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Survey of Rate Constants in the N/H/O System

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Combustion Chemistry

Abstract

Current interest in high-temperature N/H/O kinetics stems primarily from the practical importance of combustion-generated emissions of nitrogen oxides (NOx). The recognition of air pollution as a problem of societal concern has prompted a concentrated research effort on the kinetics of NOx formation and decomposition and has led to a considerable expansion in the fundamental data base for rate constants of elementary reactions in the N/H/O system. The objectives of this survey are twofold: (1) to provide critical rate constant evaluations of reactions for which high-temperature data have been recently acquired, with due consideration given to previous evaluations, particularly the widely used survey at Leeds University (Baulch, et al., 1973); and (2) to provide an extensive compilation of N/H/O reactions and rate constants including both nonevaluated and evaluated reactions, that is, reactions for which limited or no rate data are available currently as well as reactions which have undergone critical reviews previously or in this study.

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References

  • Albers, E. A. et al. (1975). 15th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 765–773.

    Google Scholar 

  • Ando, H. & Asaba, T. (1976). Int. J. Chem. Kinet. 8, 259–275.

    Article  CAS  Google Scholar 

  • Balakhnine, V. P, Vandooren, J, & Van Tiggelen, P. J. (1977). Combust. Flame 28, 165–173.

    Article  CAS  Google Scholar 

  • Baulch, D. L, Drysdale, D. D, & Horne, D. G. (1969). Report No. 5, Dept, of Physical Chemistry, The University of Leeds.

    Google Scholar 

  • Baulch, D. L, Drysdale, D. D, & Horne, D. G. (1973). Evaluated Kinetic Data for High Temperature Reactions, Vol. 2, Butterworths, London.

    Google Scholar 

  • Baulch, D. L. et al. (1976). Evaluated Kinetic Data for High Temperature Reactions, Vol. 3, Butterworths, London.

    Google Scholar 

  • Benson, S. W. et al. (1975). Environmental Protection Agency, Washington, D.C. Report No. EPA-600/2-75-019.

    Google Scholar 

  • Benson, S. W. (1981). 18th Int. Symp. Combust, Combustion Institute, Pittsburgh, p. 882.

    Google Scholar 

  • Binkley, J. S. & Melius, C. F. (1982). Paper No. WSS/CI 82-96, Fall Meeting of the Western States Section of the Combustion Institute.

    Google Scholar 

  • Blauwens, J, Smets, B, & Peeters, J. (1977). 16th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 1055–1064.

    Google Scholar 

  • Bowman, C. T. (1971). Combust. Sci. Technol. 3, 37–45.

    Article  CAS  Google Scholar 

  • Bradley, J. N. & Craggs, X. (1975). 15th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 833–842.

    Google Scholar 

  • Camac, M. & Feinberg, R. M. (1967). 11th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 137–145.

    Google Scholar 

  • Campbell, I. M. & Thrush, B. A. (1968). Trans. Faraday Soc. 64, 1265–1274.

    Article  CAS  Google Scholar 

  • Chase, M. W, Jr. et al. (1982). J. Phys. Chem. Ref. Data 11, 695–940.

    Article  CAS  Google Scholar 

  • Clark, T. C, Garnett, S. H, & Kistiakowsky, G. B. (1969). J. Chem. Phys. 51, 2885–91.

    Article  CAS  Google Scholar 

  • Clyne, M. A. A. & McDermid, J. S. (1975). J. Chem. Soc. Faraday Trans. I 71, 2189–2202.

    Article  CAS  Google Scholar 

  • Clyne, M. A. A. & Thrush, B. A. (1961a). Proc. Royal Soc. A. 261, 259–273.

    Article  CAS  Google Scholar 

  • Clyne, M. A. A. & Thrush, B. A. (1961b). Nature 189, 56–57.

    Article  CAS  Google Scholar 

  • Dean, A. M. (1976). Int. J. Chem. Kinet. 8, 459–474.

    Article  CAS  Google Scholar 

  • Dean, A. M. & Steiner, D. C. (1977). J. Chem. Phys. 66, 598–604.

    Article  CAS  Google Scholar 

  • Dean, A. M., Steiner, D. C., & Wang, E. E. (1978). Combust. Flame 32, 73–83.

