Abstract
A normative review of the literature describing the products, mechanisms, and rates of lignin and whole biomass pyrolysis is presented. The role of a complex sequence of competing solid- and vapor-phase pyrolysis pathways is elucidated.
This paper is dedicated to the memory of Fred Shafizadeh, Professor of Chemistry and Director of the Wood Chemistry Laboratory, University of Montana.
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References
M. J. Moran, Availability Analysis: A Guide to Efficient Energy Uses (Prentice-Hall, Englewood Cliffs, 1982).
M. J. Antal, Jr., “Biomass pyrolysis: A review of the literature Part I-Carbohydrate pyrolysis” in Advances in Solar Energy edited by K. W. Bäer and J. A. Duffie (American Solar Energy Society, Boulder, Colo.) Vol. 1, pp. 61–112 (1982).
F. Shafizadeh, Adv. in Carbohydrate Chem. 23, 419 (1968).
G. David and M MacKay, Forestry Branch Dept. Pub. 1201, ODC 813.4 (1967).
J. R. Welker, J. Fire and Flammability 1, 12 (1970).
F. Shafizadeh, in Appl. Polymer Symp. No. 28 (J. Wiley and Sons, New York, 1975) p. 153.
F. Shafizadeh, in Proceedings of the Specialists Workshop on Fast Pyrolysis of Biomass, SERI/CP-622-1096 (Solar Energy Research Institute, Golden, Colo., 1980).
P. M. Molton and T. F. Demmitt, BNWL-2297 UC (Battelle Pacific Northwest Lab., Richland, Wash., 1977).
T. Milne, in Biomass Gasification: Principles and Technology edited by T. Reed (Noyes Data Corp., Park Ridge, N. J., 1981).
F. J. Kilzer, in Cellulose and Cellulose Derivatives, Vol. 5, 2nd Ed. (Wiley-Interscience, New York, 1971) pp. 1015–1046.
O. Wolf, Staerke 2, 273 (1950).
J. A. Radley, Starch and Its Derivatives, Vol. 2, 3rd Ed. (Chapman Hall Ltd., London, 1953) p. 107.
C. C. Gaper and D. M. Rathman, in Industrial Gums edited by R. L. Whistler (Academic Press, Inc., New York, 1959) p. 699.
G. V. Caesar, in Chemistry and Industry of Starch, 2nd Ed., edited by R. W. Kerr (Academic Press, Inc., New York, 1950) p. 345.
C. T. Greenwood, Adv. Carbohyd. Chem. 22, 483 (1967).
O. Theander, in Carbohydrate Sweeteners in Foods and Nutrition edited by P. Koivistoinen and C Hyvonen (Academic Press, Inc., London, 1980) p. 185.
S. Peat et al., J. Chem. Soc., 586 (1958).
M. Cerny and J Stanek, Fortschr. Chem. Forsch. 14, 526–555 (1970).
R. J. Dimler, Adv. Carbohy. Chem. 7, 37 (1952).
M. Cerny and J Stanek, Jr., Adv. Carbohyd Chem. 34, 23 (1977).
F. Shafizadeh et al., Carbohyd. Res. 13, 184 (1970).
F. Shafizadeh et al., Carbohyd. Res. 15, 165 (1970).
F. Shafizadeh, R. A. Susott, and C. R. McIntyre, Carbohyd. Res. 41, 351 (1975).
F. Shafizadeh and R. A. Susott, J. Org. Chem. 38, 3710 (1973).
Y. J. Park, H. S. Kim, and G. A. Jeffrey, Acta Cryst. B27, 220 (1971).
W. Sandermann and H Augustin, Holz Roh Werkst. 22, 377–386 (1964).
W. Sandermann and H Augustin, Chem. Abstr. 66, 11994 (1967).
M. S. Bains, Carbohydr. Res. 34, 169–173 (1979).
International Critical Tables, Vol. 5 (McGraw-Hill, New York, 1929) p. 166.
