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Surface-Photopolymerization of Maleimides

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Photochemistry of Macromolecules

Abstract

It has been known for some time that butadiene in contact with metallic substrates polymerizes under the influence of ultraviolet light1. Depositions on various substrates from C4H 2,36 , and other diene and vinyl monomers3, and from the perhalogenated monomers C4C16 and C2F 2−44 have been described in some detail. The surface-photopolymerization process has also been extended to the vapors from solid monomers such as pyromellitic diimide and succinimide5. This paper describes surface-deposition of polymeric films from solid maleimide and other imide monomers, with emphasis on the thermally stable films deposited from the vapor of N-phenylmaleimide.

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© 1970 Plenum Press, New York

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Christopher, A., Fritzsche, A.K., Wright, A.N. (1970). Surface-Photopolymerization of Maleimides. In: Reinisch, R.F. (eds) Photochemistry of Macromolecules. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8035-1_10

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  • DOI: https://doi.org/10.1007/978-1-4684-8035-1_10

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8037-5

  • Online ISBN: 978-1-4684-8035-1

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