Skip to main content
SpringerLink
Log in

Organically Doped Sol-Gel Porous Glasses: Chemical Sensors, Enzymatic Sensors, Electrooptical Materials, Luminescent Materials and Photochromic Materials

  • Chapter
Sol-Gel Optics

Part of the book series: The Springer International Series in Engineering and Computer Science ((SECS,volume 259))

Abstract

The development of the method of trapping of organic molecules and enzymes in porous sol-gel matrices triggered the preparation and design of a wide range of novel optical materials. We review past achievements and recent progress made in the development of several classes of these materials, representing the diversity that the trapping approach allows: Chemical sensors, enzymatic sensors, electrooptical liquid crystal materials, luminescent materials and photochromic materials.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. G. W. Scherer and C. J. Brinker (1990) Sol-Gel Science, AcademicPress: San Diego.

    Google Scholar 

  2. Sol-Gel Technology, edited by L. C. Klein (1990). Noyes Publications, USA.

    Google Scholar 

  3. D. Avnir, R. Reisfeld and D. Levy (1983) Israel Patent Application 69724, Sept. 23.

    Google Scholar 

  4. D. Levy (1984) M.Sc. Thesis, The Hebrew University, Jerusalem.

    Google Scholar 

  5. D. Avnir, D. Levy, and R. Reisfeld, (1984), J. Phys. Chem., 88, 5956.

    Article  CAS  Google Scholar 

  6. For a review, see: D. Avnir, S. Braun and M. Ottolenghi, Supramolecular Architecture in Two and Three Dimensions, (1991) edited by T. Bein, ACS Symposium Ser. No. 499, Chapter 27.

    Google Scholar 

  7. D. Levy, (1992) J. Non-Cryst. Solids in press.

    Google Scholar 

  8. T. Bein, K. Brown, G. C. Frye and C. J. Brinker (1989),J. Amer. Chem. Soc., 111, 7640.

    Article  CAS  Google Scholar 

  9. K.T.V. Grattan, Badini, G.E., A.W. Palmer, and A.C.C. Tseung, (1991),Sensors and Actuators A 25–27, 483.

    Article  Google Scholar 

  10. G. Philipp and H. Schmidt (1984) J. Non-Crystal. Solids, 63, 283.

    Article  CAS  Google Scholar 

  11. K.K.Unger, Porous Silica (1979), Elsevier Scientific Pub. Company, Amsterdam.

    Google Scholar 

  12. M. Tsionsky, et al. (1992), in preparation.

    Google Scholar 

  13. H. J. Ache, (1992), private communication.

    Google Scholar 

  14. Ref. 1, p. 850–851.

    Google Scholar 

  15. L.L. Hench, (1986), in Science of Ceramic Chemical Processing, edited by L.L. Hench and D.R. Ulrich, Wiley, New York, p. 52–64.

    Google Scholar 

  16. B. Iosefzon-Kuyayskaya, I. Gigozin, M. Ottolenghi, D. Avnir and O. Lev, (1992), J. Non-Cryst. Solids, in press.

    Google Scholar 

  17. D. Levy, B. Iosefzon-Kuyayskaya, I. Gigozin, I. Zamir, D. Avnir, M. Ottolenghi and O. Lev, (1992)J. of Separation Science and Tech. 27, 589.

    Article  CAS  Google Scholar 

  18. C. Rottman, M. Ottolenghi, R. Zusman, O. Lev, M. Smith,G. Gong, M. L. Kagan and D. Avnir, (1992) Mater. Letters 13, in press.

    Google Scholar 

  19. W. R. Seitz, (1988) CRC Crit. Rev. Anal. Chem., 19, 135.

    CAS  Google Scholar 

  20. O. S. Wolfbeis, (1990)J. Anal. Chem., 337, 522.

    CAS  Google Scholar 

  21. R. E. Majors, (1977),J. of Chromatographic Science 15, 334.

    Article  CAS  Google Scholar 

  22. E. Stahl, (1969), Thin Layer Chromatography, A Laboratory Handbook, 2nd Ed., Springer-Verlag, Berlin

    Book  Google Scholar 

  23. G.V.Myasoedova and S.B. Savin (1986), CRC Crit. Rev. Anal. Chem. 17, 1.

    CAS  Google Scholar 

  24. R. W. Murray (1983) in Electroanalytical Chemistry, edited by A. J. Bard, Marcel Dekker, Inc., NY, 13, p. 191.

    Google Scholar 

  25. J. O. Norris (1989)Analyst 114, 1359.

    Article  CAS  Google Scholar 

  26. E. M. Rakhman’ko, V. V. Yegorov, A. L. Gulevich and Ya. F. Lushchik (1991)Selective Electrode Rev., 13, 5.

    Google Scholar 

  27. G. J. Moody and J. D. R. Thomas (1991) Selective Electrode Rev. 13, 113.

    CAS  Google Scholar 

  28. O. Lev, B. Iosefzon-Kuyayskaya, M. Tsionsky, D. Avnir and M. Ottolenghi, (1992) SPIE Proceedings, Vol. 1716, in preparation.