D. R. Stull, E. F. Westrum, and G. C. Sinke, The Chemical Thermodynamics of Organic Compounds (Wiley, New York, 1969).
A. Pictet, Helv. Chim. Acta 1, 276 (1918).
H. Pringsheim and K Schmalz, Ber. 55B, 3001 (1922).
J. C. Irvine and J. W. H. Oldham, J. Chem. Soc. 127, 2903 (1925).
J. daS Carvalho, W. Prins, and C Schuerch, J. Am. Chem. Soc. 81, 4054 (1959).
M. L. Wolfrom, A. Thompson, and R. B. Ward, J. Am. Chem. Soc. 81, 4623 (1959).
M. L. Wolfrom et al., J. Org. Chem. 26, 4617 (1961).
H. Abe and W Prins, Makromol. Chem. 42, 216 (1961).
A. Bhattecharya and C Schuerch, J. Org. Chem. 26, 3101 (1961).
F. Shafizadeh and Y. Z. Lai, Carbohyd. Res. 40, 263 (1975).
P. T. Mora and J. W. Wood, J. Am. Chem. Soc. 80, 685 (1958).
H. W. Durand, M. F. Dull, and R. S. Tipson, J. Am. Chem. Soc. 80, 3691 (1958).
P. T. Mora et al., J. Am. Chem. Soc. 80, 693 (1958).
H. Sugisawa and H Edo, Chem. Ind. (London, 1964) p. 892.
G. G. S. Dutton and A. M. Unrau, Can. J. Chem. 40, 1196 (1962).
G. G. S. Dutton and A. M. Unrau, Can. J. Chem. 41, 2439 (1963).
G. G. S. Dutton and A. M. Unrau, Can. J. Chem. 42, 2048 (1964).
H. Sugisawa, J. Food Sci. 31, 381 (1966).
K. Kato and H Komorita, Agr. Biol. Chem. 32, 715 (Tokyo, 1968).
G. N. Richards and F Shafizadeh, Aust. J. Chem. 31, 1825 (1978).
J. R. Katz., Rec. Trav. Chim. 53, 554 (1934).
J. R. Katz and A Weidinger, Z. Physik, Chem. A148, 100 (1939).
B. Brimhall, Ind. Eng. Chem. 36, 72 (1944).
R. W. Kerr and F. C. Cleveland, Staerke 5, 261 (1953).
A. Thompson and M. L. Wolfrom, J. Am. Chem. Soc. 80, 6618 (1958).
M. L. Wolfrom, A. Thompson, and R. B. Ward, Ind. Eng. Chem. 53, 217 (1961).
G. V. Caesar, N. S. Gruenhut, and M. L. Cushing, J. Am. Chem. Soc. 69, 617 (1947).
H. Rüggeberg, Staerke 4, 78 (1952).
J. D. Geerdes, B. A. Lewis, and F Smith, J. Am. Chem. Soc. 79, 4209 (1957).
G. M. Christensen and F Smith, J. Am. Chem. Soc. 79, 4492 (1957).
F. Shafizadeh and A. G. W. Bradbury, J. Appl. Polym. Sci. 23, 1431 (1979).
S. L. Madorsky, V. E. Hart, and S Straus, J. Res. Nat. Bur. Stand. 56, 343 (1956).
S. L. Madorsky, J. Res. Nat. Bur. Stand. 60, 343 (1958).
S. L. Madorsky, Thermal Degradation of Organic Polymers (Interscience Publishers, J. Wiley and Sons, Inc., New York, 1964).
M. Lewin and A Basch, In “Fire retardancy,” in The Encyclopedia of Polymer Science and Technology, Suppl. Vol. 2 (J. Wiley and Sons, Inc., New York, 1977) p. 340.
W. D. Major, Tappi 41, 530 (1958).
S. T. Kosiewicz, Thermochimica Acta 40, 322 (1980).
O. P. Golova and R. G. Krylova, Dokl. Akad. Nauk, SSSR 116, 419 (1957).
S. Patai and Y Halpern, Israel J. Chem. 8, 655 (1970).
T. V. Gatovskaya et al., Zh. Fiz. Khim. 33, 1418 (1959).
T. V. Gatovskaya et al., Chem. Abs. 54, 8212 (1960).
A. Paucault and G Sauret, Compt. Rend. Acad. Sci. 246, 608 (1958).
D. P. C. Fung, Tappi 52, 319 (1969).
A. Broido and F. J. Kilzer, Fire Res. Abstr. Rev. 5, 157 (1963).
Y. Halpern and S Patai, Israel J. of Chem. 7, 673 (1969).
A. Broido et al., J. Appl. Polym. Sci. 17, 3627 (1973).
A. Broido and H Yow, J. Appl. Polym. Sci. 21, 1677 (1977).
F. J. Kilzer and A Broido, Pyrodynamics 2, 151 (1965).
M. Weinstein and A Broido, Combus. Sci. & Tech. 1, 287–292 (1970).
A. Broido and M Weinstein, Combus. Sci. & Tech. 1, 279 (1970).
F. Shimazu and C Sterling, J. Food Sci. 31, 548 (1966).
A. Basch and M Lewin, J. Polym. Sci. 11, 2071 (1973).
K. Kato and H Komorita, Agr. Biol. Chem. 32, 21 (1968).
K. E. Cabradilla and S. H. Zeronian, in Thermal Uses and Properties of Carbohydrates and Lignins edited by F. Shafizadeh, K. V. Sarkanen, and D. A. Tillman (Academic Press, New York, 1976).
