescu-Pallas, Resonant charge-exchange and the kinetics of ions, Soviet Phys.-Tech. Phys. 4, 781–791 (1960).
D. Rapp and W. E. Francis, Charge exchange between gaseous ions and atoms, J. Chem. Phys. 37, 2631–2645 (1962).
R. M. Snuggs, D. J. Volz, I. R. Gatland, J. H. Schummers, D. W. Martin, and E. W. McDaniel, Ion-molecule reactions between O- and O2 at thermal energies and above, Phys. Rev. A 3, 487–493 (1971).
B. G. Reuben and L. Friedman, Isotopic hydrogen-ion-molecule reactions, J. Chem. Phys. 37, 1636–1642 (1962).
J. J. Leventhal and L. Friedman, Diatomic-ion-molecule reactions: N2 +-N2, CO+ — CO, and O2 + — O2, J. Chem. Phys. 46, 997–1005 (1967).
W.B. Maier II. Is N3 produced in reactions between N2 + and N2?, J. Chem. Phys. 47, 859–860 (1967).
S. E. Buttrill, Jr., Calculation of ion-molecule reaction product distributions using the quasiequilibrium theory of mass spectra, J. Chem. Phys. 52, 6174–6183 (1970).
J. C. Light, Statistical theory of bimolecular exchange reactions, Disc. Faraday Soc. 44, 14–29 (1967).
D. K. Bohme, J. B. Hasted, and P. P. Ong, Calculation of interchange reaction rates by a “nearest resonance” method, J. Phys. B 1, 879–892 (1968).
J. J. Kaufman and W. S. Koski, Theoretical justification of the apparently anomalous low-energy behavior of some ion-molecule reactions, J. Chem. Phys. 50, 1942–1945 (1969).
T. F. O’Malley, Simple model for high energy reaction of O+ ions with N2, J. Chem. Phys. 52, 3269–3277 (1970).
E. E. Nikitin, in “Chemische Elementarprozesse” (H. Hartmann, ed.), pp. 43–77, Springer-Verlag, Berlin (1968).
J. C. Light and J. Horrocks, Molecular rearrangement collisions at high impact energies, Proc. Phys. Soc. 84, 527–530 (1964).
A. Henglein, in “Molecular Beams and Reaction Kinetics” (Ch. Schlier, ed.), pp. 139–183, Academic Press, New York (1970).
D. R. Bates, C. J. Cook, and F. J. Smith, Classical theory of ion-molecule rearrangement collisions at high impact energies, Proc. Phys. Soc. 83, 49–57 (1964).
G. K. Ivanov and Yu. S. Sayasov, The theory of direct atom-molecule reactions, Part I, Theor. Exp. Chem. 3, 95–101 (1967).
V.L. Talrose, Ion-molecular reactions in gases, Pure Appl. Chem. 5, 455–486 (1962).
V. L. Talrose and G. V. Karachevtsev, in “Advances in Mass Spectrometry” (W. L. Mead, ed.), Vol. 3, pp. 211–233, Institute of Petroleum, London (1966).
A. Henglein, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P.J. Ausloos, ed.), pp. 63–79, American Chemical Society, Washington, D.C. (1966).
J. H. Futrell and F. P. Abramson, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P. J. Ausloos, ed.), pp. 107–130, American Chemical Society, Washington, D. C. (1966).
F. A. Wolf and B. R. Turner, Energy dependence of charge-transfer reactions in the thermal and low-electron-volt region, J. Chem. Phys. 48, 4226–4233 (1968).
R. W. Rozett and W. S. Koski, Helium ion-hydrogen reactions, J. Chem. Phys. 48, 533–534 (1968).
J. J. Leventhal, T. F. Moran, and L. Friedman, Molecular resonant charge-transfer proccesses; H2 + — H2 and N2 + — N2, J. Chem. Phys. 46, 4666–4672 (1967).
J.C. Light and S. Chan, Isotopic distributions in exothermic ion-molecule reactions. A simple model, J. Chem. Phys. 51, 1008–1015 (1969).
A. Ding, A. Henglein, and K. Lacmann, Chemische reaktionskinematik. VI. Komplex- und stripping-mechanismus der reaktion CD4 + + CD4 → CD5 + + CD3, Z. Naturforsch. 23a, 779–780 (1968).
