Abstract
The study of potassium (K) exchange on clay minerals and soils can be viewed from either a thermodynamic or a kinetic perspective. In pursuing the soil science literature, one will undoubtedly find that most of the studies on K exchange have been of an equilibrial rather than of a dynamic nature. Although the former studies have proved valuable in understanding the often elusive behavior of K in heterogeneous systems, they do not convey information about the rates or mechanisms of K exchange processes. Moreover, thermodynamic investigations on soil K are often not applicable to field conditions. Although a quasi-state equilibrium in K exchange can be achieved in the laboratory, these conditions are seldom if ever attained under field conditions.
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Sparks, D.L. (1987). Potassium Dynamics in Soils. In: Stewart, B.A. (eds) Advances in Soil Science. Advances in Soil Science, vol 6. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-4682-4_1
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