A. Basch and M Lewin, J. Polym. Sci. 11, 3071 (1973).
A. Basch and M Lewin, J. Polym. Sci. 12, 2053 (1974).
J. C. Arthur, Jr. and O Hinojosa, Textile Res. J. 36, 385 (1966).
J. C. Arthur, Jr., T. Mares, and O Hinojosa, Textile Res. J. 36, 630 (1966).
P. J. Baugh, O. Hinojosa, and J. C. Arthur, Jr., J. Appl. Polym. Sci. 11, 1139 (1967).
T. Maresad and J. C. Arthur, Jr., J. Polym. Sci. 7, 419 (1969).
N. S. Hon, J. Polym. Sci., Polym. Chem. Ed. 13, 1347 (1975).
N. S. Hon, J. Polym. Sci., Polym. Chem. Ed. 13, 955 (1975).
W. A. Reeves, J. Text. Inst. 53, 22 (1962).
H. Mehta, Text. Res. J. 31, 387 (1969).
R. S. Parikh, Text. Res. J. 37, 538 (1967).
R. H. Barker and S. L. Vail, Text. Res. J. 37, 1077 (1967).
A. Basch, private communication.
A. Broido, M. Evett, and C. C. Hodges, Carbohyd. Res. 44, 267 (1975).
G. R. Bedford and D Gardiner, Chem. Commun. 13, 287 (1965).
F. Shafizadeh et al., Carbohyd. Res. 61, 519 (1978).
F. Shafizadeh and P. P. S. Chin, Carbohyd. Res. 46, 149 (1976).
F. Shafizadeh et al., Carbohyd. Res. 64, 433 (1978).
Y. Halpern, R. Riffen, and A Broido, J. Org. Chem. 38, 204 (1973).
F. Shafizadeh, C. W. Philpot, and N Ostojie, Carbohyd. Res. 16, 279 (1971).
F. Shafizadeh, R. H. Furneaux, and T. T. Stevenson, Carbohyd. Res. 71, 169 (1979).
Y. Houminer and S Patai, Tetrahedron Letters 14, 1297 (1967).
Y. Houminer and S Patai, Israel J. Chem. 7, 513 (1969).
K. Heyns, R. Stute, and H Paulsen, Carbohyd. Res. 2, 132 (1966).
K. Heyns and M Klier, Carbohyd. Res. 6, 436 (1968).
D. J. Bryce and C. T. Greenwood, Appl. Polym. Symp. 2, 149 (1966).
D. J. Bryce and C. T. Greenwood, Staerke 15, 285 (1963).
D. J. Bryce and C. T. Greenwood, Staerke 15, 359 (1963).
A. Pictet and J Sarasin, Compt. Rend. 166, 38; Helv. Chim. Act. 1, 87 (1918).
S. Glassner and A. R. Pierce, III, Anal. Chem. 37, 525 (1965).
S. B. Martin and R. W. Ramstad, Anal Chem. 33, 982 (1961).
C. T. Greenwood, J. H. Knox, and E Milne, Chem. Ind. 46, 1878 (London, 1961).
D. Gardiner, J. Chem. Soc. (C), 1473 (1966).
G. A. Byrne, D. Gardiner, and F. H. Holmes, J. Appl. Chem. 16, 81 (1966).
A. E. Lipska and F. A. Wodley, J. Appl. Polym. Sci. 13, 851 (1969).
F. A. Wodley, J. Appl. Polym. Sci. 15, 835 (1971).
F. Shafizadeh, Y. Z. Lai, and R. A. Susott, Carbohyd. Res. 25, 387 (1972).
I. A. Puddington, Can. J. Res. B26, 415 (1948).
R. H. Furneaux and F Shafizadeh, Carbohyd. Res. 74, 354 (1979).
F. Shafizadeh et al., J. Appl Polym. Sci. 23, 3525 (1979).
F. Shafizadeh and T. T. Stevenson, J. Appl. Polym. Sci., in press.
F. Shafizadeh, T. Cochran, and Y Sakai, AlChE Symposium Series 184 75, 24 (1979).
C. M. Lakshmanan and H. E. Hoelscher, Ind. Eng. Chem. Prod. Res. Dev. 9, 57 (1970).
C. M. Lakshmanan and H. E. Hoelscher, Staerke 22, 261 (1970).
L. J. Carlson, U. S. Pat. 3,235,541, Chem. Abstr. 64, 16,122 (1966).
A. K. Esterer, U. S. Pat. 3,298,928, Chem. Abstr. 66, 56,886 (1967).
A. K. Esterer, U. S. Pat. 3,309,356, Chem. Abstr. 66, 106,072 (1967).
W. Mok and M. J. Antal, Jr., Thermochim. Acta. 68, 155 (1983).
W. Mok and M. J. Antal, Jr., Thermochim. Acta. 68, 165 (1983).
D. F. Arseneau, Can. J. Chem. 49, 632 (1971).
D. F. Arseneau, in Thermal Analysis Proceedings of the Third JCTA edited by Hans G. Wiedemann (Birkhauer, Basel, 1971).
A. Broido and M Weinstein, in Thermal Analysis Proceedings of the Third ICTA edited by Hans G. Wiedemann (Birkhauer, Basel, 1971) p. 285.
A. Broido and M. A. Nelson, Comb. Flame 24, 263 (1975).
A. Broido, in Thermal Uses and Properties of Carbohydrates and Lignins edited by F. Shafizadeh, K. V. Sarkanen, and D. A. Tillman (Academic Press, New York, 1976) p. 19.
A. G. W. Bradbury, Y. Sakai, and F Shafizadeh, J. Appl Polym. Sci. 23, 3271 (1979).
P. K. Chatterjee and C. M. Conrad, Text. Res. J. 36, 487 (1966).
C. Dollimore and B Holt, J. Polym Sei. A11, 1703 (1973).
C. Fairbridge, R. A. Ross, and S. P. Sood, J. Appl. Polym. Sci. 22, 497 (1978).
C. Kala, I. S. Gur, and H. L. Bhatnagar, Indian J. Chem. 19A, 641 (1980).
M. R. Hajaligol et al. Ind. Eng. Chem. Process Des. Dev. 21, 457 (1982).
M. J. Antal, Jr., H. L. Friedman, and F. E. Rogers, Comb. Sci. and Tech. 21, 141 (1980).
M. J. Antal, Jr., in Thermal Analysis Proceedings of the 7th 1CTA (Kingston, Canada, 1982).
J. Lédé, comments during presentation, American Chemical Society Annual Meeting, Washington, D. C., Sept. 1983.
A. Broido, private communication.
O. P. Golova, R. G. Krylova, and I. I. Nikolaeva, Vysokomol. Soedin 1, 1235 (1959).
A. M. Pakhomov, O. P. Golova, and I. I. Nikolaeva, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk. 521, Chem. Abs. 52, 3811 (1958).
O. P. Golova et al., Dokl. Akad. Nauk SSSR 115, 1122; Chem. Abs. 52, 4165 (1958).
A. N. Kislitsyn et al., Zh Prikl. Khim. 44, 2587 (Leningrad, 1971).
A. N. Kislitsyn and S. M. Rodionova, Tr. Tsentr. Nauchn.-Issled. Inst. Leokhim. Prom. 20 (1969).
A. M. Pakhomov, Izv Akad. Nauk SSSR Otdel. Khim. Nauk. (1957) 1497, Chem. Abs. 52, 5811 (1958).
O. P. Golova, A. M. Pakhomov, and E. A. Andrievskaya, Izv. Akad. Nauk. SSSR, Otdel. Khim. Nauk. 1499 (1957), Chem. Abs. 52, 5811 (1958).
O. P. Golova, Russian Chemical Reviews 44, 687 (1975).
F. Shafizadeh and Y. L. Fu, Carbohydrate Res. 29, 113 (1973).
F. Shafizadeh, A. G. W. Bradbury, and W. F. DeGroot, “Formation and reactivity of cellulosic chars,” 29, 2163 (1984).
A. Ohnishi, K. Kato, and E Takagi, Polym. J. 7, 431 (1975).
E. F. L. J. Anet, Adv. Carbohyd. Chem. 19, 181 (1964).
J. Lédé et al., Revue Phys. Appl. 15, 545 (1980).
M. Hopkins, M. J. Antal, Jr., and J Kay, J. Applied Polym. Sci., 29, 2163 (1984).
M. J. Antal, Jr., in Biomass as a Nonfossil Fuel Source edited by D. E. Klass (American Chemical Society, Washington, D. C., 1981).