    Google Scholar 

  29. V. N. Zaytsev and A. K. Trophymchuk (1984)Ukraine Chem. J. 50, 1126.

    Google Scholar 

  30. I. Kuselman et al., (1992), in preparation.

    Google Scholar 

  31. S. Ikoma, K. Kawakita and H. Yokoi (1990)J. Non-Cryst.Solids 122, 183.

    Article  CAS  Google Scholar 

  32. R. Zusman, C. Rottman, M. Ottolenghi and D. Avnir, (1990) J. NonCryst. Solids, 122, 107.

    Article  CAS  Google Scholar 

  33. M. Nogami, K. Nagaska and E. Kato (1990)J. Am. Ceram. Soc. 73, 2097.

    Article  CAS  Google Scholar 

  34. J. I. Zink and B. Dunn, (1991) Japan J. Ceram. Soc., in press.

    Google Scholar 

  35. G. C. Frye, C. J. Brinker, A. J. Ricco, S. J. Martin, J. Hilliard and D. H. Doughty (1990) Mat. Res. Soc. Symp.Proc. 180, 583.

    Article  CAS  Google Scholar 

  36. E. T. Knobbe, B. Dunn and M. Gold (1988)SPIE Proceedings 906, 39.

    Article  CAS  Google Scholar 

  37. V. Chernyak, R. Reisfeld, R. Gvishi and D. Venezky (1990)Sensors and Materials 2, 117.

    CAS  Google Scholar 

  38. M. Eyal, R. Gvishi and R. Reisfeld, (1987) Journal De Physique C7, 471.

    Google Scholar 

  39. S. Braun, S. Rappoport, R. Zusman, D. Avnir and M. Ottolenghi (1990) Mat. Lett. 10, 1.

    Article  CAS  Google Scholar 

  40. C. Rottman, M. Ottolenghi, R. Zusman, O. Lev, M. Smith, G. Gong, M. L. Kagan and D. Avnir D (1992) Mater. Letters 13, in press.

    Google Scholar 

  41. C. E. Badini, K. T. V. Grattan, A. W. Palmer and A.C.C. Tseung, (1989) Springer Proceedings in Physics 44, edited by H. J. Ardity, J. P. Dakin and R. Th., Kersten, Springer-Verlag, Berlin p. 36.

    Google Scholar 

  42. B. D. MacCraith, V. Ruddy, C. Potter, B. O’Kelly, B. and J. F. McGilp (1991)Electron Lett. 27, 1247.

    Article  CAS  Google Scholar 

  43. J. Y. Ding, M. R. Shahriari, G. H. Sigel, Jr. (1991) Electron Leu., 27, 1560.

    Article  CAS  Google Scholar 

  44. J. I. Dulebohn, B. Van Vlierberge, K. A. Berglund, R. B. Lassard, J. A. Yu and D. G. Nocera (1990) Mat. Res. Soc. Symp. Proc. 180, 733.

    CAS  Google Scholar 

  45. O. Lev, B. Iosefzon-Kyayskaya, I. Gigozin, M. Ottolenghi and D. Avnir, (1992) Fresenius J. Anal. Chem., in press.

    Google Scholar 

  46. H. L. Kusnetz, B. E. Saltzman and M. E. Lanier (1960) Amer. Ind. Hyg. Assoc. J., 21, 361.

    CAS  Google Scholar 

  47. D. Avnir, M. Ottolenghi, S. Braun, R. Zusman and O. Lev (1990), worldwide patent application pending.

    Google Scholar 

  48. I. Kuselman, B. Iosefzon-Kuyayskaya and O. Lev (1992) Analytica Chimica Acta 256, 65.

    Article  CAS  Google Scholar 

  49. I. Kuselman et al. (1992) Talanta, submitted.

    Google Scholar 

  50. J. S. Shulz, S. Mansuri and I. J. Goldstein (1982) Diabetes Care 5, 245.

    Article  Google Scholar 

  51. S. Braun, S. Rappoport, R. Zusman, S. Shtelzer, Sh. Druckman, D. Avnir, and M. Ottolenghi (1991) in Biotechnology: Bridging Research and Applications, edited by D. Makely, A. Chakrabarty and S. E. Kornguth, Kluwer Acad. Publ., Boston, pp. 205–218.

