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The Chemical Shift

  • Chapter
Multinuclear NMR

Abstract

The chemical shift (as defined by IUPAC) in terms of measured frequencies

$$ \delta = \left( {\nu - \nu _{{\text{ref}}} } \right){\text{/}}\nu _{{\text{ref}}} $$
(1)

is related to a fundamental molecular property, the nuclear magnetic shielding, σ. For a molecule held in a fixed orientation in a uniform magnetic field B, the field at a selected point in the vicinity of the molecule is different from B because of the small field arising from the circulations of the electrons induced by the magnetic field*:

$$ B_{{\text{local}}} {\text{ = }}\left( {1 - \sigma } \right)B $$
(2)

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  1. Department of Chemistry, University of Illinois, Chicago, Illinois, 60680, USA

    Cynthia J. Jameson

  2. Department of Chemistry, The Open University, Milton Keynes, MK7 6AA, England

    Joan Mason

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    Joan Mason

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Jameson, C.J., Mason, J. (1987). The Chemical Shift. In: Mason, J. (eds) Multinuclear NMR. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1783-8_3

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