M. J. Antal, Jr., Ind. Eng. Chem. Prod. Res. Dev. 22, 366 (1983).
A. Cutler, Ph.D. thesis, Princeton University, 1984.
T. A. Milne and M. N. Soltys, Fundamental Pyrolysis Studies. Annual Report for Fiscal Year 1981, SERI/PR-234-1454 (Solar Energy Research Institute, Golden, Colo., 1981).
T. A. Milne and M. N. Soltys, J. Anal. Appl. Pyrol. 5, 93 (1983).
T. A. Milne and M. N. Soltys, J. Anal. Appl. Pyrol. 5, 111 (1983).
H. R. Schulten and W Gortz, Anal. Chem. 50, 428 (1978).
H. R. Schulten, U. Bahr, and W Gortz, J. Anal. Appl. Pyrolysis 3, 137 (1981).
H. R. Schulten and W. Gärtz, Anal. Chem. 50, 428 (1978).
H. R. Schulten. U. Bahr, and W. Gärtz, J. Anal. Appl. Pyrol. 3, 137 (1981).
H. R. Schulten, U. Bahr, and W. Gärtz, J. Anal. Appl. Pyrol. 3, 229 (1981).
S. B. Martin, presented at the Tenth Symposium (International) on Combustion, The Comb. Inst., 877 (1965).
J. B. Berkowitz-Mattuck and T Noguchi, J. Appl. Polym. Sci. 7, 709 (1963).
K. A. Lincoln Pyrodynamics 2, 133 (1965).
K. A. Lincoln, in Proceedings of the Specialists’ Workshop on Fast Pyrolysis of Biomass, SERI/CP-622-1096 (Solar Energy Research Institute, Golden, Colo., 1980).
P. C. Lewellen, W. A. Peters, and J. B. Howard, presented at the Sixteenth International Symposium on Combustion, MIT (1976).
M. R. Hajaligol et al., Ind. Eng. Chem. Process Des. Dev. 21, 457 (1982).
F. Shafizadeh and Y. Z. Lai, J. Org. Chem. 37, 278 (1972).
Y. S. Stein, M. J. Antal, and M Jones, J. Anal. Appl. Pyrol. 4, 283 (1983).
R. R. Baker, J. Thermal Analysis 8, 163 (1975).
I. L. Eventova et al., Khim. Volokra 4, 29 (1974).
R. K. Agrawal and R. J. McCluskey, J. Appl. Polym. Sci. 27, 367 (1983).
R. K. Agrawal and R. J. McCluskey, Division of Fuel Chemistry preprints, Vol. 28, p. 5 (American Chemical Society, Washington, D. C., 1983).