    Google Scholar 

  52. M. Ottolenghi, O. Lev, S. Braun and D. Avnir, (1992) SPIE Proc. Ser. 1758, Sol-Gel Optics II, edited by J. D. Mackenzie, San Diego, in press.

    Google Scholar 

  53. S. Shtelzer, S. Rappoport, D. Avnir, M. Ottolenghi and S. Braun (1992) Biotechnol. Appl. Biochem., in press.

    Google Scholar 

  54. S. Braun, S. Shtelzer, S. Rappoport, D. Avnir, and M. Ottolenghi (1992) J. Non-Cryst. Solids, in press.

    Google Scholar 

  55. W. Norde and J. Lykelema (1979) J. Colloid Interface Sci. 71, 350.

    Article  CAS  Google Scholar 

  56. J. Lykelema (1984) J. Colloid Surf. 10, 33.

    Article  Google Scholar 

  57. L.L. Hench and J. Wilson (1990) Mat. Res. Soc. Symp. Proc. 180, 1061.

    Article  CAS  Google Scholar 

  58. T. T. Ngo and H. M. Lenhoff (1980)Anal. Biochem. 105, 389.

    Article  CAS  Google Scholar 

  59. Ellerby, L.M., Nishida, C.R., F. Nishida, Yamanaka, S.A., B. Dunn, Valentine, J.S., and J. I. Zink (1992)Science 225, 1113.

    Article  Google Scholar 

  60. D. Levy, C. J. Serna and J. M. Oton (1991) Mat. Leu., 10 470.

    Article  CAS  Google Scholar 

  61. D. Levy, J. M. Oton and C. J. Serna (1991) Spanish Patent Application 91013

    Google Scholar 

  62. J. M. Oton, A. Serrano, C. J. Serna and D. Levy (1991)Liq.Cryst., 10, 733.

    Article  CAS  Google Scholar 

  63. J. R. Bellare, H. T. Davis, W. G. Miller and L. E. Scriven (1990) J. Colloid. Interf. Sci., 136, 305.

    Article  CAS  Google Scholar 

  64. D. Levy, J. M. S. Pena, C. J. Serna and J. M. Oton, (1992) J. Non-Cryst. Solids, in press.

    Google Scholar 

  65. D. Levy, C. J. Serna, A. Serrano and J. M. Oton (1992) SPIE Proc. Ser. 1758, Sol-Gel Optics II, edited by J. D. Mackenzie, San Diego, in press.

    Google Scholar 

  66. A. Makishima and T. Tani (1986) J. Am. Ceram. Soc. 69, C-72.

    Google Scholar 

  67. Y. Koboyashi, Y. Imai. and Y. Kurokawa (1988)J. Mat. Sci.Lett. 7, 1148.

    Article  Google Scholar 

  68. D. Avnir, V. R. Kaufman and R. Reisfeld (1985)J. Non-Cryst. Solids 74, 395.

    Article  CAS  Google Scholar 

  69. R. Reisfeld, M. Eyal and D. Brusilowski (1988)Chem. Phys. Lett. 153, 210.

    Article  CAS  Google Scholar 

  70. E. J. A. Pope and J. D. Mackenzie (1987)MRS Bull., March 17, 29.

    Google Scholar 

  71. T. Fujii, A. Ishii and M. Anpo (1990) J. Photochem. Photobiol. A54, 231.

    Article  Google Scholar 

  72. D. I. Santos, M. A. Aegerter, C. H. Briocurz, M. Scarparo and J. Zarzycki (1986) J. Non-Cryst. Solids 82, 231.

    Article  Google Scholar 

  73. ] M. Eyal, R. Reisfeld, V. Chernyak, L. Kaczmarek and A. Grabowska (1991)Chem. Phys. Lett. 176, 531.