E. Vogt and G. H. Wannier, Scattering of ions by polarization forces, Phys. Rev. 95, 1190–1198 (1954).
J. V. Dugan Jr. and J. L. Magee, Capture collisions between ions and polar molecules, J. Chem. Phys. 47, 3103–3112 (1967).
E. W. McDaniel, “Collision Phenomena in Ionized Gases,” John Wiley and Sons, New York (1964).
J. V. Dugan Jr., J. H. Rice, and J. L. Magee, On the nature of ion-molecule collisions, Chem. Phys. Letters 2, 219–222 (1968).
R.C.C. Lao, R.W. Rozett, and W.S. Koski, Ion-molecule reactions of C+ with N2 and O2, J. Chem. Phys. 49, 4202–4209 (1968).
G. R. North and J. J. Leventhal, Two-channel model for electron transfer in ion-molecule collisions, J. Chem. Phys. 51, 4236–4237 (1969).
N. Boelrijk and W. H. Hamill, Effects of relative velocity upon gaseous ion-molecule reactions; charge transfer to the neopentane molecule, J. Am. Chem. Soc. 84, 730–742 (1962).
A. MacKenzie Peers, The hard-sphere correction for ion-molecule collisions, Int. J. Mass. Spectrom. Ion Phys. 3, 99–102 (1969).
A. Jacobson, T. H. McGee, and M. J. Henchman, unpublished results.
J.L. Franklin, J.G. Dillard, H.M. Rosenstock, J.T. Herron, K. Draxl, and F.H. Field, “Ionization Potentials, Appearance Potentials, and Heats of Formation of Gaseous Positive Ions,” Nat. Stand. Ref. Data Ser., Nat. Bur. Stand (U.S.) Vol. 26, U.S. Dept. of Commerce (1969).
I. G. Csizmadia, R. E. Kari, J. C. Polanyi, A. C. Roach, and M. A. Robb, Ab initio SCF-MO-CI calculations for H-, H2, and H3 + using Gaussian basis sets, J. Chem. Phys. 52, 6205–6211 (1970).
J. D. Payzant and P. Kebarle, Clustering equilibrium N2 + + 2N2 = N4 + + N2 and the bond dissociation energy of N4 +, J. Chem. Phys. 53, 4723–4724 (1970).
F. H. Field and D. P. Beggs, Reversible reactions of gaseous ions. III. Studies with methane at 0.1–1.0 Torr and 77–300°K, J. Am. Chem. Soc. 93, 1585–1591 (1971).
W.A. Lester, Jr., Interaction potential between Li+ and H2. I. Region appropriate for rotational excitation, J. Chem. Phys. 53, 1511–1515 (1970).
T. L. Gilbert and A. C. Wahl, Single-configuration wave functions and potential curves for low-lying states of He2 +, Ne2 +, Ar2 +, F2 -, Cl2 - and the ground states of Cl2, J. Chem. Phys. 55, 5247–5261 (1971).
M. Krauss, Compendium of ab initio Calculations of Molecular Energies and Properties, NBS Technical Note 438, U. S. Dept. of Commerce (December 1967).
C. F. Giese, in “Advances in Mass Spectrometry” (W. L. Mead, ed.), Vol. 3, pp. 321–330, Institute of Petroleum, London (1966).
J. B. Hasted, in “Advances in Atomic and Molecular Physics” (D. R. Bates and I. Estermann, ed.), Vol. 4, pp. 237–266, Academic Press, New York (1968).
E. F. Greene and J. Ross, Molecular beams and a chemical reaction, Science 159, 587–595 (1968).
G. H. Dunn, Franck-Condon factors for the ionization of H2 and D2, J. Chem. Phys. 44, 2592–2594 (1966).
D.P. Ridge and J.L. Beauchamp, Analysis of collision-broadened ion cyclotron resonance lineshapes: ions in methane. Cited in Ref. (321).
R. C. Dunbar, Energy dependence of ion-molecule reactions, J. Chem. Phys. 47, 5445–5446 (1967).
E. E. Ferguson, in “Advances in Electronics and Electron Physics” (L. Marton, ed.), Vol. 24, pp. 1–50, Academic Press, New York (1968).