P. K. Chatterjee, J. Appl. Polym. Sci. 12, 1859 (1968).
A. E. Lipska and W. J. Parker, J. Appl. Polym. Sci. 13, 851 (1966).
W. K. Tang and W. K. Neill, J. Polym. Sci. C:6, 65 (1964).
J. G. Wiegerink, J. Res. Natl. Bur. Stand. 25, 435 (1940).
R. C. Waller, K. C. Bass, and W. E. Roseveare, Ind. Eng. Chem. 40, 138 (1948).
A. J. Stamm, Ind. Eng. Chem. 48, 413 (1956).
M. J. Antal, Jr., H. L. Friedman, and F. E. Rogers, Comb. Sci. and Tech. 21, 141 (1980).
O. P. Golova and R. G. Krylova, Dokl. Akad. Nauk SSR 135, 1391 (1960).
J. W. Lyons, The Chemistry and Uses of Fire Retardants, (Wiley-Interscience, New York, 1970).
F. H. Newth. Advances in Carbohydrate Chemistry 6, 83 (1951).
A. Basch et al., Cell. Chem. Tech. 5, 353 (1973).
A. Basch, B. Hirschman, and M Lewin, Cell. Chem. Tech. 7, 255 (1973).
B. Schaffer. A. Basch, and M Lewin, Proc. 6th Intl. Wool Text. Conf. 5, 267 (1980).
A. Basch and M Lewin, Text. Res. J. 43, 693 (1973).
A. Basch and M Lewin. Text. Res. J. 45, 246 (1975).
M. J. Antal. Jr., in Proceedings, Bio-Energy’ 80 (BioEnergy Council, Washington, D. C., 1980).
D. W. Goheen, D. W. Glennie, private communication.
D. W. Goheen, in Lignins edited by K. V. Sarkanen and C. H. Ludwig (Wiley-Interscience, New York, 1971).
D. W. Goheen, in Organic Chemicals from Biomass edited by I. S. Goldstein (CRC Press, 1981).
G. G. Allan and T Matilla, in Lignins edited by K. V. Sarkanen and C. H. Ludwig (Wiley-Interscience, New York, 1971).
E. Adler, Wood Sci. Technol. 2, 169 (1977).
S. Drew, AIChE Symposium Series 181 79, 21 (1978).
T. Nguyen, E. Zavarin, and E. M. Barrai, III, J. Macromol. Sci. Rev. Macromol. Chem. C20, 1 (1981).
R. W. Coughlin, E. Avni, and D. W. Sundstrom, Conversion of Lignin to Useful Products, in press.
W. Sandermann and H Augustin, Holz. Roh-Werkstoff 21, 305 (1963).
W. Sandermann and H Augustin, Holz. Roh-Werkstoff 22, 377 (1964).
M. V. Ramiah and D. A. I. Goring, Cellul. Chem. Technol. 1, 277 (1967).
H. Hatakeyama et al., Tappi 52, 1724 (1969).
H. Hatakeyama and J Nakano, Tappi 53, 472 (1970).
H. Hatakeyama, K. Kubota, and J Nakano, Cellul. Chem. Technol. 6, 521 (1972).
H. Hatakeyama et al., Mokuzai Gakkaishi. 21, 618 (1975).
T. Hatakeyama, K. Nakamura, and H Hatakeyama, Polymer 19, 593 (1978).
S. Hirose, T. Hatakeyama, and H Hatakeyama, Cellul. Chem. Technol. 12, 713 (1978).
G. Domburgs et al., Khim. Drev. 10, 97 (1971).
J. O. Lephardt and R. A. Fenner, Polym. Prepr. 22, 282 (1981).
R. A. Fenner and J. D. Lephardt, J. Agric. Food Chem. 29, 846 (1981).
G. Domburgs, V. N. Sergeeva, and G Zeibe, Khim. Drev. 7, 59 (1971).
H. F. J. Wenzl, The Chemical Technology of Wood (Academic Press, New York, 1970).
J. Gierer and S. Y. Lin, Sv. Papperstidn. 75, 239 (1972).
N. S. Hon, J. Polym. Sci., Polym. Chem. Ed. 13, 2641 (1975).
F. Martin, C. Saiz-Jimenez, and F. J. Gonzalez-Vila, Holzforschung 33, 210 (1979).
G. Domburgs, V. N. Sergeeva, and A Kamins, Therm. Anal. Proc. Int. Conf., 3rd 1971 3, 327 (1972).
T. L. Fletcher and E. E. Harris, Tappi 35, 536 (1952).
M. T. Klein and P. S. Virk, Report, MIT-EL-81-005 (1981).
A. Gillet and J Urlings, Chimie & Industrie. 67, 909 (1952).
T. J. J. Elder, Ph.D. thesis, Texas A & M University (1979).
R. J. Dimler, Adv. Carbohyd. Chem. 7, 37 (1952).
G. Domburgs, I. Kirsbaums, and V. N. Sergeeva, Khim. Drev. 7, 51 (1971).
G. Domburgs et al., Khim. Drev. 10, 97 (1971).
G. Domburgs, V. N. Sergeeva, and Z Trops, Khim. Drev. 7, 55 (1971).
G. Domburgs, V. N. Sergeeva, and G Zeibe, Khim. Drev. 9, 119 (1971).
G. Domburgs et al., Khim. Drev. 14, 109 (1973).
G. Domburgs. G. A. Rossinskaya, and G Dobele, Khim. Drev. 4, 87 (1975).
G. Domburgs, G. A. Rossinskaya, and G Dobele, Khim. Drev. 5, 103 (1975).
G. Domburgs et al., in Khim. Ispol’z. Lignina edited by V. N. Sergeeva (Rigga., USSR, 1974).
G. A. Rossinskaya and G Domburgs, Khim. Drev. 4, 95 (1975).
G. Domburgs, V. N. Sergeeva, and A. N. Popov, Khim. Drev. 6, 133 (1970).
G. Domburgs, Latv. PSR Zinat. Akad. Vestis, Kim. Serv. 6, 734 (1974).
G. Domburgs et al., in Khim. Ispol’z. Lignina edited by V. N. Sergeeva (Rigga., USSR, 1974).
G. Domburgs, I. Kirsbaums, and V. N. Sergeeva, Khim. Drev. 7, 43 (1971).
G. Domburgs et al., Khim. Drev. 1, 51 (1974).
L. K. Dubova et al. Khim. Drev. 2, 83 (1981).
G. Domburgs et al. Khim. Drev. 15, 101 (1974).
T. Arima, Mokuzai Gakkaishi 19, 443 (1973).
R. Ceylan and J. B. Bredenberg, Fuel 61, 377 (1982).
M. T. Klein and P. S. Virk, Ind. Eng. Chem. Fundam. 22, 35 (1983).
K. J. Freudenberg and A. C. Neish, Constitution and Biosynthesis of Lignin (Springer, New York, 1968).
V. I. Savinykh et al., Khim. Drev. 5, 100 (1975).
V. I. Savinykh et al, Khim. Drev. 3, 91 (1976).
A. H. Cutler, M. J. Antal, Jr., and M Jones, submitted to Ind. Eng. Chem. Fundam.
S. S. Kim, M. L. Jarand, and K Durai-Swamy, Fuel 61(2), 1124 (1982).
Y. S. Stein, M. J. Antal, Jr., and M Jones, J. Anal. and Appl. Pyrol. 4, 283 (1983).
F. Shafizadeh, R. A. Susott, and G. D. McGinnis, Carbohyd. Res. 22, 63 (1972).
F. Shafizadeh, Y. Z. Lai, and R. A. Susott, Carbohyd. Res. 25, 387 (1972).
F. Shafizadeh, M. H. Meshreki, and R. A. Susott, J. Org. Chem. 38, 1190 (1973).