    Article  CAS  Google Scholar 

  • Dean, A. M., Hardy, J. E., & Lyon, R. K. (1981). Submitted to 15th Int. Symp. on Free Radicals.

    Google Scholar 

  • Dove, J. E. & Nip, W. S. (1974). Can. J. Chem. 52, 1171–1180.

    Article  CAS  Google Scholar 

  • Dove, J. E. & Nip, W. S. (1979). Can. J. Chem. 57, 689–701.

    Article  CAS  Google Scholar 

  • Dove, J. E., Nip, W. S., & Teitelbaum, H. (1975). 15th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 903–916.

    Google Scholar 

  • Duff, R. E. & Davidson, N. (1959). J. Chem. Phys. 31, 1018–1027.

    Article  CAS  Google Scholar 

  • Duxbury, J. & Pratt, N. H. (1975). 15th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 843–855.

    Google Scholar 

  • Endo, H., Glanzer, K, & Troe, J. (1979). J. Phys. Chem. 83, 2083–2090.

    Article  CAS  Google Scholar 

  • Fenimore, C. P. & Jones, G. W. (1962). 8th Int. Symp. Combust., Williams and Wilkins, Baltimore, pp. 127–133.

    Google Scholar 

  • Engleman, V. S. (1976). Environmental Protection Agency, Washington, D. C. Report No. EPA-600/2-76-003.

    Google Scholar 

  • Flower, W. L., Hanson, R. K., & Kruger, C. H. (1975). 15th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 823–832.

    Google Scholar 

  • Flower, W. L., Hanson, R. K., & Kruger, C. H. (1977). Combust. Sci. Technol. 15, 115–128.

    Article  CAS  Google Scholar 

  • Freedman, E. & Daiber, J. W. (1961). J. Chem. Phys. 34, 1271–1278.

    Article  CAS  Google Scholar 

  • Fujii, N. et al (1981). 18th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 873–883.

    Google Scholar 

  • Gehring, V. M. et al (1971). Ber. Bunsenges Phys. Chem. 75, 1287–1294.

    Article  CAS  Google Scholar 

  • Gehring, V. M. et al (1973). 14th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 99–105.

    Google Scholar 

  • Glanzer, K. & Troe, J. (1975). Ber. Bunsenges Phys. Chem. 79, 465–469.

    Article  Google Scholar 

  • Glick, H. S., Klein, J. J., & Squire, W. (1957). J. Chem. Phys. 27, 850–857.

    Article  CAS  Google Scholar 

  • Gordon, S., Mulac, W., & Nangia, P. (1971). J. Phys. Chem. 75, 2087–2093.

    Article  CAS  Google Scholar 

  • Hack, V. W., Hoyermann, K., & Wagner, H. Gg. (1974). Ber Bunsenges Phys. Chem. 78, 386–391.

    CAS  Google Scholar 

  • Hack, V. W. et al (1979). 17th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 505–513.

    Google Scholar 

  • Hancock, G. et al (1975). Chem. Phys. Lett. 33, 168–172.

    Article  CAS  Google Scholar 

  • Hansen, I. et al (1976). Chem. Phys. Lett. 42, 370–372.

    Article  CAS  Google Scholar 

  • Hanson, R. K., Flower, W. L., & Kruger, C. H. (1974). Combust. Sci. Technol. 9, 79–86.

    Article  CAS  Google Scholar 

  • Harris, G. W., Atkinson, R., & Pitts, J. N. (1979). J. Phys. Chem. 83, 2557–2559.

    Article  CAS  Google Scholar 

  • Harris, R. J., Nasralla, M., & Williams, A. (1976). Combust. Sci. Technol. 14, 85–94.

    Article  CAS  Google Scholar 

  • Henrici, M. (1966). Ph.D. thesis, University of Gottingen, Gottingen.

    Google Scholar 

  • Holzrichter, K. (1980). Ph.D. thesis, Gottingen, Germany.

    Google Scholar 

  • Holzrichter, K. & Wagner, H. Gg. (1981). 18th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 769–775.

    Google Scholar 

  • Howard, C. J. (1980). J. Am. Chem. Soc. 102, 6937–6941.

    Article  CAS  Google Scholar 

  • JANAF Thermochemical Tables (1971). D. R. Stull & H. Prophet, Project Directors, Nat. Bur. Stand, Washington, D. C.:NBS37, 2nd Ed.