C. Lifshitz and R. Grajower, Electron transfer reactions between polyatomic negative molecule-ions and neutral molecules at thermal energies, Int. J. Mass Spectrom. Ion Phys. 3, App. 5–8 (1969).
H. M. Rosenstock, C. R. Mueller, M. B. Wallenstein, M. L. Vestal, A. Tory, D. Rivers, and W. H. Johnston, Ion-Molecule Reactions, Report # JLI-650–3–7, U. S. Dept. of Commerce (October 1959).
D. R. Herschbach, unpublished results.
C. F. Giese, in “Ion-Molecule Reactions in the Gas Phase” (Advances in Chemistry Series, No. 58, P. J. Ausloos, ed.), pp. 20–27, American Chemical Society, Washington, D. C. (1966).
C. F. Giese, in “Advances in Chemical Physics” (J. Ross, ed.), Vol. 10, pp. 247–273, Interscience, New York (1966).
J. Schaefer and J. M. S. Henis, Electron density rearrangement description of ion-molecule reactions, J. Chem. Phys. 49, 5377–5381 (1968).
A. L. Schmeltekopf, F. C. Fehsenfeld, and E. E. Ferguson, Laboratory measurement of the rate constant for H- + H → H2 + e, Astrophys. J. 148, L155-L156 (1967).
D. Hyatt and L. Stanton, Application of a multipole potential in a theoretical investigation of collision cross-sections for ions with linear molecules, Proc. Roy. Soc. Lond. A 318, 107–118 (1970). [Errata: Chem. Phys. Letters 10, 12 (1971)].
A. M. Arthurs and A. Dalgarno. The mobilities of ions in molecular gases, Proc. Roy. Soc. Lond. A 256, 552–558 (1960).
J. V. Dugan Jr., and J. L. Magee, in “Advances in Chemical Physics” (J. O. Hirschfelder and D. Henderson, eds.), Vol. 21, pp. 207–235, Interscience, New York (1971).
D. P. Beggs and F. H. Field, Reversible reactions of gaseous ions. I. Methane-water system, J. Am. Chem. Soc. 93, 1567–1575 (1971).
J. H. Futrell, M. J. Henchman, D. Hyatt, and T. H. McGee, to be published.
J. V. Dugan Jr. and R. B. Canright Jr., A preliminary study of vibrational effects in ion-dipole collisions: “classical tunneling,” Chem. Phys. Letters 8, 253–258 (1971).
K. R. Ryan, Ionic collision processes in gaseous ammonia, J. Chem. Phys. 53, 3844–3848 (1970).
J. V. Dugan, Jr., Comparison of numerical capture cross sections with experimental reaction cross sections for NH3 + + NH3, Chem. Phys. Letters 8, 198–200 (1971).
L. J. Leger and G. G. Meisels, Preferred dipole orientation in ion-polar molecule reactions, Chem. Phys. Letters 1, 661–664 (1968).
L. J. Leger and G. G. Meiseis, Ion-polar-molecule reactions: energy dependency of hydrogen atom and ion transfer in the methanol-acetaldehyde system, J. Chem. Phys. 52, 4319–4324 (1970).
W.B. Maier II, Reactions between H+ and D2, J. Chem. Phys. 54, 2732–2739 (1971).
J. Krenos and R. Wolfgang, “Simplest” chemical reactions: exchange in the H3 + system, J. Chem. Phys. 52, 5961–5962 (1970).
T. F. George and R. J. Suplinskas, Kinematic model for reaction. III. Detailed dynamics of the reaction of Ar+ with D2, J. Chem. Phys. 54, 1037–1045 (1971).
T. F. George and R. J. Suplinskas, Kinematic model for reaction. IV. Orientation and isotope effect in the Ar+ + HD reaction, J. Chem. Phys. 54, 1046–1049 (1971).
A. E. Roche, M. M. Sutton, D. K. Bohme, and H. I. Schiff, Determination of proton affinity from the kinetics of proton transfer reactions. I. Relative proton affinities, J. Chem. Phys. 55, 5480–5484 (1971).