Y. Z. Lai and F Shafizadeh, Carbohyd. Res. 38, 177 (1974).
B. Kosikova, D. Joniak, and M Kosk, Cellul. Chem. Technol. 9, 61 (1975).
B. Kosikova et al., Cellul. Chem. Technol. 12, 657 (1978).
B. Kosikova et al., Cellul. Chem. Technol. 12, 665 (1978).
M. T. Klein and P. S. Virk, Preprints of Div. Fuel Chem. Am. Chem. Soc., Vol. 26, p. 77 (1981).
D. L. Urban and M. J. Antal, Jr., Fuel 61, 799 (1982).
H. H. King et al., Preprints of Div. Fuel Chem. Am. Chem. Soc., Vol. 28, p. 319 (1983).
E. Avni et al., Preprints of Div. Fuel Chem. Am. Chem. Soc., Vol. 28, p. 307 (1983).
J. H. Flynn, Thermochim. Acta. 37, 225 (1980).
B. Iatridis and G. R. Gavalas, Ind. Eng. Chem. Prod. Res. Dev. 18, 127 (1979).
D. W. Goheen and J. T. Henderson, Cellulose Chem. Technol. 12, 363 (1978).
R. W. Chan and B. B. Krieger, J. Appl. Polym. Sci. 26, 1533 (1981).
H. Traitler and K Kratzl, JAOCS, 153 (1980).
H. Traitler, E, Lorbeer, and K Kratzl, JAOCS, 335 (1980).
W. J. Connors et al., Holzforschung. 34, 29 (1980).
D. W. Goheen, Advan. Chem. Ser. 59, 205 (1966).
K. M. Sprouse and M. D. Schuman, Combust. Flame 43, 265 (1981).
L. F. Hawley. Wood Distillation (Chemical Catalog Co., Inc., New York, 1923).
A. W. Goos, Wood Chemistry 2, ACS Nomograph Series No. 97, 2nd ed. (1952).
E. S. Lipinsky, Science 212, 465 (1981).
Y. Fahmy, Cellul. Chem. Technol. 16, 347 (1982).
T. K. Ng et al., Science 219, 733 (1983).
G. I. Sorokina and V. S. Petrov, Izv. Vyssh. Uchebn. Zaved., Lesn. Zh. 6, 90 (1981).
P. R. Blackenhorn et al., Wood Science 2, 90 (1981).
D. Mackay and P. V. Roberts, Ext. Abstr. Program— Bienn. Conf. Carbon 15, 218 (1981).
D. M. Mackay and P. V. Roberts, Carbon 20, 87 (1982).
S. M. Krutov and V. E. Kovalev, Gidroliz. Lesokhim. Prom. 21, 22 (1968).
M. Dalbina et al, Khim. Drev. 2, 78 (1980).
M. Dalbina et al., Khim. Drev. 5, 99 (1980).
K. Beall and D Duncan, in Proc.—Bioenergy R & D Semin. 2nd, 147 (1980).
C. Roy et al., in Proc.—Bioenergy R & D Semin. 3rd, 191 (1981).
M. Miura et al., Mokuzai Gakkaishi 28, 649 (1982).
M. Miura, H. Nishizaki, and H Kaga, Mokuzai Gakkaishi 28, 727 (1982).
M. Kosik and V Reiser, Holztechnolgie 14, 179 (1973).
V. Karlivans et al., Gidroliz. Lesokhim. Prom-st. 3, 6 (1981).
D. P. Barnes, P. R. Blankenhorn, and W. K. Murphey, Wood Science 12, 122 (1979).
T. W. Mattocks, MSE thesis, Princeton University, 1981.
M. J. Antal, Jr., in Fundamentals of Thermochemical Biomass Conversion edited by R. P. Overend, T. A. Milne and L. K. Mudge (Elsevier, London, 1985).
R. A. Susott, W. F. DeGroot, and F Shafizadeh, Journal of Fire and Flammability 6, 311 (1975).
F. Shafizadeh, P. P. S. Chin, and W. F. DeGroot, Forest Science 23, 81 (1977).
R. A. Susott, F. Shafizadeh, and T. W. Aanerud, Journal of Fire and Flammability 10, 94 (1979).
R. A. Susott, Forest Science 28, 404 (1982).
F. Beall, Ph.D. thesis, Syracuse University, 1968.
A. Broido and M Weinstein, in Thermal Analysis Proceedings 3rd ICTA, edited by Hans G. Wiedemann (Birkhauer, Basel. 1971) p. 285.
H. W. Eickner, Forest Prod. J. 12, 194 (1962).
F. C. Beall and H. W. Eickner, Thermal Degradation of Wood Components. A Review of the Literature (U. S. D. A. Forest Serv. Res. Pap. FPL130, 1970).
A. F. Roberts, Flame 14, 261 (1970).
J. A. Havens, Ph.D. thesis, University of Oklahoma, 1969.
J. A. Havens, J. R. Welker, and C. M. Sliepcevich, J. Fire and Flammability 2, 321 (1971).
K. Akita, Rep. Fire Res. Inst. 9, 10 Japan (1956).
A. J. Stamm, Ind. Eng. Chem. 48, 413 (1956).
D. F. Arseneau, Can. J. Chem. 39, 1915 (1961).
D. Radislav and R Frantisek, Holz. Roh-Werkstoff 20, 473 (1962).
W. K. Tang, U. S. Dept. Agriculture Forest Serv. Res. Paper, FPL 71 (1967).
F. Shafizadeh and W. F. DeGroot, in Fuels and Energy from Renewable Resources edited by F. Shafizadeh, K. Sarkanen, and D Tillman (Academic Press, New York, 1977).
V. N. Sergeeva and A Valvads, Latvijas PSR Zinatnu Akad. Vestis 86, 102 (1954).
R. Keylwerth and N Christoph, Materialpruf 2, 281 (1960).
F. C. Beall, Wood Science and Technology 5, 159 (1971).
A. F. Roberts, in 13th International Symp. of Combustion (The Combustion Institute, Pittsburgh, Pa., 1971) p. 893.
F. Shafizadeh and G. D. McGinnis, Carbohyd. Res. 16, 273 (1971).
M. S. Duvvuri et al., J. Fire and Flammability 6, 468 (1975).
T. W. Mattocks, MSE thesis, Princeton University, 1981.
F. Thurner, U. Mann and S. R. Beck, Report, DOE/ET/20041-T2 (1980).
A. F. Roberts, Combustion and Flame 17, 79 (1971).
V. Hornof et al., Thermochimica Acta. 19, 63 (1977).
F. Shafizadeh et al., J. Org. Chem. 36, 2813 (1971).
F. Shafizadeh, G. D. McGinnis and C. W. Philpot, Carbohyd. Res. 25, 23 (1972).
F. Shafizadeh, R. A. Susott, and G. D. McGinnis, Carbohyd. Res. 22, 63 (1972).
F. Shafizadeh, Y. Z. Lai, and R. A. Susott, Carbohyd. Res. 25, 387 (1972).
F. Shafizadeh, M. H. Meshreki, and R. A. Susott, J. Org. Chem. 38, 1190 (1973).
F. Shafizadeh and Y. Z. Lai, Carbohyd. Res. 31, 57 (1973).
Y. Z. Lai and F Shafizadeh, Carbohyd. Res. 38, 177 (1974).
G. Domburgs, T. N. Skripchenoko, and I. Z. Kirshbaum, in Therm. Anal. Tezisy Dokl., Soveshch. 7th edited by V. Karlivan and P Zinatne (Riga, USSR, 1979).