    Google Scholar 

  • Kaufman, F. & Decker, L. J. (1959). 7th Int. Symp. Combust, Butterworths, London, pp. 57–60.

    Google Scholar 

  • Kaufmann, F. & Kelso, J. (1955). J. Chem. Phys. 23, 1702–1707.

    Article  Google Scholar 

  • Koshi, M. et al. (1975). 15th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 809–822.

    Google Scholar 

  • Koshi, M. et al. (1979). 17th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 553–562.

    Google Scholar 

  • Leonard, P. A, Plee, S. L.,& Mellor, A. M.(1976). Combust. Sci. Technol. 14, 183–193.

    Article  CAS  Google Scholar 

  • Lesclaux, R. et al. (1975). Chem. Phys. Lett. 35, 493–497.

    Article  CAS  Google Scholar 

  • Livesey, J. B, Roberts, A. L, & Williams, A. (1971). Combust. Sci. Technol. 4, 9–15.

    Article  CAS  Google Scholar 

  • Louge, M. Y. & Hanson, R. K. (1981) (unpublished).

    Google Scholar 

  • Lyon, R. K. (1975). U. S. Patent No. 3900554.

    Google Scholar 

  • Lyon, R. K. (1976). Int. J. Chem. Kinet. 8, 315–318.

    Article  CAS  Google Scholar 

  • McCullough, R. W, Kruger, C. H, & Hanson, R. K. (1977). Combust. Sci. Technol. 15, 213–223.

    Article  CAS  Google Scholar 

  • Michel, K. W. (1965). 10th Int. Symp. Combust, Combustion Institute, Pittsburgh, p. 351.

    Google Scholar 

  • Miller, J. A, Branch, M. C, & Kee, R. J. (1981). Combust. Flame 43, 81–98.

    Article  CAS  Google Scholar 

  • Miller, J. A. (1982). Paper No. WSS/CI 82-93, Fall Meeting of the Western States Section of the Combustion Institute.

    Google Scholar 

  • Monat, J. P. (1977). Ph.D. thesis. Stanford University, Stanford, California.

    Google Scholar 

  • Monat, J. P., Hanson, R. K, & Kruger, C. H. (1977). Combust. Sci. Technol. 16, 21–28.

    Article  CAS  Google Scholar 

  • Monat, J. P, Hanson, R. K, & Kruger, C. H. (1979). 17th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 543–552.

    Google Scholar 

  • Morley, C. (1981). 18th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 23–32.

    Google Scholar 

  • Muzio, L. J. & Arand, J. K. (1976). Electric Power Research Inst, Palo Alto, CA. Report No. FP-253.

    Google Scholar 

  • Muzio, L. J, Arand, J. K, & Teixeira, D. P. (1977). 16th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 199–208.

    Google Scholar 

  • Myerson, A. L. (1973). 14th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 219–228.

    Google Scholar 

  • Newhall, H. K. & Shahed, S. M. (1970). 13th Int. Symp. Combust, Combustion Institute, Pittsburgh, pp. 381–389.

    Google Scholar 

  • Niemitz, K. J, Wagner, H. Gg, & Zellner, R. (1981). Z. Phys. Chem. Neue Folge 124, 155–170.

    Article  CAS  Google Scholar 

  • Nip, W. S. (1974). Ph.D. thesis, University of Toronto, Toronto, Canada.

    Google Scholar 

  • Olschewski, H. A, Troe, J, & Wagner, H. Gg. (1966). Ber. Bunsenges Phys. Chem. 70, 450–459.

    CAS  Google Scholar 

  • Perry, R. A., Atkinson, R., & Pitts, J. N. (1976). J. Chem. Phys. 64, 3237–3239.

    Article  CAS  Google Scholar 

  • Peterson, R. C. (1981). Ph.D. thesis. Purdue University, West Lafayette.

    Google Scholar 

  • Phillips, L. F. & Schiff, H. I. (1965). J. Chem. Phys. 42, 3171–3174.

    Article  CAS  Google Scholar 

  • Piper, L. G. (1979). J. Chem. Phys. 70, 3417–3419.

    Article  CAS  Google Scholar 

  • Pouchan, C. & Chaillet, M. (1982). Chem. Phys. Lett. 90, 310–316.

    Article  CAS  Google Scholar 

  • Roose, T. R., Hanson, R. K., & Kruger, C. H. (1980). Proc. 12th Int. Symp. Shock Tubes and Waves, Magnus, Hebrew Univ. Press, Jerusalem, pp. 476–485.

    Google Scholar 

  • Roose, T. R. (1981). Ph.D. thesis. Stanford University, Stanford, California.

    Google Scholar 

  • Roose, T. R., Hanson, R. K., & Kruger, C. H. (1981). 18th Int. Symp. Combust., Combustion Institute, Pittsburgh, pp. 853–862.

    Google Scholar 

  • Roth, P. & Just, T. (1977). Ber. Bunsenges Phys. Chem. 81, 572–577.

    Article  CAS  Google Scholar 

  • Salimian, S. & Hanson, R. K. (1980). Combust. Sci. Technol. 23, 225–230.

    Article  CAS  Google Scholar 

  • Salimian, S., Hanson, R. K., & Kruger, C. H. (1983). Int. J. Chem. Kinet, in press.

    Google Scholar 

  • Seery, D. J. & Zabielski, M. F. (1980). Laser Probes for Combustion Chemistry, American Chem. Society, Washington, D. C., pp. 375–380.

    Book  Google Scholar 

  • Silver, J. A. & Kolb, C. E. (1980). Chem. Phys. Lett. 75, 191–195.

    Article  CAS  Google Scholar 

  • Silver, J. A., Gozewski, C. M., & Kolb, C. E. (1980). Western State Section, The Combustion Inst. Paper No. 80-41, Los Angeles, California.

    Google Scholar 

  • Silver, J. A. (1981). Opt. Eng. 20, 540–545.

    Article  CAS  Google Scholar 

  • Smith, G. P., Crosley, D. R. (1981). 18th Int. Symposium Combust., Combustion Institute, Pittsburgh, pp. 1511–1520.

    Google Scholar 

  • Smith, I. W. M. & Zellner, R. (1975). Int. J. Chem. Kinet., Symp. 1, 341–351.

    Google Scholar 

  • Sulzmann, K. G. P., Kline, J. M., & Penner, S. S. (1980). Proc. 12th Int. Symp. Shock Tubes and Waves, Magnus, Hebrew University Press, Jerusalem, pp. 465–475.

    Google Scholar 

  • Thompson, D., Brown, T. D., & Beer, J. M. (1972). Combust. Flame 19, 69–79.

    Article  CAS  Google Scholar 

  • Troe, J. (1975). Proc. 10th. Int. Symp. Shock Tubes and Waves, Shock Tube Research Society Japan, Kyoto, pp. 29–51.

    Google Scholar 

  • Vetter, K. (1949). Z. Electrochem. 53, 369–376.

    CAS  Google Scholar 

  • Waldman, C. H, Wilson, R. D., & Maloney, K. L. (1974). EPA Report No. EPA-650/2-74-045.

    Google Scholar 

  • Westbrook, C. K. & Dryer, F. L. (1981). 18th Int. Symposium Combust., Combustion Institute, Pittsburgh, pp. 749–767.

    Google Scholar 

  • Westley, F. (1980). Nat. Bureau of Standards, Washington D. C. Report No. NSRDS-NBS 67.

    Google Scholar 

  • Wray, K. L. & Teare, J. D. (1962). J. Chem. Phys. 36, 2582–2596.

    Article  CAS  Google Scholar 

  • Yumura, M. & Asaba, T. (1981). 18th Int. Symposium Combust., Combustion Institute, Pittsburgh, pp. 863–872.

    Google Scholar 

  • Zeldovich, Ya. B. (1946). Acta Physiochim. U.R.S.S. 21, 577–628.

    CAS  Google Scholar 

  • Zellner, R. & Smith, I. W. M. (1974). Chem. Phys. Lett. 26, 72–74.

    Article  CAS  Google Scholar 

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Authors
  1. Ronald K. Hanson
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  2. Siamak Salimian
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Editors and Affiliations

  1. Department of Chemistry, University of Texas at Austin, Austin, Texas, 78712, USA

    William C. Gardiner Jr.

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Hanson, R.K., Salimian, S. (1984). Survey of Rate Constants in the N/H/O System. In: Gardiner, W.C. (eds) Combustion Chemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-0186-8_6

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