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Adhesion Promotion and Polymer Composite Performance with Titanate Coupling Agents

  • Chapter
Adhesion Aspects of Polymeric Coatings

Abstract

The paper discusses adhesion, composite property and corrosion performance results using titanate coupling agents in organic polymer composites consisting mainly of epoxy, epoxy blends, urethanes and acrylics. It proposes that chemical titanate coupling agents assist adhesion and corrosion inhibition through reduction of air and water contained either on the metal surface, various substrates, or in the inorganics used in barrier film coatings. Mechanisms and subsequent dispersion effects are offered. The use of silica in conjunction with pyrophosphato titanates as a functional replacement for barium metaborate and basic lead silico chromate in epoxy/polyamide primer systems is evaluated in detail. Titanate performance in an epoxy ester spray zinc rich primer is shown.

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References

  1. A. N. Gent, Adhesives Age, 25 (No. 2), 27 (1982).

    Google Scholar 

  2. T. J. Reinhart, U. S. Air Force Wright Aeronautical Laboratories, (22 January 1980), personal communication.

    Google Scholar 

  3. T. J. Reinhart, U. S. Air Force Wright Aeronautical Laboratories, (12 March 1980), personal communication.

    Google Scholar 

  4. N. H. Sung, in “Proc. of 36th Annual Conference, Reinforced Plastics/Composites Institute”, SPI, February 16–20, 1981.

    Google Scholar 

  5. C. D. Han, T. Van Den Weghe, P. Shete and J. R. Haw, Polymer Eng. Sci., 21 (No. 4) 196 (1981).

    Article  CAS  Google Scholar 

  6. A. Damusis and P. Patel, Polymer Institute, University of Detroit, (27 July 1981), personal communication.

    Google Scholar 

  7. G. Hutchins, R. Spell, LNP Corp., Malvern, PA, (Sept. 1981), personal communication.

    Google Scholar 

  8. T. Skidmore, Siecor Corp., Hickory, NC, (Feb. 1982), personal communication.

    Google Scholar 

  9. T. Baker, Raytheon Corp., Sudbury, MA, (March 1982), personal communication.

    Google Scholar 

  10. M. Briggs, Colebrand Ltd., Rossendale U.K, (March 1981), personal communication.

    Google Scholar 

  11. P. Westerman, BP Research Ltd., Middlesex U.K., (April 1981), personal communication.

    Google Scholar 

  12. K. Geddes, University of Lowell, Lowell MA, (June 1981), personal communication.

    Google Scholar 

  13. A. Chattopadhyay, De Soto, Inc., DesPlaines, IL, (July 1981), personal communication.

    Google Scholar 

  14. Jpn. Kokai Tokkyo Koho 80,120,649, 17 Sept. 1980, Hitachi Chemical Co., Ltd.

    Google Scholar 

  15. Jpn. Kokai Tokkyo Koho 81,28,222, 19 Mar. 1981., Shin-Kobe Electric Machinery Co., Ltd.

    Google Scholar 

  16. Jpn. Kokai Tokkyo Koho 81,999,266, 10 Aug. 1981, Dainippon Toryo Co., Ltd.

    Google Scholar 

  17. Technical Committee, Cleveland Society for Coatings Technology, J. Coatings Technol., 51 (No. 655), 38 (August 1979).

    Google Scholar 

  18. Jpn. Kokai Tokkyo Koho 80,152,759, 28 Nov. 1980, Dainippon Toryo Co., Ltd.

    Google Scholar 

  19. German Patent No. 3038646, 13 Oct. 1980, Sony Corp.

    Google Scholar 

  20. L.T. Warfield, Pfizer, Inc., Evston, PA, (Nov. 1981), personal communication

    Google Scholar 

  21. J.H. Silner, S. Spindel, and S.B. Levinson, DL Laboratories, “Evaluation of the Corrosion Resistant Properties of Ken-React® KR 38S and Busan 11-M1 in an Epoxy/Polyamide Primer”, Report DL-3299 (8 Sept. 1981 )

    Google Scholar 

  22. S. Spindel, S.B. Levinson, DL Laboratories, “Evaluation of the Corrosion Resistant Properties of Kenrich KR 38S in an Epoxy/Polyamide Primer”, Report DL-2871E, (Nov. 1978).

    Google Scholar 

  23. K. Frantz, Electrocoat Chemical Co., Detroit, MI., (Sept. 1981), personal communication.

    Google Scholar 

  24. E. Sanhueza, Mobil Chemicals, Finishes Div., Edison, NJ, (Nov. 1981), personal communication.

    Google Scholar 

  25. P. D. Calvert, R. R. Lalanandam, D. R. M. Walton, this proceedings volume.

    Google Scholar 

  26. S. Prasad and R. C. Srivastava, J. Ind. Chem. Soc., 39, 9 (1962).

    CAS  Google Scholar 

  27. Jpn. Kokai Tokkyo Koho JP 81,46,835, 28 Apr. 1981, Matsumoto Seivaku Kogyo Co., Ltd.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Kenrich Petrochemicals, Inc., East 22nd Street, Bayonne, NJ, 07002, USA

    Salvatore J. Monte & Gerald Sugerman

Authors
  1. Salvatore J. Monte
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  2. Gerald Sugerman
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Editor information

Editors and Affiliations

  1. East Fishkill Facility, IBM Corporation, Hopewell Junction, New York, 12533, USA

    K. L. Mittal

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© 1983 Plenum Press, New York

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Monte, S.J., Sugerman, G. (1983). Adhesion Promotion and Polymer Composite Performance with Titanate Coupling Agents. In: Mittal, K.L. (eds) Adhesion Aspects of Polymeric Coatings. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3658-7_25

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  • DOI: https://doi.org/10.1007/978-1-4613-3658-7_25

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3660-0

  • Online ISBN: 978-1-4613-3658-7

  • eBook Packages: Springer Book Archive

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