A. F. Roberts and G Clough, in 9th Symposium on Combustion (Academic Press, New York, 1963).
A. M. Kanury and P. L. Blackshear, Jr., Pyrodynamics 4, 285 (1966).
J. A. Havens et al., Combustion Science and Technology 5, 91 (1972).
C. Fairbridge, R. A. Ross, and P Spooner, Wood Sci. Technol. 9, 257 (1975).
D. Q. Tran and C Rai, Fuel 57, 293 (1978).
C. Fairbridge, R. A. Ross, and S. P. Sood, J. Appl. Polym. Sci. 22, 497 (1978).
R. D. Cardwell and P Luner, Tappi 61, 81 (1978).
E. Chornet and C Roy, Thermochimica Acta. 35, 389 (1980).
A. Kumar and R. S. Mann, in Proc.—Bio-energy R & D Semin. 3rd, 231 (1981).
A. Kumar and R. S. Mann, J. Anal. Appl. Pyrolysis 4, 219 (1982).
F. Mobarak, Y. Fahmy, and W Schweers, Wood Sci Technology 16, 59 (1982).
J. N. Foussard, B. Talayrach, and J Besombes Vailhe, Afinidad 36, 335 (1979).
M. A. Hamad, J. Chem. Tech. Biotechnol. 31, 624 (1981).
J. P. Diebold and G. D. Smith, Noncatalytic Conversion of Biomass to Gasoline, 79-Sol-29 (American Society of Mechanical Engineers, 1978).
J. P. Diebold and J Scahill, in SERI/PR-234-1456 (1982).
J. P. Diebold and J Scahill, in 14th Biomass Thermochemical Conversion Contractors’ Review Meeting. SERI/TP-234-1654 (1982).
J. Lédé et al., Rev. Phys. Appl. 15, 545 (1980).
J. Lédé and J Villermaux, Recherche 13, 786 (1982).
M. Bohn and C Benham, in Proc. Specialists Workshop on Fast Pyrolysis of Biomass, SERI/CP-622-1096 (Solar Energy Research Institute, Golden, Colo., 1980).
M. Bohn and C Benham, SERI/TP-252-1398 (Solar Energy Research Institute, Golden, Colo., 1982).
T. A. Milne and M. N. Soltys, Quarterly Report, SERI/PR-234-1923 (Solar Energy Research Institute, Golden, Colo., 1982).
X. Deglise et al., Comm. Eur. Communities in 1st Energy Biomass Conf. EUR:7091:548.
S. Caubet et al., Solar Energy 29, 565 (1982).
D. S. Scott and J Piskorz, Canadian Journal of Chem. Eng. 60, 666 (1982).
T. Reed, A Survey of Biomass Gasification (Noyes Data Corp., Park Ridge, N. J., 1981).
E. Rensfelt et al., in Energy from Biomass and Wastes edited by D. E. Klass (Washington, D. C., 1978).
J. R. Richard, M. Cathonnet, and J. P. Rouan, Gasification of Charcoal Influence of Water Vapor, to appear.
D. S. Scott and J Piskorz, Canadian Journal of Chem. Eng. 60, 666 (1982).
C. Roy and E Chornet, to appear.
C. Roy et al., to appear.
W. C. Chan, M. Kelbon, and B. B. Krieger, in Proceedings, Fundamentals of Thermochemical Biomass Conversion: An International Conference (Estes Park, Colo., 1982).
R. Chan et al., presented at Western States Combustion Inst. Meeting (1981).
R. Chan and B. B. Krieger, in Chemical Reaction Engineering (American Chemical Society, Washington, D. C., 1982).
M. Steinberg and P Fallon, in Proceedings of the 12th Biomass Thermochemical Conversion Contractors’ Meeting (Washington, D. C., 1981).
M. Steinberg and P Fallon, in Proceedings of the 13th Biomass Thermochemical Conversion Contractors’ Meeting, PNL-SA-10093 (Arlington, Va., 1981).
P. C. Stangeby and S. N. Basu, in Proc.—Bio-energy R & D Seminar, 2nd, 239 (1980).
S. N. Basu and P. C. Stangeby, in Proc.—Bio-energy R & D Seminar, 3rd, 257 (1981).
M. Steinberg. P. Fallon, and M. S. Sundaram, in Proceedings, Fundamentals of Thermochemical Biomass Conversion: An International Conference, Estes Park, Colo (1982).
C. W. Philpot, Forest Sci. 16, 461 (1970).
C. W. Philpot, USDA Forest Service, Research Note INT-139 (1971).
X. Deglise et al., in Energy from Biomass, 1st E. C. Conference edited by W. Palz, P. Chartier, and D. O. Hall (Applied Science Publishers, London, 1980).
X. Deglise et al., Rev. Gen. Therm. Fr. 19, 871 (1980).
L. K. Mudge, L. J. Sealock, Jr., and S. L. Weber, J. Anal. Appl. Pyrolysis 1, 165 (1979).
D. H. Mitchell, L. K. Mudge, and E. G. Baker, in Proceedings of the 13th Biomass Thermoconversion Contractors’ Meeting, PNL-SA-10093 (Arlington, Va., 1981).
P. Fong and R. A. Ross, Wood Sci. 13, 87 (1980).
P. Fong and R. A. Ross, Applied Energy 9, 211 (1981).
R. A. Ross and P Fong Ind. Eng. Chem. Prod. Res. Dev. 20, 197 (1981).
A. Rolin et al., J. Anal. Appl. Pyrolysis 5, 151 (1983).
M. J. Antal, Jr. Method and Apparatus for Producing Synthetic Fuels from Solid Wastes. U. S. Patent 3,993,458.
R. C. Feber and M. J. Antal, Jr., Environmental Protection Technology Series, EPA-600/2-77-147 (1977).
M. J. Antal, Jr., Thermochemical Conversion of Biomass: The Scientific Aspects, NTIS DE 081904166 (PB-81-134793, 1980).
F. Shafizadeh and T. T. Stevenson, J. Appl. Polym. Sci. 27, 4577 (1982).
O. P. Golova, Russian Chemical Reviews 44, 687 (1975).
T. B. Reed, “Principles and technology of biomass gasification,” Advances in Solar energy edited by K. W. Böer and J. A. Duffie (Plenum Publishing Corp., New York, 1985).
J. L. Jones, in Solid Wastes and Residues edited by J. L. Jones and S. B. Radding (American Chemical Society, Washington, D. C., 1978).
R. F. Probstein and R. E. Hicks, Synthetic Fuels (McGraw-Hill, New York, 1982).
B. Guthrie, Colorado School Mines Quart. 3, 7 (1964).
G. L. Baughman, Synthetic Fuels Handbook, 2nd ed. (Cameron Engineers, Inc., Denver, Colo., 1978).
M. J. Antal, Jr., in Energy from Biological Processes. Appendices 3, NTIS/DE 081904166 (PB-81-134793, 1980).
Office of Technology Assessment, “An assessment of oil shale technologies,” 052-003-00759-2 (1980).
E. M. Wilson et al., Engineering and Economic Analysis of Waste to Energy Systems, NTIS/EPA-600/7-78-086 (1978).
T. E. Ctvitnicek, R. J. McCormick, and A Wojtowicz, Technical, Environmental and Economic Feasibility of Multiwaste Gasification (U. S. E. P. A, Monsanto Research Corp., Dayton, 1978).
Dow Chemical, U. S. A. Technical, Econonmic and Environmental Feasibility of China Lake Pyrolysis System (U. S. E. P. A, Freeport, 1978).
R. D. Mikesell, D. E. Garrett, and D. C. Hoag, in Solid Wastes and Residues edited by J. L. Jones and S. B. Radding (American Chemical Society, Washington, D. C., 1978).
J. Diebold and G Smith, Conversion of Trash to Gasoline, NWC Tech. Pub. 6022 (1978).
E. Epstein, H. Kosstrin, and J Alpert, in IGT’s Symposium on Energy from Biomass and Wastes (IGT, Washington, D. C, 1978).
R. O. Williams et al., in Solid Wastes and Residues edited by J. L Jones and S. B. Radding (American Chemical Society, Washington, D. C., 1978).
R. Bailie and C. A. Richmond, in Solid Wastes and Residues edited by J. L. Jones and S. B. Radding, (American Chemical Society, Washington, D. C., 1978).
J. A. Coffman, in Proceedings of the 14th Biomass Thermochemical Conversion Contractors’ Meeting, CONF-820685/PNL-SA-10646 (Arlington, Va., 1982).
Biomass Gasification: Principles and Technology edited by T. B. Reed, Energy Technology Review No. 67 (Noyes Data Corp., Park Ridge, N. J., 1981).
J. Diebold and J Scahill, Ablative Pyrolysis of Biomass in the Entrained Flow Cyclonic Reactor at SERI, SERI/PR-234-1883 (Solar Energy Research Institute, Golden, Colo., 1983).
J. Diebold, in Proceedings of the Specialists’ Workshop on Fast Pyrolysis of Biomass, SERI/CP-622-1096 (Solar Energy Research Institute, Golden, Colo., 1980).
J. Lédé et al., in Proceedings of the Specialists’ Workshop on Fast Pyrolysis of Biomass, SERI/CP-622-1096 (Solar Energy Research Institute, Golden, Colo., 1980).
V. S. Kothari, MSE thesis, Princeton University, 1980.
V. S. Kothari and M. J. Antal, Jr., Division of Fuel Chemistry preprints, Vol. 28, p. 5 (American Chemical Society, Washington, D. C., 1983).
M. J. Antal, Jr. et al., Solar Energy 30, 299 (1983).
M. W. Hopkins, MSE thesis, Princeton University, 1982.
M. W. Hopkins, C. I. DeJenga, and M. J. Antal, Jr., Progress in Solar Energy. In Press.
M. W. Hopkins, C. I. DeJenga, and M. J. Antal, Jr., Solar Energy 32, 547 (1984).
L. Hoffman, MSE thesis, Princeton University, 1981.
L. Hofmann and M. J. Antal, Jr., Solar Energy. In press.
C. K. DeJenga, M. J. Antal, Jr., and M Jones, J. Applied Polym. Sci. 27, 4313 (1982).
T. B. Reed, in Proceedings of the 13th Biomass Thermochemical Conversion Contractors’ Meeting, CONF 8110115/PNL-SA-10093 (Arlington, Va., 1981).
L. Waldheim and E Rensfelt, in Proceedings of the 11th Biomass Thermochemical Conversation Contractors’ Meeting (Richland, Wa., 1980).
P. McGeer and E Durbin, Methane Fuel for the Future (Plenum Press, New York, 1982).
Myles Thompson, private communication.
R. C. Bailie, in Proceedings of the 14th Biomass Thermochemical Conversion Contractors’ Meeting, CONF-820685/PNL-SA-10646 (Arlington, Va., 1982).
H. F. Feldman, M. A. Paisley, and H. R. Appelbaum, in Proceedings of the 14th Biomass Thermochemical Conversion Contractors’ Meeting, CONF-820685/PNL-SA-10646 (Arlington, Va., 1982).
L. K. Mok et al., Forest Products Research Society Annual Forum, Washington, D. C., 1982.
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Antal, M.J. (1985). Biomass Pyrolysis: A Review of the Literature Part 2—Lignocellulose Pyrolysis. In: Böer, K.W., Duffie, J.A. (eds) Advances in Solar Energy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-9951-3_4
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