H.-U. Mittmann, H.-P. Weise, A. Ding, and A. Henglein, Streuung von Ionen. I. Regenbogeneffekt bei der elastischen Streuung von Protonen an Argon, Z. Naturforsch. 26a, 1112–1121 (1971).
A. C. Roach and P. Kuntz, The potential curve of ArH+ and the heats of the reactions Ar+ + H2 → ArH+ + H and Ar + H2 + → ArH+ + H, Chem. Comm. 1336–1337 (1970).
T. F. Moran and L. Friedman, Application of the Piatt electrostatic model to diatomic hydride ions, J. Chem. Phys. 40, 860–866 (1964).
E. E. Nikitin, Present-day state of the theory of bimolecular reactions, Russ. Chem. Rev. 38, 505–512 (1969).
M. Vestal, in “Fundamental Processes in Radiation Chemistry” (P. J. Ausloos, ed.), pp. 59–118, Interscience, New York (1968).
M. H. Chiang, E. A. Gislason, B. H. Mahan, C. W. Tsao, and A. S. Werner, Dynamics of the reactions of O2 + with H2 and D2, J. Phys. Chem. 75, 1426–1437 (1971).
A. S. Werner, Ph.D. Thesis, University of California at Berkeley (1971); Lawrence Radiation Laboratory Report UCRL-20363 (April 1971).
Z. Herman, A. Lee, and R. Wolfgang, Crossed-beam studies of energy dependence of intermediate complex formation in an ion-molecule reaction, J. Chem. Phys. 51, 452–454 (1969);
R. Wolfgang, Energy and chemical reaction. I. Dynamics of simple ionic and atomic processes, Accounts Chem. Res. 2, 248–256 (1969).
W. A. Chupka and M. Kaminsky, Energy distribution and fragmentation processes resulting from electron impact on propane and n-butane, J. Chem. Phys. 35, 1991–1998 (1961).
F. P. Abramson and J. H. Futrell, Ion-molecule reactions of methane, J. Chem. Phys. 45, 1925–1931 (1966).
H. von Koch, Dissociation of ethane molecule ions formed in charge exchange collisions with positive ions. Ion-molecule reactions of ethane, Arkiv Fysik 28, 559–574 (1965).
E. V. Waage and B. S. Rabinovitch, Centrifugal effects in reaction rate theory, Chem. Rev. 70. 377–387 (1970).
J. L. Franklin and M. A. Haney, Translational energies of products of exothermic ion-molecule reactions, J. Phys. Chem. 73, 2857–2863 (1969).
D.K. Bohme, D.B. Dunkin, F.C. Fehsenfeld, and E.E. Ferguson, Flowing afterglow studies of ion-molecule association reactions, J. Chem. Phys. 51, 863–872 (1969).
J. M. S. Henis, An ion cyclotron resonance study of ion-molecule reactions in methanol, J. Am. Chem. Soc. 90, 844–851 (1968).
Z. Herman, P. Hierl, A. Lee, and R. Wolfgang, Direct mechanism of reaction CH3 + + CH4 → C2H5 + + H2, J. Chem. Phys. 51, 454–455 (1969).
J. C. Polanyi, Dynamics of chemical reactions, Disc. Faraday Soc. 44, 293–307 (1967).
S. N. Ghoshal, An experimental verification of the theory of compound nucleus, Phys. Rev. 80, 939–942 (1950).
J. N. Butler and G. B. Kistiakowsky, Reactions of methylene. IV. Propylene and cyclopropane, J. Am. Chem. Soc. 82, 759–765 (1960).
R. Wolfgang, Energy and chemical reaction. II. Intermediate complexes vs. direct mechanisms, Acccounts Chem. Res. 3, 48–54 (1970).
P. Pechukas and J. C. Light, On detailed balancing and statistical theories of chemical kinetics, J. Chem. Phys. 42, 3281–3291 (1965).
F. A. Wolf, Computer calculations of ion-molecule reactions, J. Chem. Phys. 44, 1619–1628 (1966).
L. M. Tannenwald, On the rarity of certain ion-molecule reactions, Proc. Phys. Soc. Lond. 87, 109–117 (1966).
E. E. Nikitin, Statistical theory of exothermic ion-molecule reactions, Theor. Exp. Chem. 1, 275–280 (1965).
F. A. Wolf and J. L. Haller, Statistical theory of four-body bimolecular resonant ion-molecule reactions, J. Chem. Phys. 52, 5910–5922 (1970).
