Skip to main content

Gas Chromatography-Mass Spectrometry in Insect Pheromone Identification: Three Extreme Case Histories

  • Chapter
Chromatography and Isolation of Insect Hormones and Pheromones

Part of the book series: Chromatographic Society Symposium Series ((CSSS))

Summary

Use of modern gas chromatography-mass spectrometry (GC-MS) for the identification of insect pheromones, using a minimum of insect material, is described for three extreme cases: (i) a mosquito oviposition pheromone: a GC-MS peak but no evidence of activity; (ii) the Siiona lineatus aggregation pheromone: no GC-MS peaks in active region; (iii) aphid sex pheromones: GC-MS peaks associated with activity — the ideal situation.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. B. R. Laurence and J. A. Pickett, Erythro-6-acetoxy-5-hexadecanolide, the major component of a mosquito oviposition attractant pheromone, J. Chem. Soc. Chem. Comm., 59–60 (1982).

    Google Scholar 

  2. B. R. Laurence, K. Mori, T. Otsuka, J. A. Pickett and L. J. Wadhams, Absolute configuration of mosquito oviposition attractant pheromone, 6-acetoxy-5-hexadecanolide, J. Chem. Ecol., 643–648 (1985).

    Article  CAS  PubMed  Google Scholar 

  3. M. M. Blight, J. A. Pickett, M. C. Smith and L. J. Wadhams, An aggregation pheromone of Sitona lineatus, Naturwissenschaften, 71:S.480 (1984).

    Article  CAS  Google Scholar 

  4. G. W. Dawson, D. C. Griffiths, N. F. Janes, A. Mudd, J. A. Pickett, L. J. Wadhams and C. M. Woodcock, Identification of an aphid sex pheromone, Nature, 325:614–616 (1987).

    Article  CAS  Google Scholar 

  5. G. W. Dawson, D. C. Griffiths, L. A. Merritt, A. Mudd, J. A. Pickett, L. J. Wadhams and C. M. Woodcock, The sex pheromone of the greenbug, Schizaphis graminum, Entomol. Exp. et Applic., 48:91–93 (1988).

    Article  CAS  Google Scholar 

  6. G. W. Dawson, N. F. Janes, A. Mudd, J. A. Pickett, A. M. Z. Slawin, L. J. Wadhams and D. J. Williams, The aphid sex pheromone, Pure & Applied Chem., 61:555–558 (1989).

    Article  CAS  Google Scholar 

  7. D. W. Bruno and B. R. Laurence, The influence of the apical droplet of Culex egg rafts on oviposition of Culex pipiens Jatigans (Diptera: Culicidae), J. Med. Entomol., 16:300–305 (1979).

    Article  Google Scholar 

  8. P. Powers, P. H. D’Arsey, J. C. Bill and M. J. Wallington, Applications of a new realtime accurate mass facility for organic mass spectrometers, 26th Annual Conference of Mass Spectrometry Allied Topics, St. Louis, Missouri, p 480 (1978).

    Google Scholar 

  9. C. E. Osgood, An oviposition pheromone associated with the egg rafts of Culex tarsalis, J. Econ. Entomol., 64:1038–1041 (1971).

    Article  CAS  PubMed  Google Scholar 

  10. S. Sasaki, H. Abe, Y. Itagaki and K. Nakanishi, Two-step expulsion of aldehydes and ketones in the fragmentation of acyclic α-glycol diesters, Tet. Lett, 25:2357–2361 (1967).

    Article  Google Scholar 

  11. W. A. Otieno, T. O. Onyango, M. M. Pile, B. R. Laurence, G. W. Dawson, L. J. Wadhams and J. A. Pickett, A field trial of the synthetic oviposition pheromone with Culex quinquefasciatus Say (Diptera: Culicidae) in Kenya, Bull Entomol. Res., 78:463–470 (1988).

    Article  CAS  Google Scholar 

  12. S. A. Abou-Donia, L. J. Fish and G. Pattenden, Iridodial from the odoriferous glands of Staphylinus olens (Coleoptera: Staphylinidae), Tet. Lett, 43:4037–4038 (1971).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1990 Plenum Press, New York

About this chapter

Cite this chapter

Pickett, J.A. (1990). Gas Chromatography-Mass Spectrometry in Insect Pheromone Identification: Three Extreme Case Histories. In: McCaffery, A.R., Wilson, I.D. (eds) Chromatography and Isolation of Insect Hormones and Pheromones. Chromatographic Society Symposium Series. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8062-7_29

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-8062-7_29

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4684-8064-1

  • Online ISBN: 978-1-4684-8062-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics