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Flavor Chemistry and Odor Thresholds

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Flavor Chemistry

Abstract

Determination of odor thresholds of components in water solution was an early method adopted by many researchers for evaluating the relative contribution of food aroma/flavor components. Some more recent methods determine odor thresholds in air added to GC effluent from flavor volatile separation. Relatively simple methods are available for calculating thresholds in air from thresholds determined in water. Similar methods can be used for calculating oil and oil-water mixture thresholds from water threshold data. The ratio of a component’s concentration in the food to its water odor threshold value has been useful in determining relative aroma/flavor importance for mostly aqueous foods. Small variations in chemical nature and structure can lead to large changes in threshold values. Water threshold values are compared for various acetyl nitrogen heterocyclic compounds, alkylhydroxyfuranones and 4-alkoxyfuranone derivatives. Even the most careful studies can lead to errors in threshold measurements. Some examples are given where threshold determination errors were caused by minor amounts of very low threshold impurities.

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References

  • Acree, T. E.; Barnard, J.; Cunningham, D. G. A procedure for the sensory analysis of gas chromatographic effluents. Food Chem. 1984 14, 273–286.

    Article  CAS  Google Scholar 

  • Blank, I; Fay, L. B. Formation of 4-hydroxy-2,5-dimethyl-3(2H)-furanone and 4-hydroxy-2(or5)-ethyl-5(or2)methyl-3(2H)-furanone through Maillard reaction based on pentose sugars. J. Agric. Food Chem. 1996 44, 531–536.

    Article  CAS  Google Scholar 

  • Buttery, R. G.; Haddon, W. E; Seifert, R. M.; Turnbaugh, J. G. Thiamin odor and bis(2-methyl-3-furfuryl) disulfide. 1984 32, 674–676.

    CAS  Google Scholar 

  • Buttery, R. G. Quantitative and sensory aspects of flavor of tomato and other vegetables. and fruits. Flavor Science: Sensible Principles and Techniques. Eds. T. E. Acree and R. Teranishi. American Chemical Society, Washington, DC 1993 pp. 259–286.

    Google Scholar 

  • Buttery, R. G.; Guadagni, D. G.; Ling, L. C. Flavor compounds: volatilities in vegetable oil and oil-water mixtures. Estimation of odor thresholds. J. Agric. Food Chem. 1973 21, 198–201.

    Article  CAS  Google Scholar 

  • Buttery, R. G.; Guadagni, D G.; Lundin, R. E. Some 4,5-Dialkylthiazoles with potent bell pepper like aromas. J. Agric. Food Chem. 1976 24, 1–3.

    Article  CAS  Google Scholar 

  • Buttery, R. G.; Ling, L. C. Direct formation of 4-alkoxy derivatives from 2,5-dimethyl-4-hydroxy-3(2H)-furanone and aliphatic alcohols. J. Agric. Food Chem. 1996 44, 1512–1514.

    Article  CAS  Google Scholar 

  • Buttery, R. G.; Ling, L. C. 2-Ethyl-3,5-dimethylpyrazine and 2-ethyl-3,6-dimethylpyrazine: Odor thresholds in water solution. Lebensm. - Wiss. U-Technol. 1997 30, 109–110.

    Article  CAS  Google Scholar 

  • Buttery, R. G.; Ling, L. C.; Juliano, B. O.; Turnbaugh, J. G. Cooked rice aroma and 2-acetyl-l-pyrroline. J. Agric. Food Chem. 1983 31, 823–826.

    Article  CAS  Google Scholar 

  • Buttery, R. G.; Teranishi, R. Measurement of fat autoxidation and browning aldehydes in food vapors by direct vapor injection gas-liquid chromatography. J. Agric. Food Chem. 1963 11, 504–507.

    Article  CAS  Google Scholar 

  • Ciamician, G.; Silber, P. Ueber die sedanolsaure and das sedanolid. Ber., 1897 30, 1427–1433.

    CAS  Google Scholar 

  • Frijters, J. E. R. Some psychophysical notes on the use of the odour unit number. In Progress in Flavor Research. Eds. D. Land and H. Nursten, 1979 pp. 47–51.

    Google Scholar 

  • Grosch, W; Zeller-Hilgart, G.; Cerny, C.; Guth, H. Studies on the formation of odorants contributing to meat flavor. In Progress in Flavor Precursor Studies. Eds. Schreier, P. and Winterhalter, P. Allured Publ. Corp. Carol Stream, Illinois 1993 pp. 329–342.

    Google Scholar 

  • Guadagni, D. G.; Buttery, R. G.; Okano, S. Odor thresholds of some organic compounds associated with food flavors. J. Sci. Fd. Agric. 1963A 14, 761–765.

    Article  CAS  Google Scholar 

  • Guadagni, D. G.; Buttery, R. G.; Harris, J. Odour intensities of hop oil components. J Sci. Fd Agric. 1966 17, 142–144.

    Article  CAS  Google Scholar 

  • Guadagni, D. G.; Buttery, R. G.; Okano, S.; Burr, H. K. Additive effect of sub-threshold concentrations of some organic compounds associated with food aromas. Nature 1963B 200, 1288–1289.

    Article  CAS  Google Scholar 

  • Guenther, E. The Essential Oils. D. Van Nostrand Co., Inc. New York, 1948–1952.

    Google Scholar 

  • Hodge, J. E.; Fisher, B. E.; Nelson, E. C. Dicarbonyls, reductones and heterocyclics produced by reactions of reducing sugars with secondary amine salts. Amer. Soc. Brewing Chem. Proc. 1963 84–92.

    Google Scholar 

  • Hunter, I. R.; Walden, M. K.; Scherer, J. R.; Lundin, R. E. Preparation and properties of 1,4,5,6-tetrahydro-2-acetopyridine, a cracker-odor constituent of bread aroma. Cereal Chem. 1969 46, 189–196.

    CAS  Google Scholar 

  • Keppler, J. G.; Schols, J. A.; Feenstra, W. H.; Meijboom, P. W. Components of the hardening flavor present in hardened linseed oil and soybean oil. J. Amer. Oil Chem. Soc. 1965 42, 246–250.

    Article  CAS  Google Scholar 

  • Lea, C. H.; Swoboda, P. A. T. Flavor of aliphatic aldehydes. Chem. & Ind. (London)., 1958, 1289–1290.

    Google Scholar 

  • Moncrieff, R. W. The Chemical Senses,CRC Press, 1967.

    Google Scholar 

  • Murahashi, S. The odor of matsutake. Rikagaku Kenkyusho Iho 1937 19, 414.

    Google Scholar 

  • Ohloff, G. Relationship between odor sensation and stereochemistry of decalin ring compounds. In Gustation and Olfaction. Eds. G. Ohloff and A. F. Thomas, Academic Press, London, 1971 pp. 178–185.

    Google Scholar 

  • Parliment, T. H. Characteristics of a compound with an intense corn chip/cereal aroma. In Flavors and Off-Flavors, Proceedings of the 6 th International Flavor Conference, Greece; Charalambouse, G., Ed; Elsevier: Amsterdam, 1989; pp. 299–304.

    Google Scholar 

  • Patton, S.; Josephson, D. V. A method of determining significance of volatile flavor compounds in foods. Food Research, 1957 22, 316–318.

    Article  Google Scholar 

  • Roberts, D. L. Pyrazine derivatives for improving flavor and aroma. U.S. Patent No. 3.402,051, Sep., 1968.

    Google Scholar 

  • Rodin, J. O.; Himel, C. M.; Silverstein, R. M.; Leeper, R. W; Gortner, W. A. Volatile flavor and aroma constiuents of pineapple. I. J. Food Sci. 1965 30, 280–285.

    Article  CAS  Google Scholar 

  • Rothe, M.; Thomas, B. Evaluation of chemical taste analyses with the aid of threshold values. Z. Lebensm. — Untersuch. Forsch 1963 119, 302–310.

    Article  CAS  Google Scholar 

  • Sanz, C.; Richardson, D. G.; Perez, A. G. 2,5-Dimethyl-4-hydroxy-3(2H)-furanone and derivatives in strawberries during ripening. In Fruit Flavors: Biogenesis,Characterization and Authentication. Eds. R. L. Rouseff and M. M. Leahy. ACS Symposium Series No. 596, American Chemical Society, Washington D. C. 1995 pp. 268–275.

    Google Scholar 

  • Schieberle, P. Primary odorants of popcorn. J. Agric. Food Chem. 1991 39, 1141–1144.

    Article  CAS  Google Scholar 

  • Schieberle, P.; Grosch, W. Quantitative analysis of aroma compounds in wheat and bread crusts using a stable isotope dilution assay. J. Agric. Food Chem. 1987 35, 252–257.

    Article  CAS  Google Scholar 

  • Schieberle, P.; Grosch, W. Quantitative analysis of important volatile flavor compounds in fresh and stored lemon oil/citric acid emulsions. Lebensm. —Wiss. U. —Technol. 1988 21, 158–162.

    CAS  Google Scholar 

  • Schorigin, P.; Issaguljanz, W; Below, W; Alexandrowa, S. Uber die zusammensetzung von hochsiedenden anteilen des fuselols. Ber. 1933 66, 1087–1093.

    Google Scholar 

  • Seifert, R. M.; Buttery, R. G.; Lundin, R. E.; Haddon, W. E; Benson, M. Identification of a Thiamin Odor Compound from Photolysis of Thiamin. J Agric. Food Chem. 1978 26, 1173–1176.

    Article  CAS  Google Scholar 

  • Stark, W; Forss, D. A. A compound responsible for metallic flavor in dairy products. J Dairy Res. 1962 29, 173–180.

    Article  CAS  Google Scholar 

  • Sulser, H; Habeggar, M; Buchi, W. Synthesis and sensory evaluation of 3,4-disubstituted 2-hydroxy-2-buten1,4-olides. Z. Lebensm. Unters. Forsch. 1972 148, 215–221.

    Article  CAS  Google Scholar 

  • Takei, S.; Ono, M. On the Odor of the Cucumber. J. Agric. Chem. Soc. Japan, 1939 15, 193–198.

    CAS  Google Scholar 

  • Teranishi, R; Buttery, R. G.; Guadagni, D. G. Odor, thresholds and molecular structure. Geruch-and Geschmack-stojfe. Ed. E. Drawert. Verlag, Nurnberg, Germany, 1975. pp. 177–186.

    Google Scholar 

  • Tonsbeek, C. H. Th.; Copier, H.; Plancken, A. J. Isolation of 2-acetyl-2-thiazoline from beef broth. J. Agric. Food Chem 1971 19, 1014–1016.

    Article  Google Scholar 

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© 1999 Springer Science+Business Media New York

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Buttery, R.G. (1999). Flavor Chemistry and Odor Thresholds. In: Teranishi, R., Wick, E.L., Hornstein, I. (eds) Flavor Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4693-1_30

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  • DOI: https://doi.org/10.1007/978-1-4615-4693-1_30

  • Publisher Name: Springer, Boston, MA

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