R. Wolfgang, Disc. Faraday Soc. 44, 80 (1967).
J. C. Light, Disc. Faraday Soc. 44, 80–81 (1967).
R. D. Levine, Disc. Faraday Soc. 44, 81–82 (1967).
J. C. Tully, Z. Herman, and R. Wolfgang, Crossed-beam study of the reaction N+ + O2, → NO+ + O, J. Chem. Phys. 54, 1730–1737 (1971).
P. M. Hierl, Z. Herman and R. Wolfgang, Chemical accelerator studies of isotope effects on collision dynamics of ion-molecule reactions: elaboration of a model for direct reactions, J. Chem. Phys. 53, 660–673 (1970).
D. L. Albritton, A. L. Schmeltekopf, and E. E. Ferguson, in “Abstracts of Papers, Sixth International Conference on the Physics of Electronic and Atomic Collisions” (I. Amdur, ed.), pp. 331–332, M.I.T. Press, Cambridge (1969).
D. C. Fullerton and T. F. Moran, Application of the statistical phase-space theory to the reactions of rare-gas ions with nitrogen molecules, J. Chem. Phys. 54, 5221–5230 (1971).
T. F. Moran and L. Friedman, Energy transfer in the reaction of He+ with O2, J. Geophys. Res. 70, 4992–4994 (1965).
J. F. Paulson, private communication of unpublished results.
J.J. Leventhal, Collision mechanism leading to the formation of NO+ in O+-N2 collisions, J. Chem. Phys. 54, 5102–5103 (1971).
E. E. Ferguson, F. C. Fehsenfeld, P. D. Goldan, and A. L. Schmeltekopf, and H. I. Schiff, Laboratory measurement of the rate of the reaction N2 + + O → NO+ + N at thermal energy, Plantary Space Sci. 13, 823–827 (1965).
I. Opauszky, K. Birkinshaw, and M. J. Henchman, unpublished results.
J. J. Leventhal, Energetics of HeH+ formed in H2 +-He collisions, J. Chem. Phys. 54, 3279–3282 (1971).
F. S. Klein and L. Friedman, Intramolecular isotope effects in the HD-rare gas ion-molecule reactions, J. Chem. Phys. 41, 1789–1798 (1964).
C. R. Iden, R. Liardon, and W. S. Koski, Complex formation in the reaction C+(D2,D) CD+, J. Chem. Phys. 54, 2757–2758 (1971).
E. E. Nikitin, Statistical theory of endothermic reactions. Part 1. Bimolecular reactions, Theor. Exp. Chem. 1, 83–89 (1965).
L. D. Doverspike and R. L. Champion, Experimental investigations of ion-molecule reactions of D2 + with D2 and H2, J. Chem. Phys. 46, 4718–4725 (1967).
J. Durup and M. Durup, Collisions réactives entre ions et molécules à énergie incidente de 1 à 50 eV. Le système D2 + + D2, J. Chim. Phys. 64, 386–394 (1967).
B. H. Mahan, Molecular orbital correlations and ion-molecule reaction dynamics. J. Chem. Phys. 55, 1436–1446 (1971).
G. Bosse, A. Ding, and A. Henglein, Chemische Reaktionskinematik. XIV. Die Winkel-und Geschwindigkeitsverteilung für die Reaktion O2 + + D2 → O2D+ + D, und der Isotopieeffekt für die Reaktion mit HD, Ber. Bunsenges. Physik. Chem. 75, 413–420 (1971).
R. K. Preston and J. C. Tully, Effects of surface crossing in chemical reactions: the H3 + system, J. Chem. Phys. 54, 4297–4304 (1971).
E. E. Ferguson, D. K. Bohme, F. C. Fehsenfeld, and D. B. Dunkin, Temperature dependence of slow ion-atom interchange reactions, J. Chem. Phys. 50, 5039–5040 (1969).
A. L. Schmeltekopf, F. C. Fehsenfeld, G. I. Gilman, and E. E. Ferguson, Reaction of atomic oxygen ions with vibrationally excited nitrogen molecules, Planetary Space Sci. 15, 401–406 (1967).