    Article  Google Scholar 

  74. R. Reisfeld, D. Brusilovski, M. Eyal and K. Jorgensen (1989)Chimia 43, 385.

    CAS  Google Scholar 

  75. T. Fujii, O. Kawauchi, Y. Kurikawa, A. Ishii, N. Negishi and M. Anpo (1990) Chem. Express 5, 917.

    CAS  Google Scholar 

  76. R. Reisfeld and R. Gvishi (1987)Chem. Phys. Lett. 138, 377.

    Article  CAS  Google Scholar 

  77. T. Fujii, A. Ishii, H. Nagai, M. Niwano, N. Negishi, and M. Anpo (1989)Chem. Express 4, 1.

    CAS  Google Scholar 

  78. J. C. Pouxviel, S. Parvaneh, E. T. Knobbe and B. Dunn (1989) Solid State Ionics 32/33, 646.

    Article  Google Scholar 

  79. K. Matsui, T. Matsuzuka and H. Fujita (1989) J. Phys. Chem. 93, 4991.

    Article  CAS  Google Scholar 

  80. T. F’ujii, T. Mabuchi and I. Mitsui (1990) Chem. Phys. Lett. 68, 5.

    Article  Google Scholar 

  81. T. Yamanaka, Y. Takahashi and K. Uchida (1990)Chem. Phys. Lett. 172, 405.

    Article  CAS  Google Scholar 

  82. J. McKiernan J. C. Pouxviel, B. Dunn and J. I. Zink (1989) J. Phys. Chem. 93, 2129.

    Article  Google Scholar 

  83. R. Winter, D. W. Hua, X. Song, W. Mantulinand J. Jonas (1990) J. Phys. Chem. 94, 2706.

    Article  CAS  Google Scholar 

  84. D. Preston, J. C. Pouxviel, T. Novinson, W.C. Kaska, B. Dunn and J. I. Zink (1990)J. Phys. Chem. 94, 4167.

    Article  CAS  Google Scholar 

  85. A. R. Gutierez, J. Friedrich, D. Haarer and H. Wolfrum (1982)IBM J. Res. Div. 26, 198.

    Article  Google Scholar 

  86. R. Locher, A. Renn and V.P. Wild (1987)Chem. Phys. Lett. 138, 405.

    Article  CAS  Google Scholar 

  87. H. Tanaka, J. Takahashi, J.Tsuchiya, Y. Koboyashi and Y. Kurokawa (1989)J. Non-Cryst. Solids 109, 164.

    Article  CAS  Google Scholar 

  88. T. Tani, A. Namikawa, K. Arai and A. Makishima (1985)J. Appl. Phys. 58,:3559.

    Article  CAS  Google Scholar 

  89. Y. Koboyashi, Y. Kurokawa, Y. Imai and S. Muto (1988)J. Non-Cryst. Solids 105, 198.

    Article  Google Scholar 

  90. H. Sasaki, Y. Koboyashi, S. Muto and Y. Kurokawa (1990)J. Am. Ceram. Soc. 73, 453.

    Article  CAS  Google Scholar 

  91. B. Dunn, E. T. Knobbe, J. M. McKiernan, J. C. Pouxviel and J. I. Zink (1988) Mat. Res. Soc. Symp. Proc. 121, 331.

    Article  CAS  Google Scholar 

  92. E. T. Knobbe, B. Dunn, P. D. Fuqua and F. Nishida (1990)Appl. Opt. 29, 2729.

    Article  CAS  Google Scholar 

  93. F. Salin, G. Le Saux, P. Georges, A. Brun, C. Bagnall and J. Zarzycki (1989)Appl. Opt. 14, 785.

    CAS  Google Scholar 

  94. J. I. Zink and B. Dunn (1993) this volume, pp. 301–326.

    Google Scholar 

  95. J. Fitreman, S. Doeuff, S. and C. Sanchez (1990),Ann. Chim.Fr. 15, 421.

    Google Scholar 

  96. J. C. Altman, R. E. Stone, B. Dunn and F. Nishida (1991)IEEE Photonics Tech. Lett. 3, 189.

    Article  Google Scholar 

  97. M. Canva, P. Georges, A. Brun, D. Larrue and J. Zarzycki (1992) J. NonCryst. Solids, in press.

    Google Scholar 

  98. A. C. Capozzi and L. D. Pye (1989) SPIE Proc., Properties and Characteristic Optical Glass, 970.

    Google Scholar 

  99. R. Reisfeld (1990)J.Non-Cryst. Solids, 121, 254.

    Article  CAS  Google Scholar 

  100. J. I. Zink, B. Dunn, R. B. Kaner, E. T. Knobbe and J. McKiernan (1990) ACS Symp. Materials for Nonlinear Optics, edited by S. R. Marder 455 Ch. 36, 541, Boston.