P. Stubbe, Temperature dependence of the rate constants for the reactions O+ + O2 → O2 + + O and O+ + N2 → NO+ + N, Planetary Space Sci. 17, 1221–1331 (1969).
J. B. Hasted and L. Moore, in “Abstracts of Papers, Sixth International Conference on the Physics of Electronic and Atomic Collisions” (I. Amdur, ed.), pp. 328–330, M. I. T. Press, Cambridge (1969).
Ju. N. Demkov, in “Atomic Collision Processes” (M. R. C. McDowell, ed.), pp. 831–838, North-Holland Publishing Co., Amsterdam (1964).
K. Birkinshaw and J. B. Hasted, Inelastic collisions between atomic ions and diatomic molecules, J. Phys. B4, 1711–1725 (1971).
R. L. Champion, L. D. Doverspike, and T. L. Bailey, Collision-induced dissociation of D2 + ions by argon and nitrogen, J. Chem. Phys. 45, 4377–4384 (1966).
T. O. Tiernan and R. E. Marcotte, Collision-induced dissociation of NO+ and O2 + at low kinetic energies. Effects of internal ionic excitation, J. Chem. Phys. 53, 2107–2122 (1970).
M. H. Cheng, M. Chiang, E. A. Gislason, B. H. Mahan, C. W. Tsao, and A. S. Werner, Collision induced dissociation of molecular ions, J. Chem. Phys. 52, 5518–5525 (1970).
R. W. Rozett and W. S. Koski, Collision-induced dissociation on HD+ by rare gases, J. Chem. Phys. 49, 2691–2695 (1968).
P. Wilmenius and E. Lindholm, Dissociation of methanol molecule ions formed in charge exchange collisions with positive ions. Ion-molecule reactions of methanol with very slow positive ions, Arkiv Fysik 21, 97–122 (1962).
T. F. Moran and L. Friedman, Cross sections and intramolecular isotope effects in AB-HD ion-molecule reactions, J. Chem. Phys. 42, 2391–2405 (1965).
W. S. Koski, Some ion-molecule reactions of the C+ ion in the gas phase, Record Chem. Progr. (Kresge-Hooker Sci. Lib.) 31, 155–170 (1970).
M. A. Berta and W. S. Koski, The argon-deuterium hydride ion reaction, J. Am. Chem. Soc. 86, 5098–5101 (1964).
R. D. Levine, Quasi-bound states in molecular collisions, Accounts Chem. Res. 3, 273–280 (1970).
G. Heiche and E. A. Mason, Ion mobilities with charge exchange, J. Chem. Phys. 53, 4687–4696 (1970).
J. Krenos, R. Preston, J. Tully and R. Wolfgang, Reaction of hydrogen atomic ions with hydrogen molecules: experiment, ab initio theory, and a conceptual model, Chem. Phys. Letters 10, 17–21 (1971).
G. A. Sinnott, Bibliography of Ion-Molecule Reaction Rate Data, JILA Information Center Report # 9, University of Colorado (August 1969).
A.R. Hochstim (ed.), “Bibliography of Chemical Kinetics and Collision Processes,” IFI/Plenum, New York-Washington (1969).
“Mass Spectrometry Bulletin,” Mass Spectrometry Data Center, AWRE, Aldermaston, Berks, England, Vols. 1–5 (1966–71).
“Bibliography of Atomic and Molecular Processes,” Atomic and Molecular Processes Information Center, Oak Ridge National Laboratory, Tenn. Vols. 1–13 (1963–69).
J. Polanyi, Nonequilibrium processes, Appl. Optics. 10, 1717–1724 (1971).
B. R. Turner, J. A. Rutherford, and D. M. J. Compton, Abundance of excited ions in O+ and O2 + ion beams, J. Chem. Phys. 48, 1602–1608 (1968).
R. F. Mathis, B. R. Turner, and J. A. Rutherford, Abundance of exicted ions in an NO+ ion beam, J. Chem. Phys. 49, 2051–2056 (1968).
J. L. Kinsey, Microscopic reversibility for rates of chemical reactions carried out with partial resolution of the product and reactant states, J. Chem. Phys. 54, 1206–1217 (1971).
J. Dubrin and M. J. Henchman, in “MTP International Review of Science. Physical Chemistry,” Ser. 1, Vol. 9: Reaction Kinetics (J. C. Polanyi, ed.) Chapter 7, Butterworths, London (1972).
M. B. Comisarow, Comprehensive theory for ion cyclotron resonance power absorption: application to line shapes for reactive and nonreactive ions, J. Chem. Phys. 55, 205–217 (1971).
J. L. Beauchamp, in “Annual Reviews of Physical Chemistry” (H. L. Eyring, ed.), Vol. 22, pp. 527–561, Annual Reviews, Palo Alto (1971).
A. Pipano and J. J. Kaufman, in “Abstracts of Papers, Seventh International Conference on the Physics of Electronic and Atomic Collisions” (L. Branscomb, ed.), pp. 966–968, North-Holland, Amsterdam (1971).
R. D. Levine, in “MTP International Review of Science, Physical Chemistry,” Ser. 1, Vol. 1: Theoretical Chemistry (W. Byers Brown, ed.), Chapter 7, Butterworths, London (1972).
M. G. Holliday, J. T. Muckerman, and L. Friedman, Investigation of back-scattering in the D+/H2 reaction system, J. Chem. Phys. 54, 3853–3856 (1971).
S. B. Woo and S. F. Wong, Interpretation of rate constants measured in drift tubes in terms of cross sections, J. Chem. Phys. 55, 3531–3541 (1971).
G. A. Gray, in “Advances in Chemical Physics” (I. Prigogine and S. A. Rice, eds.), Vol. 19, pp. 141–207, Wiley-Interscience, New York (1971).
R. C. Dunbar, Transient ion cyclotron resonance method for studying ion-molecule collision and charge-transfer rates: N2 + and CH4 +, J. Chem. Phys. 54, 711–719 (1971).
R. T. McIver, Jr., A trapped ion analyzer cell for ion cyclotron resonance spectroscopy, Rev. Sci. Instr. 41, 555–558 (1970).
R. T. Mclver, Jr., and M. A. Haney, cited in Ref. 321.
T. B. McMahon and J. L. Beauchamp, Determination of ion-transit times in an ion cyclotron resonance spectrometer, Rev. Sci. Instr. 42, 1632–1638 (1971).
W. T. Huntress Jr., M. M. Mosesman, and D. D. Elleman, Relative rates and their dependence on kinetic energy for ion-molecule reactions in ammonia, J. Chem. Phys. 54, 843–849 (1971).
A. G. Marshall, Theory for ion cyclotron resonance absorption line shapes, J. Chem. Phys. 55, 1343–1354 (1971).
J. A. Burt, J. L. Dunn, M. J. McEwan, M. M. Sutton, A. E. Roche, and H. I. Schiff, Some ion-molecule reactions of H3 + and the proton affinity of H2, J. Chem. Phys. 52, 6062–6075 (1970).
Y. Kaneko, N. Kobayashi, and I. Kanomata, Low energy ion-neutral reactions. I. 22Ne+ + 20Ne, and Ar+ + N2, J. Phys. Soc. Japan 27, 992–998 (1969); Y. Kaneko, private communication.
R. D. Levine, “Quantum Mechanics of Molecular Rate Processes,” Oxford University Press, London (1969), pp. 252–259.
G. Bosse, A. Ding, and A. Henglein, Chemische Reaktionskinematik. XV. Winkel- und Geschwindingskeitsverteilung des Produkt-Ions der Reaktion Kr+ + D2 → KrD+ + D, Z. Naturforsch. 26a, 932–933 (1971).
P. F. Fennelly, Ph.D. Thesis, Brandeis University (1972); P. F. Fennelly, A. S. Werner, and M. J. Henchman, unpublished results.
B. H. Mahan, private communication.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1972 Plenum Press, New York
About this chapter
Cite this chapter
Henchman, M. (1972). Rate Constants and Cross Sections. In: Franklin, J.L. (eds) Ion-Molecule Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0088-6_5
Download citation
DOI: https://doi.org/10.1007/978-1-4757-0088-6_5
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-0090-9
Online ISBN: 978-1-4757-0088-6
eBook Packages: Springer Book Archive