    Google Scholar 

  101. E. Toussaere, J. Zyss, P. Griesmar and C. Sanchez (1991)Nonlinear Optics 1, 1.

    Google Scholar 

  102. M. Nakamura, H. Nasu and K. Kamiya (1991)J. Non-Cryst. Solids 135, 1.

    Article  CAS  Google Scholar 

  103. Y. Haruvy and S. E. Webber (1992) Chem. Mater. 4, 89.

    Article  CAS  Google Scholar 

  104. P. N. Prasad (1990) Mat. Res. Soc. Symp. Proc. 180, 741.

    CAS  Google Scholar 

  105. P.Griesmar, C.Sanchez, G.Puccetti, I.Ledoux and J.Zyss,(1991)J. Mol. Engineering 3,1.

    Google Scholar 

  106. R. Reisfeld in Sol-Gel Science and Technology,(1989) edited by M. A. Aegerter et al. World Scientific:Singapore(1989)pp.323–345.

    Google Scholar 

  107. R. Reisfeld and G. Seybold (1990)Chimia 44, 295.

    CAS  Google Scholar 

  108. R. Reisfeld et al.,(1989)Chem. Phys. Lett. 160, 43.

    Article  CAS  Google Scholar 

  109. H. Nakazumi, S. Amano and T. Kitao (1991)Chem. Express 6, 607.

    CAS  Google Scholar 

  110. E. J. A. Pope, M. Asami and J. D. Mackenzie (1989)J. Mater. Res. 4, 1018.

    Article  CAS  Google Scholar 

  111. V. R. Kaufman, D. Levy and D. Avnir (1986)J. Non-Cryst. Solids 82 103.

    CAS  Google Scholar 

  112. D. Levy and D. Avnir (1991) J. Photochem. Photobiol. A: Chem., 57, 41.

    Article  CAS  Google Scholar 

  113. M. Ueda, H.B. Kim, T. Ikeda and K. Ichimura (1992) K. Chem. Mater. in press.

    Google Scholar 

  114. D. Levy and D. Avnir (1988)J. Phys. Chem., 92, 4734.

    Article  CAS  Google Scholar 

  115. D. Levy, S. Einhorn and D. Avnir (1989) J. Non-Cryst. Solids 113, 137.

    Article  CAS  Google Scholar 

  116. V. R. Kaufman, D. Levy and D. Avnir (1986) J. Non-Cryst.Solids 82, 103.

    Article  CAS  Google Scholar 

  117. K. Matsui, T. Morohoshi and S. Yoshida (1988) Proc. Int. Meet. Adv. Mat., Tokyo.

    Google Scholar 

  118. T. Morohoshi and K. Matsui (1989)Kenkyiu Hokoku 32, 229 (Chem. Abstr. 1989,111:47962r)

    CAS  Google Scholar 

  119. S. Dire, F. Babonneau, G. Carturan and J. Livage (1992) J. Non-Cryst. Solids, in press.

    Google Scholar 

  120. M. Canva, G. Le Saux, P. Georges, A. Braun, F. Chaput, and J-P. Boilot, (1992) Opt. Letters, in press.

    Google Scholar 

  121. M. Canva, G. Le Saux, P. Georges, A. Braun, F. Chaput, and J-P. Boilot, (1992) J. Non-Cryst. Solids, in press.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institutes of Chemistry, The Hebrew University, Jerusalem, 91904, Israel

    David Avnir & Michael Ottolenghi

  2. Life Sciences, The Hebrew University, Jerusalem, 91904, Israel

    Sergei Braun

  3. Environmental Sciences, The Hebrew University, Jerusalem, 91904, Israel

    Ovadia Lev

  4. Instituto de Ciencia de Materiales, CSIC, Serrano, 115 dpdo., Madrid, 28006, Spain

    David Levy

Authors
  1. David Avnir
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Michael Ottolenghi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sergei Braun
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ovadia Lev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. David Levy
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Rutgers, The State University of New Jersey, USA

    Lisa C. Klein

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer Science+Business Media New York

About this chapter

Cite this chapter

Avnir, D., Ottolenghi, M., Braun, S., Lev, O., Levy, D. (1994). Organically Doped Sol-Gel Porous Glasses: Chemical Sensors, Enzymatic Sensors, Electrooptical Materials, Luminescent Materials and Photochromic Materials. In: Klein, L.C. (eds) Sol-Gel Optics. The Springer International Series in Engineering and Computer Science, vol 259. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2750-3_23

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-2750-3_23

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-7923-9424-2

  • Online ISBN: 978-1-4615-2750-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation